1,10-phenanthroline-5,6-bis(N-benzyl-1'-oxopropylamide) | 873570-16-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: 1,10-phenanthroline-5,6-bis(N-benzyl-1'-oxopropylamide)
• 英文别名: N-benzyl-2-[[6-[2-(benzylamino)-2-oxoethoxy]-1,10-phenanthrolin-5-yl]oxy]acetamide
• CAS: 873570-16-2
• 化学式: C₃₀H₂₆N₄O₄
• 分子量: 506.561
• InChiKey: QKOVEBLWZFOMNX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  38
• 可旋转键数：
  10
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  102
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  1,10-phenanthroline-5,6-bis(N-benzyl-1'-oxopropylamide) 、 europium(III) nitrate hexahydrate 以 乙酸乙酯 为溶剂， 以80%的产率得到[Eu4(NO3)10(1,10-phenanthroline-5,6-bis(N-benzyl-1'-oxopropylamide)3](NO3)2
  参考文献：
  名称：

  Terminal group effects on the fluorescence spectra of Eu(III) nitrate complexes with a family of amide-based 1,10-phenanthroline derivatives

  摘要：

  Four ligands 1,10-phenanthroline-5,6-bis(N,N-dibenzyl-l'-oxopropylamide) (L-a) 1,10-phenanthroline-5,6-bis(N-methyl-N-benzyl-l'oxopropylamide) (L-b) 1,10-phenanthroline-5,6-bis(N-benzyl-l'-oxopropylamide) (L-c) and 1,10-phenanthroline-5,6-bis(N,N-diethyl-l'oxopropylamide) (L-d), and their lanthanide(III) (La and Eu) complexes were synthesized. The complexes were characterized by elemental analysis, IR, fluorescence spectroscopy and conductivity. The lanthanide atoms are coordinated by O atoms from C=O, Ar-O-C and N atoms from phen With the difference of the ligands, the fluorescent intensities of the Eu(Ill) complexes vary regularly in the THF solution. Some factors that influence the fluorescent intensity were discussed. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2005.03.010
• 作为产物：
  描述：

  N-苄基-2-氯乙酰胺 、 1,10-phenanthroline-5,6-diol hydrochloride 在 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 24.0h， 以78%的产率得到1,10-phenanthroline-5,6-bis(N-benzyl-1'-oxopropylamide)
  参考文献：
  名称：

  Terminal group effects on the fluorescence spectra of Eu(III) nitrate complexes with a family of amide-based 1,10-phenanthroline derivatives

  摘要：

  Four ligands 1,10-phenanthroline-5,6-bis(N,N-dibenzyl-l'-oxopropylamide) (L-a) 1,10-phenanthroline-5,6-bis(N-methyl-N-benzyl-l'oxopropylamide) (L-b) 1,10-phenanthroline-5,6-bis(N-benzyl-l'-oxopropylamide) (L-c) and 1,10-phenanthroline-5,6-bis(N,N-diethyl-l'oxopropylamide) (L-d), and their lanthanide(III) (La and Eu) complexes were synthesized. The complexes were characterized by elemental analysis, IR, fluorescence spectroscopy and conductivity. The lanthanide atoms are coordinated by O atoms from C=O, Ar-O-C and N atoms from phen With the difference of the ligands, the fluorescent intensities of the Eu(Ill) complexes vary regularly in the THF solution. Some factors that influence the fluorescent intensity were discussed. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2005.03.010