N,N-Bis(4-nitrophenyl)-N',N'-di(4-methoxyphenyl)-1,4-phenylenediamine | 1011470-34-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N-Bis(4-nitrophenyl)-N',N'-di(4-methoxyphenyl)-1,4-phenylenediamine
• 英文别名: N,N-bis(4-nitrophenyl)-N',N'-di(4-methoxyphenyl)-1,4-benzenediamine；4-N,4-N-bis(4-methoxyphenyl)-1-N,1-N-bis(4-nitrophenyl)benzene-1,4-diamine
• CAS: 1011470-34-0
• 化学式: C₃₂H₂₆N₄O₆
• 分子量: 562.582
• InChiKey: PHLOEDPHLFAMKQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8
• 重原子数：
  42
• 可旋转键数：
  8
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  117
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  N,N-Bis(4-nitrophenyl)-N',N'-di(4-methoxyphenyl)-1,4-phenylenediamine 在 10% palladium on carbon 、 肼 作用下， 生成 N,N-bis(4-aminophenyl)-N',N'-di(4-methoxyphenyl)-1,4-phenylenediamine
  参考文献：
  名称：

  Novel anodic electrochromic aromatic polyamides with multi-stage oxidative coloring based on N,N,N′,N′-tetraphenyl-p-phenylenediamine derivatives

  摘要：

  一种新型二羧酸单体--N,N-双（4-羧基苯基）-Nâ²,Nâ²-二（4-甲氧基苯基）-1,4-苯二胺（4）和多种芳香族二胺通过直接磷酸化缩聚反应制备了一系列具有下垂的 4,4â²-二甲氧基取代三苯胺（TPA）单元的新型芳香族聚酰胺。这些聚酰胺是无定形的，在 N-甲基-2-吡咯烷酮（NMP）和 N,N-二甲基乙酰胺（DMAc）等多种有机溶剂中具有良好的溶解性，可以溶液浇铸成柔性聚合物薄膜。这些聚合物具有极佳的热稳定性，其玻璃化转变温度相对较高（233â308 °C）。在 NMP 溶液中，这些聚合物在 351- 363 nm 处显示出强烈的紫外-可见吸收带。它们的光致发光光谱在 450-504 nm 处显示出最大波段。电化学和光谱电化学方法检测了空穴传输和电致变色特性。由二羧酸单体（4）与结构相似的二胺单体 N,N-双（4-氨基苯基）-Nâ²,Nâ²-二（4-甲氧基苯基）-1,4-苯二胺（5g）制备的聚酰胺 6g 的循环伏安图显示，在乙腈溶液中，Eonset = 0.35、E1/2 = 0.64、0.84 和 0.99 V 时，存在四个可逆氧化还原偶。经过 3000 多次绿色循环切换后，聚酰胺 6g 薄膜的电致色性仍表现出极佳的连续循环稳定性。

  DOI：

  10.1039/b810750e

文献信息

• Electrode for an electrochemical element with an organic electrolyte, electrochemical elements comprising the electrode and polymeric material and its use as electrode active material or as electrode binder
  申请人：VARTA Micro Innovation GmbH

  公开号：EP3032621A1

  公开（公告）日：2016-06-15

  Disclosed is an electrode comprising a polymeric material containing or being composed of subunits according to general formulae (I) and (II) wherein in these structures (I) and (II) n is an integer not smaller than 2, Y represents an amide group (-NH-CO- or -CO-NH-), an ester group (-O-CO- or -CO-O-) or a urethane group (-NH-CO-O- or -O-CO-NH-), R1, R2, R3 and R4 each independently represent H, alkyl (preferably-CH3, -C2H5), alkoxy-(preferably -OCH3, -OC2H5), -halogen or -CN, Ar1 and Ar4 independently represent a bridging aryl group, Ar2 and Ar3 independently represent a non-bridging aryl group, and R5 is a bridging alkyl or aryl group. Further, a Lithium-ion battery and a supercapacitor with such an electrode and the use of said polymeric material as electrode active material in the electrode of a battery or in the electrode of a supercapacitor and/or as an electrode binder is disclosed.

  本发明公开了一种电极，它包含一种聚合物材料，该材料含有或由符合通式 (I) 和 (II) 的亚基组成 其中在这些结构（I）和（II）中，n 是不小于 2 的整数，Y 代表酰胺基（-NH-CO- 或 -CO-NH-）、酯基（-O-CO- 或 -CO-O-）或氨基甲酸酯基（-NH-CO-O- 或 -O-CO-NH-），R1、R2、R3 和 R4 各自独立地代表 H、烷基（优选-CH3、-C2H5）、烷氧基（优选-O 、-O ）、-卤素或-CN，Ar1 和 Ar4 各自独立地代表桥接芳基，Ar2 和 Ar3 各自独立地代表非桥接芳基，R5 是桥接烷基或芳基。此外，还公开了具有这种电极的锂离子电池和超级电容器，以及在电池电极或超级电容器电极中使用所述聚合物材料作为电极活性材料和/或作为电极粘合剂。
• Composite material, electrode, method of producing the material and the electrode and electrochemical cell
  申请人：VARTA Microbattery GmbH

  公开号：US10468715B2

  公开（公告）日：2019-11-05

  A composite material includes an electrochemically active organic material and an electrochemically active inorganic material. The organic material contains subunits according to formulae (I) and/or (II) wherein n is an integer not smaller than 2, Y represents an amide group (—NH—CO— or —CO—NH—), an ester group (—O—CO— or —CO—O—) or a urethane group (—NH—CO—O— or —O—CO—NH—), R1, R2, R3 and R4 each independently represent H, alkyl (preferably —CH3, —C2H5), alkoxy-(preferably —OCH3, —OC2H5), -halogen or —CN, Ar1 and Ar4 independently represent a bridging aryl group, Ar2 and Ar3 independently represent a non-bridging aryl group, and R5 is a bridging alkyl, alkene or aryl group.

  一种复合材料包括电化学活性有机材料和电化学活性无机材料。有机材料含有符合式 (I) 和/或 (II) 的亚基 其中 n 是不小于 2 的整数，Y 代表酰胺基（-NH-CO- 或 -CO-NH-）、酯基（-O-CO- 或 -CO-O-）或聚氨酯基（-NH-CO-O- 或 -O-CO-NH-），R1、R2、R3 和 R4 各自独立地代表 H、烷基（优选-CH3、-C2H5）、烷氧基（优选-O 、-O ）、-卤素或-CN，Ar1 和 Ar4 各自独立地代表桥接芳基，Ar2 和 Ar3 各自独立地代表非桥接芳基，R5 是桥接烷基、烯基或芳基。
• COMPOSITE MATERIAL, ELECTRODE, METHOD TO PRODUCE THE MATERIAL AND THE ELECTRODE AND ELECTROCHEMICAL CELL COMPRISING THE ELECTRODE
  申请人：VARTA Microbattery GmbH

  公开号：EP3154111B1

  公开（公告）日：2019-06-12
• ELECTRODE FOR AN ELECTROCHEMICAL ELEMENT WITH AN ORGANIC ELECTROLYTE, ELECTROCHEMICAL ELEMENTS COMPRISING THE ELECTRODE AND POLYMERIC MATERIAL AND ITS USE AS ELECTRODE ACTIVE MATERIAL OR AS ELECTRODE BINDER
  申请人：VARTA Micro Innovation GmbH

  公开号：EP3231029A1

  公开（公告）日：2017-10-18
• COMPOSITE MATERIAL, ELECTRODE, METHOD OF PRODUCING THE MATERIAL AND THE ELECTRODE AND ELECTROCHEMICAL CELL
  申请人：VARTA MICROBATTERY GMBH

  公开号：US20180287192A1

  公开（公告）日：2018-10-04

  A composite material includes an electrochemically active organic material and an electrochemically active inorganic material. The organic material contains subunits according to formulae (I) and/or (II) wherein n is an integer not smaller than 2, Y represents an amide group (—NH—CO— or —CO—NH—), an ester group (—O—CO— or —CO—O—) or a urethane group (—NH—CO—O— or —O—CO—NH—), R 1 , R 2 , R 3 and R 4 each independently represent H, alkyl (preferably —CH 3 , —C 2 H 5 ), alkoxy-(preferably —OCH 3 , —OC 2 H 5 ), -halogen or —CN, Ar 1 and Ar 4 independently represent a bridging aryl group, Ar 2 and Ar 3 independently represent a non-bridging aryl group, and R 5 is a bridging alkyl, alkene or aryl group.