Tricyclohexenylamin | 46259-19-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Tricyclohexenylamin
• 英文别名: 9-Amino-2-methyl-3,4-tetramethylen-bicyclo-(3,3,1)nonen-(2,3)；tricyclo[7.3.1.02,7]tridec-2(7)-en-13-amine
• CAS: 46259-19-2
• 化学式: C₁₃H₂₁N
• mdl: MFCD01002135
• 分子量: 191.316
• InChiKey: RNIDTNZHNRWZFL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.846
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  糠醛 、 Tricyclohexenylamin 以 乙醇 为溶剂， 以90%的产率得到[1-Furan-2-yl-meth-(E)-ylidene]-tricyclo[7.3.1.0^2,7]tridec-2(7)-en-13-yl-amine
  参考文献：
  名称：

  摘要：

  Hydroamination of tricyclo[7.3.1.0(2,7)]tridec-2(7)-en-13-one according to Leukart reaction furnished (tricyclo[7.3.1.0(2,7)]tridec-2(7)-en-13-yl)methanamides stereoisomeric at C-13 atom. The corresponding epoxides were prepared therefrom. The unsaturated and epoxidized methanamides were hydrolyzed into amines that were converted into Schiff bases. The configurations of substances were established.

  DOI：

  10.1023/a:1020941207804
• 作为产物：
  描述：

  tricyclo[7.3.1.0^2,7]tridec-2(7)-en-13-one 在 sodium hydroxide 、 甲酸 作用下， 反应 8.5h， 生成 Tricyclohexenylamin
  参考文献：
  名称：

  摘要：

  Hydroamination of tricyclo[7.3.1.0(2,7)]tridec-2(7)-en-13-one according to Leukart reaction furnished (tricyclo[7.3.1.0(2,7)]tridec-2(7)-en-13-yl)methanamides stereoisomeric at C-13 atom. The corresponding epoxides were prepared therefrom. The unsaturated and epoxidized methanamides were hydrolyzed into amines that were converted into Schiff bases. The configurations of substances were established.

  DOI：

  10.1023/a:1020941207804

文献信息

• ——
  作者：V. I. Vysotskii、O. V. Patrusheva、T. A. Vysotskaya、V. V. Isakov

  DOI：10.1023/a:1020941207804

  日期：——

  Hydroamination of tricyclo[7.3.1.0(2,7)]tridec-2(7)-en-13-one according to Leukart reaction furnished (tricyclo[7.3.1.0(2,7)]tridec-2(7)-en-13-yl)methanamides stereoisomeric at C-13 atom. The corresponding epoxides were prepared therefrom. The unsaturated and epoxidized methanamides were hydrolyzed into amines that were converted into Schiff bases. The configurations of substances were established.