2-ethylsulfonylmethylphenol | 53380-27-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 2-ethylsulfonylmethylphenol
• 英文别名: Phenol, 2-((ethylsulfonyl)methyl)-；2-(ethylsulfonylmethyl)phenol
• CAS: 53380-27-1
• 化学式: C₉H₁₂O₃S
• 分子量: 200.258
• InChiKey: PMHBGORIEUVGTQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.6
• 重原子数：
  13
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  62.8
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  杀虫丹砜 在 氢氧化钾 作用下， 以 甲醇 为溶剂， 生成 2-ethylsulfonylmethylphenol
  参考文献：
  名称：

  Photodegradation of the carbamate insecticide ethiofencarb

  摘要：

  AbstractIn order to study the photoreactivity and possible photodegradation pathways of ethiofencarb (2‐ethylthiomethylphenyl methylcarbamate) on plant surfaces, model experiments in the presence of cyclohexane, cyclohexene methylcarbamate)onand iso‐propanol were performed. Both artificial light (λ > 280 nm) and natural sunlight were used. Half‐lives of the ethiofencarb photodegradation were in the order cyclohexane < isopropanol < cyclohexene and ranged from 75 min to more than 20 h. Depending on the solvent and the light source chosen, different photo‐products were obtained. When ethiofencarb was irradiated in the presence of cyclohexane, photo‐oxidation to the corresponding sulfoxide was the main degradation pathway, followed by a cyclization reaction. In the case of isopropanol as model solvent, numerous photoproducts were detected as a result of photo‐oxidation, hydrolysis and the addition to ethiofencarb of the solvent molecule.

  DOI：

  10.1002/ps.2780430409

文献信息

• CABRAS, PAOLO;MELONI, MARCO;PLUMITALLO, ANTONIO;GENNARI, MARA, J. CHROMATOGR., 462,(1989) C. 430-434
  作者：CABRAS, PAOLO、MELONI, MARCO、PLUMITALLO, ANTONIO、GENNARI, MARA

  DOI：——

  日期：——
• Photodegradation of the carbamate insecticide ethiofencarb
  作者：Gudrun Kopf、Wolfgang Schwack

  DOI：10.1002/ps.2780430409

  日期：1995.4

  AbstractIn order to study the photoreactivity and possible photodegradation pathways of ethiofencarb (2‐ethylthiomethylphenyl methylcarbamate) on plant surfaces, model experiments in the presence of cyclohexane, cyclohexene methylcarbamate)onand iso‐propanol were performed. Both artificial light (λ > 280 nm) and natural sunlight were used. Half‐lives of the ethiofencarb photodegradation were in the order cyclohexane < isopropanol < cyclohexene and ranged from 75 min to more than 20 h. Depending on the solvent and the light source chosen, different photo‐products were obtained. When ethiofencarb was irradiated in the presence of cyclohexane, photo‐oxidation to the corresponding sulfoxide was the main degradation pathway, followed by a cyclization reaction. In the case of isopropanol as model solvent, numerous photoproducts were detected as a result of photo‐oxidation, hydrolysis and the addition to ethiofencarb of the solvent molecule.