5-norbornene-2,3-dicarbonitrile | 38447-89-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 5-norbornene-2,3-dicarbonitrile
• 英文别名: Bicyclo[2.2.1]hept-5-ene-2,3-dicarbonitrile
• CAS: 38447-89-1；51252-31-4
• 化学式: C₉H₈N₂
• 分子量: 144.176
• InChiKey: DJNPQHBMESQZIP-UHFFFAOYSA-N

物化性质

• 沸点：
  341.0±42.0 °C(Predicted)
• 密度：
  1.16±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.7
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  47.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  trifluoroacetohydroximoyl bromide etherate 、 5-norbornene-2,3-dicarbonitrile 、 三乙胺 以31%的产率得到
  参考文献：
  名称：

  TANAKA KIYOSHI; MASUDA HIDEYUKI; MITSUHASHI KEIRYO, BULL. CHEM. SOC. JAP., 59,(1986) N 12, 3901-3904

  摘要：

  DOI：
• 作为产物：
  描述：

  5-norbornene-2,3-dicarboxamide 在 四磷十氧化物 作用下， 反应 1.0h， 以87%的产率得到5-norbornene-2,3-dicarbonitrile
  参考文献：
  名称：

  腈及其相应胺的制造方法

  摘要：

  本发明涉及一种腈的制造方法，与现有技术相比，具有氨源用量显著降低、环境压力小、能耗低、生产成本低、腈产品的纯度和收率高等特点，并且能够获得结构更为复杂的腈。本发明还涉及由该腈制造相应胺的方法。

  公开号：

  CN105016943B

文献信息

• RESIN COMPOSITION AND SEMICONDUCTOR DEVICE BOARD
  申请人：Osaku Yumi

  公开号：US20140087136A1

  公开（公告）日：2014-03-27

  A resin composition which contains a binder resin (A), radiation-sensitive compound (B), silane-modified resin (C), and antioxidant (D), wherein a content of the silane-modified resin (C) is 0.1 to 150 parts by weight with respect to 100 parts by weight of the binder resin (A), a content of the antioxidant (D) is 0.1 to 10 parts by weight with respect to 100 parts by weight of the binder resin (A), and an amount of warping is 14 μm or less when using the resin composition to form a thickness 2 to 3 μm resin film and baking the formed resin film at 230° C. is provided.

  一种树脂组合物，包含粘合剂树脂（A），辐射敏感化合物（B），硅改性树脂（C）和抗氧化剂（D），其中硅改性树脂（C）的含量相对于100份粘合剂树脂（A）为0.1至150份重量，抗氧化剂（D）的含量相对于100份粘合剂树脂（A）为0.1至10份重量，并且使用该树脂组合物形成2至3μm厚度的树脂膜并在230°C下烘烤形成的树脂膜翘曲量为14μm或以下。
• Metathesis polymerization of cycloolefins
  申请人：HERCULES INCORPORATED

  公开号：EP0251033A2

  公开（公告）日：1988-01-07

  A polymer prepared by metathesis polymerizing at least one compound represented by the formula wherein m is 0 or 1 and R, and R2 respectively represent hydrogen atom or an alkyl group containing up to three carbon atoms provided that both R1 and R2 are not hydrogen atom at the same time, or a mixture of said compound with at least one other metathesis polymerizable comonomer, a useful molded article, processes for preparing the polymer and the article and a polymerizable composition therefor.

  一种聚合物，由至少一种如下式所代表的化合物通过偏析聚合反应制备而成 其中 m 为 0 或 1，R1 和 R2 分别代表氢原子或最多含有三个碳原子的烷基，但 R1 和 R2 不能同时为氢原子，或上述化合物与至少一种其他可进行元合成聚合的共聚单体的混合物。
• A process and composition for metathesis polymerization of cycloolefins
  申请人：HERCULES INCORPORATED

  公开号：EP0263425A1

  公开（公告）日：1988-04-13

  A process for producing a molded article by introducing a reactive liquid mixture which comprises a cycloalkene containing dicylopentadiene, a norbornene-type monomer containing at least one N-substituted 5-membered cyclic amide group and a metathesis polymerization catalyst system and which has moderated metathesis polymerizability into a mold in which the liquid mixture is metathesis polymerized, and a multi-part polymerizable composition for producing the molded article.

  一种生产模塑制品的工艺，其方法是将一种反应性液体混合物（其中包括含有二戊二烯的环烷烃、含有至少一个 N-取代的 5 元环状酰胺基团的降冰片烯类单体和一种偏聚催化剂体系）和一种具有适度偏聚聚合性的液体混合物引入模具中，在模具中对液体混合物进行偏聚聚合，以及一种用于生产模塑制品的多组分可聚合组合物。
• Oil soluble amino-substituted polymers containing graft polymer segments derived form aromatic nitrogen-containing monomers
  申请人：EXXON CHEMICAL PATENTS INC.

  公开号：EP0432939A2

  公开（公告）日：1991-06-19

  The novel polymers of the present invention are prepared by graft polymerization of at least one aromatic nitrogen-containing monomer onto an amino-substituted polymer (e.g., an ethylene alpha-olefin interpolymer substituted by primary amino or secondary amino groups). Preferred aromatic nitrogen-containing moieties are illustrated by aniline, and preferred amino-substituted interpolymers comprise amino-substituted ethylene propylene norbornene terpolymers. The polymers of this invention are oil soluble and are useful as dispersant and antioxidant additives in oleaginous compositions and are further useful in electrical, textile and other applications.

  本发明的新型聚合物是通过将至少一种芳香族含氮单体接枝聚合到氨基取代的聚合物（如被伯氨基或仲氨基取代的乙烯α-烯烃间聚合物）上制备的。优选的芳香族含氮分子以苯胺为例，优选的氨基取代互聚物包括氨基取代的乙烯丙烯降冰片烯三元共聚物。本发明的聚合物可溶于油，可用作含油组合物中的分散剂和抗氧化添加剂，还可用于电气、纺织和其他用途。
• Process for producing a copolymer of a non-polar olefin and a polar olefin and the copolymer obtained thereby
  申请人：MITSUI CHEMICALS, INC.

  公开号：EP1170308A2

  公开（公告）日：2002-01-09

  A process for producing a polar olefin copolymer comprises copolymerizing a non-polar olefin and a polar olefin in the presence of a transition metal compound selected from Groups 4, 5, 6 and 11 of the periodic table, which is represented by the following formula (IV): wherein M' is a transition metal atom selected from Groups 4, 5, 6 and 11 of the periodic table, m is an integer of 1 to 6, A is -O-, -Si-, -Se-, -N(R6)-, n is a number satisfying a valence of M', R1 to R4 and R6 are each a hydrogen atom, a halogen atom, a hydrocarbon group and the like, and X is a halogen atom, an oxygen atom, a hydrocarbon group and the like, and at least one compound (B) selected from the group consisting of an organometallic compound (B-1), an organoaluminum oxy-compound (B-2) and an ionic ionizing compound (B-3). Therefore, the process is capable of obtaining a polar olefin copolymer having excellent properties under mild polymerization conditions.

  一种生产极性烯烃共聚物的工艺，包括在选自元素周期表第 4、5、6 和 11 族的过渡金属化合物存在下，使非极性烯烃和极性烯烃共聚，该过渡金属化合物由下式(IV)表示： 其中 M' 是选自元素周期表第 4、5、6 和 11 族的过渡金属原子，m 是 1 至 6 的整数，A 是-O-、-Si-、-Se-、-N(R6)-，n 是满足 M' 的价数，R1 至 R4 和 R6 各为氢原子、卤素原子、烃基等、X 是卤素原子、氧原子、烃基等，以及至少一种选自有机金属化合物（B-1）、有机铝氧 化物（B-2）和离子电离化合物（B-3）的化合物（B）。因此，该工艺能够在温和的聚合条件下获得性能优异的极性烯烃共聚物。