1-(4-bromomethyl-trans-styryl)-4-trans-styryl-benzene | 102593-85-1

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 1-(4-bromomethyl-trans-styryl)-4-trans-styryl-benzene
• 英文别名: 1-(4-Brommethyl-trans-styryl)-4-trans-styryl-benzol；1-(bromomethyl)-4-[(E)-2-[4-[(E)-2-phenylethenyl]phenyl]ethenyl]benzene
• CAS: 102593-85-1
• 化学式: C₂₃H₁₉Br
• 分子量: 375.308
• InChiKey: LIFOPTPIRURFKR-GYIPPJPDSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.5
• 重原子数：
  24
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1-(4-bromomethyl-trans-styryl)-4-trans-styryl-benzene 在 氯仿 、 乌洛托品 、 乙酸酐 、 三乙胺 作用下， 生成 2-trans-stilben-4-yl-3ξ-(4'-trans(?)-styryl-trans(?)-stilben-4-yl)-acrylic acid
  参考文献：
  名称：

  Drefahl; Ploetner, Chemische Berichte, 1958, vol. 91, p. 1274,1277

  摘要：

  DOI：
• 作为产物：
  描述：

  1-(4-methyl-trans-styryl)-4-trans-styrylbenzene 在 N-溴代丁二酰亚胺(NBS) 、 氯仿 、 过氧化苯甲酰 作用下， 生成 1-(4-bromomethyl-trans-styryl)-4-trans-styryl-benzene
  参考文献：
  名称：

  Drefahl; Ploetner, Chemische Berichte, 1958, vol. 91, p. 1274,1277

  摘要：

  DOI：

文献信息

• Organic compound having functional groups different in elimination reactivity at both terminals, organic thin film, organic device and method of producing the same
  申请人：Imada Hiroshi

  公开号：US20070195576A1

  公开（公告）日：2007-08-23

  Provided are a single monomolecular film uniform in film thickness and highly ordered in molecule alignment and its multilayer film, an organic compound allowing production of such films at high reproducibility, an organic device superior in electroconductive properties and a method of producing the same. An organic compound represented by Formula: Si(A 1 )(A 2 )(A 3 )-B—Si(A 4 )(A 5 )(A 6 ) (A 1 to A 6 each represent a hydrogen atom, a halogen atom, an alkoxy group or an alkyl group and satisfy the relationship in elimination reactivity of: A 1 to A 3 >A 4 to A 6 ; and B represents a bivalent organic group), an organic thin film using the compound, and an organic device having the thin film; A method of producing an organic thin film and organic device, comprising a step of forming a single monomolecular film by allowing the silyl group having A 1 to A 3 in the organic compound to react with the substrate surface; a step of removing unreacted organic compounds by using a non-aqueous solvent; and a step of forming an additional monomolecular film of the organic compound by using the unreacted silyl groups present on the film surface side of the monomolecular film obtained as the sites for adsorption reaction.

  提供了一种在薄膜厚度上均匀且分子排列高度有序的单分子膜以及其多层膜，一种有机化合物可在高可重复性下制备这种膜，一种优越于导电性能的有机器件以及其生产方法。一种由化学式表示的有机化合物：Si(A1)(A2)(A3)-B—Si(A4)(A5)(A6)（其中A1到A6分别表示氢原子、卤素原子、烷氧基或烷基，并满足消除反应性的关系：A1到A3>A4到A6；B表示二价有机基），使用该化合物的有机薄膜，以及具有该薄膜的有机器件；一种制备有机薄膜和有机器件的方法，包括以下步骤：通过使具有A1到A3的硅基团与基底表面反应形成单分子膜；使用非水溶剂去除未反应的有机化合物；通过利用单分子膜表面上存在的未反应硅基团作为吸附反应位点形成有机化合物的额外单分子膜。
• Silicon Compound Containi-Electron Conjugated-System Molecule and Process for Producing the Same
  申请人：Nakagawa Masatoshi

  公开号：US20070287848A1

  公开（公告）日：2007-12-13

  A π-electron conjugate molecule-containing silicon compound represented by the formula (I): wherein R1 represents an organic group obtained by combining two or more units constituting plural π-electron conjugate systems, R2 represents a hydrophobic group and X1 to X3, which may be the same or different, respectively represent a group providing a hydroxyl group when it is hydrolyzed or a hydrogen atom.

  一种含有π-电子共轭分子的硅化合物，其化学式表示为(I)：其中，R1代表由构成多个π-电子共轭系统的两个或更多单元组合而成的有机基团，R2代表疏水基团，X1至X3分别可以相同或不同，代表在水解时提供羟基的基团或氢原子。
• Side Chain-Containing Type Organic Silane Compound, Thin Film Transistor and Method of Producing Thereof
  申请人：Nakagawa Masatoshi

  公开号：US20080303019A1

  公开（公告）日：2008-12-11

  A side chain-containing type organic silane compound represented by the formula (I) R—SiX 1 X 2 X 3 wherein R represents a π-electron conjugate type organic residue composed of 3 to 10 units whose units are a group derived from a monocyclic aromatic hydrocarbon, a group derived from a monocyclic heterocyclic compound or the combination thereof, or an organic residue composed of 2 to 10 five-membered or six-membered rings, both of the residues having at least one side chain and X 1 , X 2 and X 3 , the same or different represent a group affording a hydroxyl group upon hydrolysis.
• Drefahl; Ploetner, Chemische Berichte, 1958, vol. 91, p. 1274,1277
  作者：Drefahl、Ploetner

  DOI：——

  日期：——