N-[4-(2,3,4,5,6-pentafluorophenyl)phenyl]-4-phenyl-N-[4-(9-phenylcarbazol-3-yl)phenyl]aniline

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-[4-(2,3,4,5,6-pentafluorophenyl)phenyl]-4-phenyl-N-[4-(9-phenylcarbazol-3-yl)phenyl]aniline
• 化学式: C₄₈H₂₉F₅N₂
• 分子量: 728.764
• InChiKey: VAEGPDKTIFQFSN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.6
• 重原子数：
  55
• 可旋转键数：
  7
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  8.2
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  N-[4-(9-苯基-9H-咔唑-3-基)苯基]-[1,1'-联苯]-4-胺 、 4'-bromo-2,3,4,5,6-pentafluorobiphenyl 在 tris(dibenzylideneacetone)dipalladium(0) chloroform complex 、 三叔丁基膦 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 反应 8.0h， 以50%的产率得到N-[4-(2,3,4,5,6-pentafluorophenyl)phenyl]-4-phenyl-N-[4-(9-phenylcarbazol-3-yl)phenyl]aniline
  参考文献：
  名称：

  Amine derivative, organic electroluminescence material having the same and organic electroluminescence device using the material

  摘要：

  以下为化学式1中的化合物（1），其中Ar1和Ar2分别独立表示取代或未取代的芳基或取代或未取代的杂环芳基，L表示取代或未取代的芳撑基或取代或未取代的杂环芳撑基，R1和R2分别独立表示氢原子、取代或未取代的烷基、取代或未取代的烷氧基、取代或未取代的芳基或取代或未取代的杂环芳基，a是满足0≤a≤3的整数，并且Ar1和Ar2中至少有一个取代了至少一个氟原子。

  公开号：

  US09502661B2

文献信息

• AMINE DERIVATIVE, ORGANIC ELECTROLUMINESCENCE MATERIAL HAVING THE SAME AND ORGANIC ELECTROLUMINESCENCE DEVICE USING THE MATERIAL
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US20140151667A1

  公开（公告）日：2014-06-05

  An amine derivative including a fluorine substituted aryl group is represented by compound (1) of the following Formula 1. wherein, each of Ar1 and Ar2 independently represents a substituted or unsubstituted aryl group or a substituted or unsubstituted heteroaryl group, L is a substituted or unsubstituted arylene group or a substituted or unsubstituted heteroarylene group, each of R1 and R2 independently represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted heteroaryl group, a is an integer satisfying 0≦a≦3, and at least one of Ar1 and Ar2 is substituted with at least one fluorine atom.
• US9502661B2
  申请人：——

  公开号：US9502661B2

  公开（公告）日：2016-11-22
• Amine derivative, organic electroluminescence material having the same and organic electroluminescence device using the material
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US09502661B2

  公开（公告）日：2016-11-22

  An amine derivative including a fluorine substituted aryl group is represented by compound (1) of the following Formula 1. wherein, each of Ar1 and Ar2 independently represents a substituted or unsubstituted aryl group or a substituted or unsubstituted heteroaryl group, L is a substituted or unsubstituted arylene group or a substituted or unsubstituted heteroarylene group, each of R1 and R2 independently represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted heteroaryl group, a is an integer satisfying 0≦a≦3, and at least one of Ar1 and Ar2 is substituted with at least one fluorine atom.

  以下为化学式1中的化合物（1），其中Ar1和Ar2分别独立表示取代或未取代的芳基或取代或未取代的杂环芳基，L表示取代或未取代的芳撑基或取代或未取代的杂环芳撑基，R1和R2分别独立表示氢原子、取代或未取代的烷基、取代或未取代的烷氧基、取代或未取代的芳基或取代或未取代的杂环芳基，a是满足0≤a≤3的整数，并且Ar1和Ar2中至少有一个取代了至少一个氟原子。