Ethyl-<2-hydroxy-naphthyl-methylen>-amin | 715-56-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: Ethyl-<2-hydroxy-naphthyl-methylen>-amin
• 英文别名: 2-Hydroxy-naphthaldehyd-ethylimin；2-Hydroxy-1-ethyliminomethyl-naphthalin；2-Hydroxy-1-naphthyliden-ethylamin；N-<2-Hydroxy-naphthyliden-(1)>-ethylamin；(2-hydroxy-1-naphthylmethylene)ethylamine；1-(Aethylimino-methyl)-[2]naphthol；2-Hydroxy-naphthaldehyd-aethylimin；1-(ethylimino-methyl)-[2]naphthol；1-[(Ethylimino)methyl]-2-naphthalenol；1-(ethyliminomethyl)naphthalen-2-ol
• CAS: 715-56-0
• 化学式: C₁₃H₁₃NO
• 分子量: 199.252
• InChiKey: HPTRMLDYMAIMCF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.15
• 拓扑面积：
  32.6
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  Ethyl-<2-hydroxy-naphthyl-methylen>-amin 在 NH₄ vanadate 作用下， 以 乙醇 为溶剂， 生成 oxo bis-((2-hydroxonaphthyl 1-methylene) ethylamine) vanadium (IV)
  参考文献：
  名称：

  Gusev, S. I.; Kumov, V. I.; Sokolova, E. V., Zhurnal Analiticheskoi Khimii, 1960, vol. 15, p. 205 - 208

  摘要：

  DOI：
• 作为产物：
  描述：

  乙胺 、 2-羟基-1-萘甲醛 生成 Ethyl-<2-hydroxy-naphthyl-methylen>-amin
  参考文献：
  名称：

  1-(bicyclic carbocyclic aryl)-2-(monocyclic carbocyclic aryl) ethylamines

  摘要：

  公开号：

  US02711428A1

文献信息

• Coupling Reactions of <i>N</i>-Propargyl Semi-Salen Compounds Induced by Ruthenium Complex
  作者：Hsin-Tzu Hsu、Fu-Yuan Tsai、Ying-Chih Lin、Yi-Hong Liu

  DOI：10.1021/om500268x

  日期：2014.7.14

  The coupling reaction of N-propargyl semi-salen compound 1d on [Ru]-Cl ([Ru] = Cp(PPh3)2Ru) generates the carbene complex 3d containing a substituted 2H-chromene unit in 7 d. The precursor vinylidene complex 2d is isolated from the reaction of the propargyl group of 1d with [Ru]-Cl in 12 h. Addition of an o-cresol moiety to Cα and Cβ of the vinylidene ligand of 2d takes place in a longer reaction time

  的偶联反应Ñ -propargyl半沙仑化合物1D上的[Ru] -Cl（的[Ru] = CP（PPH 3）2 Ru）的生成卡宾络合物3D含有取代的2- ħ色烯单元在7 d。该前体亚乙烯基复合2D从炔丙基的反应中分离1D用的[Ru] -Cl中12小时。一个的加成ö甲酚部分到的偏二配体的Cα和Cβ 2d中在更长的反应时间发生，以产生3D。的[Ru] -Cl的反应与其它类似化合物1A，1B，和1C通过类似的偶联过程，在48小时内，过量地，也分别提供了卡宾络合物3a，3b和3c。在12小时内还观察到了它们的前体亚乙烯基配合物2a，2b和2c。2和3的结构是根据光谱数据确定的。通过X射线衍射分析进一步证实了dppe类似物3a'的固态结构。添加的邻甲酚部分来自化合物1，而不是醛，这是通过2和1的交叉偶联反应确定的使用质谱法。为了比较，用保留炔丙基和苯酚部分的胺类似物13b处理[Ru] Cl没有产生偶联产物。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: U: SVol.E2, 1.7.5, page 60 - 104
  作者：

  DOI：——

  日期：——
• Structures and properties of di-μ-oxo dimanganese(IV) complexes with bidentate Schiff bases, N-alkyl-substituted-salicylideneamine
  作者：Hitoshi Torayama、Hideyuki Asada、Manabu Fujiwara、Takayuki Matsushita

  DOI：10.1016/s0277-5387(98)00144-2

  日期：1998.11

  Novel di-mu-oxo dimanganese(IV) complexes, [Mn-IV(N-R-X-sal)(2)(mu-O)](2), with bidentate Schiff base ligands, N-alkyl-substituted-salicylideneamine, N-R-X-salH [R= CH3(Me), C2H5 (Et), n-C3H, (Pr), n-C4H9 (Bu), n-C6H13 (Hx), n-C8H17 (Oct), II-C10H21 (Dec), n-C12H25 (Dod), or n-C18H37 (Octd) and X = H or 5,6-benzo]: have been prepared by their reaction with potassium permanganate (KMnO4) in MeCN, while stirring at room temperature. These complexes were characterized by spectroscopy, magnetic susceptibility, thermal analysis and X-ray crystallography. The structures consist of a Mn-2(IV)(mu-O)(2) core with a Mn-Mn separation of 2.731 (4) Angstrom for [Mn-IV(N-Me-sal)(2)(mu-O)](2), 1, 2.769(2) Angstrom for [Mn-2(IV)(N-Et-sal)(2)(mu-O)](2), 2, 2.780(2) Angstrom for [(Mn-IV-Hx-sal)(2)(mu-O)](2), 5, 2.780(2)Angstrom for [Mn-IV(N-Dec-sal)(2)(mu-O)](2), 7, and 2.756(3) Angstrom for [Mn-IV(N-Me-5,6-benzo-sal)(2)(mu-O)](2), 10. The complex 1 is the first di-mu-oxo dimanganese(IV) complex having asymmetrical form in which two manganese ions adopt different configurations each other. Moreover, the complexes 5 and 7 are found to exhibit the longest one among all of the Mn-Mn separation observed for the structurally characterized Mn-2(mu-O)(2) complexes prior to this work. The antiferromagnetic exchange interaction has been found to be J= -83 and -188 cm(-1) for 1 and 7, respectively. (C) 1998 Elsevier Science Ltd. All rights reserved.
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: V: MVol.B2, 185, page 764 - 766
  作者：

  DOI：——

  日期：——
• Kazitsyna,L.A. et al., Journal of general chemistry of the USSR, 1961, vol. 31, p. 286 - 294
  作者：Kazitsyna,L.A. et al.

  DOI：——

  日期：——