3,3'-spirobichroman | 178-23-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并吡喃
• 英文名称: 3,3'-spirobichroman
• 英文别名: 3,3'-spirobi[2,4-dihydrochromene]
• CAS: 178-23-4
• 化学式: C₁₇H₁₆O₂
• 分子量: 252.313
• InChiKey: UZODKQUUGXTBGF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  19
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-氟溴苄 在 (η⁵-ethyltetramethylcyclopentadienyl)(η⁶-benzene)rhodium(III) hexafluorophosphate lithium aluminium tetrahydride 、 sodium ethanolate 作用下， 以 乙醚 、 乙醇 为溶剂， 反应 17.0h， 生成 3,3'-spirobichroman
  参考文献：
  名称：

  Houghton, Roy P.; Voyle, Martyn; Price, Raymond, Journal of the Chemical Society. Perkin transactions I, 1984, # 5, p. 925 - 931

  摘要：

  DOI：

文献信息

• Intramolecular nucleophilic substitutions of co-ordinated aryl halides. A preparation of chromans
  作者：Roy P. Houghton、Martyn Voyle、Raymond Price

  DOI：10.1039/c39800000884

  日期：——

  3-(o-Fluorophenyl)propan-1-ol can be cyclised readily to chroman either through chromium tricarbonyl complexes or (as also with substituted fluorophenylpropanols) by the action of the (η6-benzene)(η5-ethyltetramethylcyclopentadienyl)rhodium(III) cation.

  3-（ø氟苯基）丙-1-醇可以容易地或者通过三羰基铬络合物或通过的作用环化成苯并二氢吡喃（如也与取代fluorophenylpropanols）的（η 6 -苯）（η 5 -ethyltetramethylcyclopentadienyl）铑（ III）阳离子。
• HOUGHTON R. P.; VOYLE M.; PRICE R., J. CHEM. SOC. CHEM. COMMUN., 1980, NO 18, 884-885
  作者：HOUGHTON R. P.、 VOYLE M.、 PRICE R.

  DOI：——

  日期：——
• RETARDATION FILM, METHOD FOR PRODUCING RETARDATION FILM, POLARIZING PLATE AND LIQUID CRYSTAL DISPLAY
  申请人：Yamada Rumiko

  公开号：US20090169772A1

  公开（公告）日：2009-07-02

  Disclosed are a retardation film, a method for producing the retardation film, a polarizing plate comprising the retardation film, and a liquid crystal display comprising the polarizing plate. Specifically disclosed is a method for producing a retardation film, which comprises an extrusion step for extruding a composition containing a thermoplastic resin and having a temperature of To [° C.] from a die; a cooling step for cooling a film extruded from the die and having a glass transition temperature of Tg [° C.] to a temperature Ta [° C.]; a heating step for heating the cooled film to a temperature Tb [° C.] at least once; and a stretching step for cooling the heated film to a temperature Tc [° C.] and then stretching the cooled film in the width direction.