(sodium)3 | 943598-98-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: (sodium)3
• 英文别名: sodium trimer；sodium
• CAS: 943598-98-9
• 化学式: Na₃
• 分子量: 68.9693
• InChiKey: YEDTWOLJNQYBPU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  sodium 以 gaseous matrix 为溶剂， 生成 (sodium)3
  参考文献：
  名称：

  Photodepletion spectroscopy and predissociation of the Na3 A′(′) state

  摘要：

  The A'((2)A'(1)) <-- X(E-2') system of the sodium trimer Na-3 was studied by photodepletion in a supersonic molecular beam, in which the ion signal of Na-3(+) generated by one-photon ionization of Na-3 ((XE)-E-2') with an excimer laser decreased when an excimer-pumped dye laser was also applied prior to the ionizing laser to excite the neutral Na-3 from the (XE)-E-2' ground state to the A' state. Photodepletion spectra were recorded in the wavelength range 700-780 nm with a spectral resolution of 7.5 GHz of the pulsed dye Iaser. The strongest depletion was found at wavelengths around 740 nm with a measured depletion cross-section of about 1.2 Angstrom(2). Structures with typical widths between 10 and 30 cm(-1) were observed in the photodepletion spectra and are attributed to vibronic bands in the A' state. (C) 1999 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0009-2614(99)00002-0

文献信息

• Laser-induced excitation and photodissociation of potassium and mixed potassium-sodium (1.5%) clusters: diverse formation and relaxation processes and bounds on alkali trimer (M-M2) bond energies from LIAF
  作者：J. S. Hayden、R. Woodward、James L. Gole

  DOI：10.1021/j100400a013

  日期：1986.4
• Spectroscopy of vibrational ground-state levels of sodium molecule (Na3)
  作者：M. Broyer、G. Delacretaz、P. Labastie、J. P. Wolf、L. Woeste

  DOI：10.1021/j100294a033

  日期：1987.5