PROCESS FOR PRODUCING POLYURETHANE EMULSION FOR WATER-BASED ONE-PACK TYPE COATING MATERIAL
申请人:Nippon Polyurethane Industry Co., Ltd.
公开号:EP1721947A1
公开(公告)日:2006-11-15
[PROBLEMS] The invention is to provide an aqueous one-component coating agent that is environmentally friendly and safe, and is excellent in productivity and storage stability, and also in alkali resistance and solvent resistance of a coated film.
[MEANS FOR SOLVING PROBLEMS] The problems are solved by providing a method for producing polyurethane emulsion for an aqueous one-component coating agent, comprising: reacting an organic diisocyanate (a1), a high molecular weight polyol (a2) and a low molecular weight glycol containing a carboxyl group (a3) to produce an isocyanate-terminated urethane prepolymer having a carboxyl group (A); mixing the urethane prepolymer (A) with a polyisocyanate containing a nonionic polar group (B); neutralizing the carboxyl group in the system with a neutralizing agent (C); and subjecting the mixture to emulsification in water and chain extension with water or an amine.
[问题] 本发明旨在提供一种单组分水性涂布剂,该涂布剂环保、安全、生产效率高、储 存稳定性好、涂膜耐碱性和耐溶剂性好。
[解决问题的方法] 为了解决上述问题,我们提供了一种生产单组分水性涂料用聚氨酯乳液的方法,该方法包括: 1:使有机二异氰酸酯(a1)、高分子量多元醇(a2)和含有羧基的低分子量乙二醇 (a3)反应,生成具有羧基(A)的异氰酸酯封端聚氨酯预聚物;将聚氨酯预聚物 (A) 与含有非离子极性基团的多异氰酸酯 (B) 混合;用中和剂 (C) 中和体系中的羧基;以及将混合物在水中乳化,并用水或胺进行扩链。