4-Allyl-[1]naphthol | 133956-40-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 4-Allyl-[1]naphthol
• 英文别名: 4-Allyl-1-naphthol；4-prop-2-enylnaphthalen-1-ol
• CAS: 133956-40-8
• 化学式: C₁₃H₁₂O
• 分子量: 184.238
• InChiKey: GAZRRSBRGUXREF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  甲基-1-羟基-2-萘甲酸盐 在 甲醇 、 氢氧化钾 、 potassium carbonate 、 丙酮 作用下， 生成 4-Allyl-[1]naphthol
  参考文献：
  名称：

  THE VON AUWERS REARRANGEMENT IN THE NAPHTHALENE SERIES

  摘要：

  DOI：

  10.1021/jo01136a021

文献信息

• Water‐Accelerated Claisen Rearrangements
  作者：Peter Wipf、Sonia Rodríguez

  DOI：10.1002/1615-4169(200206)344:3/4<434::aid-adsc434>3.0.co;2-#

  日期：2002.6

  Allyl aryl ethers undergo accelerated Claisen and [1,3] rearrangements in the presence of a mixture of trialkylalanes and water or aluminoxanes. The ratio of ortho-, meta-, and para-Claisen products depends to a large extent on the presence of water and to a much lesser extent on the nature of the alane.

  在三烷基丙烷和水或铝氧烷的混合物存在下，烯丙基芳基醚经历加速的克莱森和 [1,3] 重排。邻位、间位和对位克莱森产物的比例在很大程度上取决于水的存在，而在较小程度上取决于铝烷的性质。
• Polyphosphazene process
  申请人：ETHYL CORPORATION

  公开号：EP0159020A2

  公开（公告）日：1985-10-23

  A process for making an alkali metal alkoxide (e.g. sodium alkoxide) of a halogen-substituted alcohol (e.g. fluorine-substituted alcohols) by dispersing an alkali metal (e.g. sodium) in a cycloalkane (e.g. cyclohexane) or a cycloalkane containing a phenol (e.g., o-allylphenol) and adding the resultant dispersion to an ether (e.g. THF) solution of a halogen-substituted alcohol. The resultant alkali metal haloalkoxide solution, or alkali metal haloalkoxide solution containing phenoxides, can be reacted with a phosphotnitrilic chloride polymer to introduce haloalkoxide substituents or haloalkoxide and phenoxide substituents.

  将碱金属（如钠）分散于环烷烃（如环己烷）或含有苯酚（如邻烯丙基苯酚）的环烷烃中，然后将分散液加入卤代醇的乙醚（如四氢呋喃）溶液中，制成卤代醇（如氟代醇）的碱金属碱氧化物（如碱氧化钠）的工艺。 所得碱金属卤氧化物溶液或含有苯氧基的碱金属卤氧化物溶液可与磷硝酰氯聚合物反应，以引入卤代醇取代基或卤代醇和苯氧基取代基。
• PROCESS FOR PRODUCING VINYL POLYMER HAVING ALKENYL GROUP AT END, VINYL POLYMER, AND CURABLE COMPOSITION
  申请人：KANEKA CORPORATION

  公开号：EP1375531A1

  公开（公告）日：2004-01-02

  Objects of the present invention are to provide a process for easily producing an alkenyl-terminated vinyl polymer without using a metal compound requiring a complicated purification step, and to provide a curable composition containing the vinyl polymer. An alkenyl group is incorporated into an end of a vinyl polymer having a thiocarbonylthio structure at the end to produce an alkenyl-terminated vinyl polymer. Mixing this vinyl polymer with a compound having a hydrogen-silicon bond and a hydrosilylation catalyst gives the curable composition.

  本发明的目的是提供一种无需使用需要复杂纯化步骤的金属化合物即可轻松生产烯基封端的乙烯基聚合物的工艺，并提供一种含有该乙烯基聚合物的可固化组合物。 在端部具有硫代羰基硫结构的乙烯基聚合物的端部加入烯基，生成烯基封端的乙烯基聚合物。将这种乙烯基聚合物与具有氢硅键的化合物和氢化硅催化剂混合，就得到了可固化组合物。
• CURABLE COMPOSITION
  申请人：KANEKA CORPORATION

  公开号：EP1452550A1

  公开（公告）日：2004-09-01

  The present invention provides a curable composition that comprises a polymer (A) containing a cross-linkable silyl group and a condensation catalyst (B). The polymer (A) containing a cross-linkable silyl group is obtained by a process comprising the steps of conducting a radical polymerizable monomer in the presence of a thiocarbonylthio compound. For example, the polymer (A) is obtained by (i) initiating a reversible addition-fragmentation chain transfer polymerization of a radical polymerizable monomer in the presence of a thiocarbonylthio compound, and (ii) adding an unsaturated compound containing a cross-linkable silyl group for copolymerization when a consumed amount of the radical polymerizable monomer by the polymerization has reached a level of 80% or more.

  本发明提供了一种可固化组合物，它包括含有可交联硅基的聚合物（A）和缩合催化剂（B）。含有可交联硅烷基的聚合物(A)是通过在硫代羰基硫代化合物存在下进行自由基聚合单体的步骤得到的。例如，聚合物(A)是通过以下方法获得的：(i) 在硫代羰基硫代化合物存在下，启动可自由基聚合单体的可逆加成-断裂链转移聚合；(ii) 当聚合消耗的可自由基聚合单体量达到 80% 或以上时，加入含有可交联硅烷基的不饱和化合物进行共聚。
• Process for producing vinyl polymer having alkenyl group at end vinyl polymer and curable composition
  申请人：——

  公开号：US20040097678A1

  公开（公告）日：2004-05-20

  Objects of the present invention are to provide a process for easily producing an alkenyl-terminated vinyl polymer without using a metal compound requiring a complicated purification step, and to provide a curable composition containing the vinyl polymer. An alkenyl group is incorporated into an end of a vinyl polymer having a thiocarbonylthio structure at the end to produce an alkenyl-terminated vinyl polymer. Mixing this vinyl polymer with a compound having a hydrogen-silicon bond and a hydrosilylation catalyst gives the curable composition.

  本发明的目的是提供一种无需使用需要复杂纯化步骤的金属化合物即可轻松生产烯基封端的乙烯基聚合物的工艺，并提供一种含有该乙烯基聚合物的可固化组合物。 在端部具有硫代羰基硫结构的乙烯基聚合物的端部加入烯基，生成烯基封端的乙烯基聚合物。 将这种乙烯基聚合物与具有氢硅键的化合物和氢化硅催化剂混合，就得到了可固化组合物。