[3-(3H-Inden-1-yl)-propoxy]-trimethyl-silane | 878553-00-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 茚和异茚
• 英文名称: [3-(3H-Inden-1-yl)-propoxy]-trimethyl-silane
• 英文别名: 3-(3-Trimethylsiloxypropyl)indene；3-(3H-inden-1-yl)propoxy-trimethylsilane
• CAS: 878553-00-5
• 化学式: C₁₅H₂₂OSi
• 分子量: 246.425
• InChiKey: FHVSYXMCPGGMLY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.26
• 重原子数：
  17
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.47
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  [3-(3H-Inden-1-yl)-propoxy]-trimethyl-silane 在 正丁基锂 作用下， 以 乙醚 、 正己烷 为溶剂， 生成 1-[Dimethyl-(2,3,4,5-tetramethyl-cyclopenta-2,4-dienyl)-silanyl]-3-(3-trimethylsilanyloxy-propyl)-1H-indene
  参考文献：
  名称：

  新型茚基锆配合物在乙烯聚合中作为负载催化剂

  摘要：

  一系列取代茚{C 9 H 7 R-3 [R = CH 2 CH 2 CH 2 O-SiMe 3 (1), CH 2 CH 2 CH 2 OCH 2 C 6 H 5 (2), CH 2 CH 2 CH 2 OSiMe 2 -tBu (3)]}、茚化合物{Me 2 Si(C 9 H 6 R-3) 2 -1 [R = CH 2 CH 2 CH 2 OSiMe 3 (4)]、Me 2 Si(C 9 H 6 R-3)-1(C 5 HMe 4 ) [R = CH 2 CH 2 CH 2 OSiMe 3 (5), CH 2 CH 2 CH 2 OCH 2 C 6 H 5 (6), CH 2 CH=CH 2 (7), CH 2 CH 2 CH 2 OSiMe 2 tBu (8)]} 已制备。1-8 的锂衍生物用于合成茚基锆配合物 [Zr(η 5 -C 9 H 6 R-1) 2 Cl 2 ] [R = CH

  DOI：

  10.1002/ejic.200500165
• 作为产物：
  描述：

  (3-bromopropoxy)trimethylsilane 、 inden-1-yl lithium 以 乙醚 为溶剂， 以80%的产率得到[3-(3H-Inden-1-yl)-propoxy]-trimethyl-silane
  参考文献：
  名称：

  新型茚基锆配合物在乙烯聚合中作为负载催化剂

  摘要：

  一系列取代茚{C 9 H 7 R-3 [R = CH 2 CH 2 CH 2 O-SiMe 3 (1), CH 2 CH 2 CH 2 OCH 2 C 6 H 5 (2), CH 2 CH 2 CH 2 OSiMe 2 -tBu (3)]}、茚化合物{Me 2 Si(C 9 H 6 R-3) 2 -1 [R = CH 2 CH 2 CH 2 OSiMe 3 (4)]、Me 2 Si(C 9 H 6 R-3)-1(C 5 HMe 4 ) [R = CH 2 CH 2 CH 2 OSiMe 3 (5), CH 2 CH 2 CH 2 OCH 2 C 6 H 5 (6), CH 2 CH=CH 2 (7), CH 2 CH 2 CH 2 OSiMe 2 tBu (8)]} 已制备。1-8 的锂衍生物用于合成茚基锆配合物 [Zr(η 5 -C 9 H 6 R-1) 2 Cl 2 ] [R = CH

  DOI：

  10.1002/ejic.200500165

文献信息

• CATALYTIC SYSTEMS FOR THE POLYMERIZATION AND COPOLYMERIZATION OF ALPHA-OLEFINS
  申请人：——

  公开号：US20030191013A1

  公开（公告）日：2003-10-09

  The invention relates to heterogeneous catalytic systems obtainable by reacting a porous inorganic support with an alumoxane and subsequently supporting at least one metallocene compound thereon, characterized in that the metallocene compound is defined by the following general formulas: 1 wherein: L, equal to or different from each other, is selected from the group comprising: cyclopentadienyl, indenyl, tetrahydroindenyl, fluorenyl, octahydrofluorenyl or benzoindenyl; each R is independently selected from hydrogen, C 1 -C 20 alkyl, C 3 -C 20 cycloalkyl, C 6 -C 20 aryl, C 3 -C 20 alkenyl, C 7 -C 20 arylalkyl, C 7 -C 20 alkylaryl, C 8 -C 20 arylalkenyl, linear or branched, optionally substituted by 1 to 10 halogen atoms, or a group SiR II 3 ; each R I , equal to or different from each other, is a divalent aliphatic or aromatic hydrocarbon group containing from 1 to 20 carbon atoms, optionally containing from 1 to 5 heteroatoms of groups 14 to 16 of the periodic table of the elements and boron ; preferably it is: C 1 -C 20 alkylene, C 3 -C 20 cycloalkylene, C 6 -C 20 arylene, C 7 -C 20 alkenyl, C 7 -C 20 arylalkylene, or alkylarylene, linear or branched, or a group SiR II 2 ; each R II is independently selected from C 1 -C 20 alkyl , C 3 -C 20 cycloalkyl, C 6 -C 20 aryl, C 3 -C 20 alkenyl, C 7 -C 20 arylalkyl, C 8 -C 20 arylalkenyl or C 7 -C 20 alkylaryl, linear or branched; preferably R II is methyl, ethyl, isopropyl; each Q is independently selected from B, C, Si, Ge, Sn; M is a metal of group 3, 4 or 10 of the Periodic Table, Lanthanide or Actinide; preferably it is titanium, zirconium or hafnium; each X is independently selected from: hydrogen, chlorine, bromine, OR II , NR II 2 , C 1 -C 20 alkyl or C 6 -C 20 aryl; L′ is N or O; z is equal to 0, 1 or 2; x is equal to 1, 2 or 3; y is equal to 1, 2 or 3; x+y+z is equal to the valence of M; m is an integer which can assume the values 1, 2, 3 or 4; a and b are integers whose value ranges from 0 to k−1; f is an integer whose value ranges from 1 to k; g is an integer whose value ranges from 0 to 1; c and e are equal to 0 or 1; a+b+c is at least 1; a+g+c is at least 1; d is equal to 0, 1 or 2; when Q is B then c+d=1; when Q is C, Si, Ge or Sn, then c+d=2; when L′ is N, then g+e=1; when L′ is O, then g=0 and e=0. The invention also relates to the polymerization process making use of the above defined catalytic

  本发明涉及通过将多孔无机支撑物与铝氧烷反应，随后在其上支撑至少一种金属茂化合物而获得的异质催化系统，其特征在于所述金属茂化合物由以下一般式定义：其中，L，相同或不同，选自包括：环戊二烯基、茚基、四氢茚基、芴基、八氢芴基或苯并茚基的群体；每个R独立地选自氢、C1-C20烷基、C3-C20环烷基、C6-C20芳基、C3-C20烯基、C7-C20芳基烷基、C7-C20烷基芳基、C8-C20芳基烯基，线性或支链，可选地被1到10个卤素原子取代，或SiRII3基团；每个RI，相同或不同，是含有1到20个碳原子的二价脂肪族或芳香族碳氢基团，可选地含有周期表14到16族和硼的1到5个杂原子；优选为：C1-C20烷基、C3-C20环烷基、C6-C20芳基、C7-C20烯基芳基烷基或烷基芳基烷基，线性或支链，或SiRII2基团；每个RII独立地选自C1-C20烷基、C3-C20环烷基、C6-C20芳基、C3-C20烯基、C7-C20芳基烷基、C8-C20芳基烯基或C7-C20烷基芳基，线性或支链；优选RII为甲基、乙基、异丙基；每个Q独立地选自B、C、Si、Ge、Sn；M为周期表3、4或10族、镧系或锕系金属；优选为钛、锆或铪；每个X独立地选自：氢、氯、溴、ORII、NRII2、C1-C20烷基或C6-C20芳基；L'为N或O；z等于0、1或2；x等于1、2或3；y等于1、2或3；x+y+z等于M的价；m是可以取值为1、2、3或4的整数；a和b是值范围从0到k-1的整数；f是值范围从1到k的整数；g是值范围从0到1的整数；c和e等于0或1；a+b+c至少为1；a+g+c至少为1；d等于0、1或2；当Q为B时，则c+d=1；当Q为C、Si、Ge或Sn时，则c+d=2；当L'为N时，则g+e=1；当L'为O时，则g=0且e=0。本发明还涉及利用上述定义的催化剂进行聚合的过程。
• Catalytic systems for the polymerization and copolymerization of alpha-olefins
  申请人：Repsol Quimica, S.A.

  公开号：US07148173B2

  公开（公告）日：2006-12-12

  Heterogeneous catalytic compositions obtained by reacting a porous inorganic support with an alumoxane and subsequently supporting at least one metallocene compound thereon. A process for polymerization of α-olefins in a slurry or in a gas phase, the process catalyzed by such heterogeneous catalytic compositions.

  通过将多孔无机支撑物与氧化铝烷反应，然后在其上支撑至少一种金属茂化合物而获得的异质催化组合物。一种在悬浮液或气相中聚合α-烯烃的过程，该过程由这种异质催化组合物催化。
• Novel Indenylzirconium Complexes as Supported Catalysts in the Polymerization of Ethylene
  作者：Carlos Alonso‐Moreno、Antonio Antiñolo、Fernando Carrillo‐Hermosilla、Pedro Carrión、Isabel López‐Solera、Antonio Otero、Sanjiv Prashar、José Sancho

  DOI：10.1002/ejic.200500165

  日期：2005.7

  substituted indene C 9 H 7 R-3 [R = CH 2 CH 2 CH 2 O-SiMe 3 (1), CH 2 CH 2 CH 2 OCH 2 C 6 H 5 (2), CH 2 CH 2 CH 2 OSiMe 2 -tBu (3)]}, and ansa-indene compounds Me 2 Si(C 9 H 6 R-3) 2 -1 [R = CH 2 CH 2 CH 2 OSiMe 3 (4)], Me 2 Si(C 9 H 6 R-3)-1(C 5 HMe 4 ) [R = CH 2 CH 2 CH 2 OSiMe 3 (5), CH 2 CH 2 CH 2 OCH 2 C 6 H 5 (6), CH 2 CH=CH 2 (7), CH 2 CH 2 CH 2 OSiMe 2 tBu (8)]} have been prepared. The lithium

  一系列取代茚C 9 H 7 R-3 [R = CH 2 CH 2 CH 2 O-SiMe 3 (1), CH 2 CH 2 CH 2 OCH 2 C 6 H 5 (2), CH 2 CH 2 CH 2 OSiMe 2 -tBu (3)]}、茚化合物Me 2 Si(C 9 H 6 R-3) 2 -1 [R = CH 2 CH 2 CH 2 OSiMe 3 (4)]、Me 2 Si(C 9 H 6 R-3)-1(C 5 HMe 4 ) [R = CH 2 CH 2 CH 2 OSiMe 3 (5), CH 2 CH 2 CH 2 OCH 2 C 6 H 5 (6), CH 2 CH=CH 2 (7), CH 2 CH 2 CH 2 OSiMe 2 tBu (8)]} 已制备。1-8 的锂衍生物用于合成茚基锆配合物 [Zr(η 5 -C 9 H 6 R-1) 2 Cl 2 ] [R = CH