N-propionyl-1-hydroxy-2-naphthoylhydrazide | 1254074-14-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: N-propionyl-1-hydroxy-2-naphthoylhydrazide
• CAS: 1254074-14-0
• 化学式: C₁₄H₁₄N₂O₃
• 分子量: 258.277
• InChiKey: HVKGBGDTGOLMLB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.72
• 重原子数：
  19.0
• 可旋转键数：
  2.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  78.43
• 氢给体数：
  3.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  吡啶 、 N-propionyl-1-hydroxy-2-naphthoylhydrazide 、 nickel(II) acetate tetrahydrate 以 吡啶 为溶剂， 以75%的产率得到[Ni(II)3(N-propionyl-1-hydroxy-2-naphthoylhydrazide)2(pyridine)4]
  参考文献：
  名称：

  Metal coordination architectures of N-propionyl-1-hydroxy-2-naphthoylhydrazide: From metalladiazamacrocycles to trinuclear complexes

  摘要：

  Two metalladiazamacrocycles, 24-membered octanuclear [Mn-8(pnhz)(8)(DMF)(5)(MeOH)(3)]DMF 3.5MeOH (1) and 18-membered hexanuclear [Fe-6(pnhz)(6)(DMF)(6)] (2), and two linear trinuclear complexes, [Cu-3(pnhz)(2)(Py)(6)] 2Py (3) and [Ni-3(pnhz)(2)(Py)(4)] (4), have been synthesized based on a trianionic pentadentate bridging ligand N-propionyl-1-hydroxy-2-naphthoylhydrazide (H(3)pnhz). The complexes are characterized by elemental analysis, IR, UV-vis spectroscopy and single-crystal X-ray diffraction. The nature of metal ions and steric effect of N-propionyl-1-hydroxy-2-naphthoylhydrazide ligand play key roles in the formation of complexes with different nuclearity. Complexes 1,2 and 3 exhibit antiferromagnetic coupling interactions between the metal centers. (C) 2010 Elsevier Inc. All rights reserved.

  DOI：

  10.1016/j.jssc.2010.07.021