N,N'-diphenyl-N'-di(m-tolyl)benzidine | 184104-81-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N'-diphenyl-N'-di(m-tolyl)benzidine
• 英文别名: N-[4-(4-anilinophenyl)phenyl]-3-methyl-N-phenylaniline
• CAS: 184104-81-2
• 化学式: C₃₁H₂₆N₂
• 分子量: 426.561
• InChiKey: HUDPZCBEKKXUMD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.7
• 重原子数：
  33
• 可旋转键数：
  6
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.03
• 拓扑面积：
  15.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N,N'-diphenyl-N'-di(m-tolyl)benzidine 在 18-冠醚-6 铜 、 potassium carbonate 作用下， 以 xylene 为溶剂， 反应 80.0h， 生成 C₉₃H₇₃N₅
  参考文献：
  名称：

  Novel hole-transporting materials based on triphenylamine for organic electroluminescent devices

  摘要：

  合成了具有高玻璃化转变温度的低聚三苯胺，可用于热稳定有机电致发光器件。

  DOI：

  10.1039/cc9960002175
• 作为产物：
  描述：

  间碘甲苯 、 N,N'-二苯基联苯二胺 在 18-冠醚-6 铜 、 potassium carbonate 作用下， 以 xylene 为溶剂， 反应 40.0h， 以16%的产率得到N,N'-diphenyl-N'-di(m-tolyl)benzidine
  参考文献：
  名称：

  Novel hole-transporting materials based on triphenylamine for organic electroluminescent devices

  摘要：

  合成了具有高玻璃化转变温度的低聚三苯胺，可用于热稳定有机电致发光器件。

  DOI：

  10.1039/cc9960002175

文献信息

• Solvents containing cycloakyl alkyl ethers and process for production of the ethers
  申请人：Kin Idan

  公开号：US20050065060A1

  公开（公告）日：2005-03-24

  The present inventions are (A) a solvent comprising at least one cycloalkyl alkyl ether (1) represented by the general formula: R1-O-R2 (wherein R1 is cyclopentyl or the like; and R2 is C1-10 alkyl or the like); (B) a method of preparations the ethers (1) characterized by reacting an alicyclic olefin with an alcohol in the presence of an acid ion-exchange resin having a water content of 5 wt % or less. The solvent is useful as cleaning solvent for electronic components, precision machinery components or the like, reaction solvent using various chemical reactions, extraction solvent for extracting objective organic substances, solvent or remover for electronic and electrical materials, and so on. The process enables industrially advantageous production of the objective cycloalkyl alkyl ethers (1).

  本发明涉及(A)一种溶剂，其包括至少一种环烷基烷醚(1)，其通式为R1-O-R2(其中R1为环戊基或类似物；R2为C1-10烷基或类似物)；(B)一种制备醚(1)的方法，其特征在于在酸性离子交换树脂的存在下，用醇反应环状烯烃，其水含量为5重量％或以下。该溶剂可用作电子元件、精密机械元件等的清洗溶剂，用于各种化学反应的反应溶剂，用于提取目标有机物的萃取溶剂，电子电器材料的溶剂或清除剂等。该过程使得目标环烷基烷醚(1)的工业优势生产成为可能。
• Solvents containing cycloalkyl alkyl ethers and process for production of the ethers
  申请人：Kim Idan

  公开号：US20080312125A1

  公开（公告）日：2008-12-18

  The present inventions are (A) a solvent comprising at least one cycloalkyl alkyl ether (1) represented by the general formula: R1—O—R2 (wherein R1 is cyclopentyl or the like; and R2 is C1-10 alkyl or the like); (B) a method of preparations the ethers (1) characterized by reacting an alicyclic olefin with an alcohol in the presence of an acid ion-exchange resin having a water content of 5 wt % or less. The solvent is useful as cleaning solvent for electronic components, precision machinery components or the like, reaction solvent using various chemical reactions, extraction solvent for extracting objective organic substances, solvent or remover for electronic and electrical materials, and so on. The process enables industrially advantageous production of the objective cycloalkyl alkyl ethers (1).

  本发明涉及（A）至少包含一种环状烷基烷醚（1）的溶剂，该烷醚由通式R1-O-R2表示（其中R1为环戊基或类似物；R2为C1-10烷基或类似物）；（B）一种制备醚（1）的方法，其特征在于在酸性离子交换树脂的存在下，将脂环烯与醇反应制备而成，该酸性离子交换树脂的水含量为5重量％或更低。该溶剂可用作电子元件、精密机械元件等的清洗溶剂，用于各种化学反应的反应溶剂，用于提取目标有机物的萃取溶剂，电子和电气材料的溶剂或去除剂等。该过程使得生产目标环状烷基烷醚（1）具有工业上的优势。
• SOLVENTS CONTAINING CYCLOALKYL ALKYL ETHERS AND PROCESS FOR PRODUCTION OF THE ETHERS
  申请人：Zeon Corporation

  公开号：EP1405840A1

  公开（公告）日：2004-04-07

  The present inventions are (A) a solvent comprising at least one cycloalkyl alkyl ether (1) represented by the general formula: R1-O-R2 (wherein R1 is cyclopentyl or the like; and R2 is C1-10 alkyl or the like); (B) a method of preparations the ethers (1) characterized by reacting an alicyclic olefin with an alcohol in the presence of an acid ion-exchange resin having a water content of 5 wt% or less. The solvent is useful as cleaning solvent for electronic components, precision machinery components or the like, reaction solvent using various chemical reactions, extraction solvent for extracting objective organic substances, solvent or remover for electronic and electrical materials, and so on. The process enables industrially advantageous production of the objective cycloalkyl alkyl ethers (1).

  本发明是(A)一种包含至少一种由通式表示的环烷基烷基醚(1)的溶剂：R1-O-R2（其中 R1 是环戊基或类似物；R2 是 C1-10 烷基或类似物）；(B) 醚 (1) 的制备方法，其特征在于在水含量为 5 wt% 或以下的酸性离子交换树脂存在下，脂环族烯烃与醇发生反应。该溶剂可用作电子元件、精密机械元件等的清洗溶剂、各种化学反应的反应溶剂、萃取客观有机物的萃取溶剂、电子和电气材料的溶剂或去除剂等。该工艺可以生产出具有工业优势的环烷基烷基醚（1）。
• ORGANIC ELECTROLUMINESCENT ELEMENT, AND MANUFACTURING METHOD AND USES THEREFOR
  申请人：Showa Denko K.K.

  公开号：EP2249410A1

  公开（公告）日：2010-11-10

  Organic electroluminescence devices of the invention have excellent luminous efficiency and durability. Uses of the devices are also disclosed. The organic electroluminescence device includes a pair of electrodes and one or more organic layers including an emitting layer between the pair of electrodes, wherein one of the organic layer(s) includes a hole transporting compound having 2 to 10 arylamine structures in the molecule, an electron transporting compound having a structure of Formula (a) below and an emitting compound.

  本发明的有机电致发光器件具有出色的发光效率和耐用性。本发明还公开了该装置的用途。 有机电致发光器件包括一对电极和一个或多个有机层，其中一个或多个有机层包括一对电极之间的发光层，其中一个或多个有机层包括分子中具有 2 至 10 个芳基胺结构的空穴传输化合物、具有下式（a）结构的电子传输化合物和发光化合物。
• Process for producing cycloalkyl alkyl ethers
  申请人：Zeon Corporation

  公开号：EP2279995A2

  公开（公告）日：2011-02-02

  The invention consists in a process for producing a cycloalkyl alkyl ether compound of formula (1): R1-O-R2, wherein R1 represents a cyclopentyl group or cyclohexyl group which may have a substituent and R2 represents an alkyl group having 1 to 10 carbon atoms or a cycloalkyl group having 3 to 8 carbon atoms which may have a substituent; said process comprising reacting an alicyclic olefin with an alcohol in the presence of an acidic ion-exchange resin having a water content of 5 wt.-% or less. Preferably, the process comprises reacting a gaseous alicyclic olefin with a gaseous alcohol in the presence of an acidic ion-exchange resin having a water content of 5 wt.-% or less.

  本发明包括一种生产式（1）环烷基烷基醚化合物的工艺：R1-O-R2，其中 R1 代表可能具有取代基的环戊基或环己基，R2 代表具有 1 至 10 个碳原子的烷基或具有 3 至 8 个碳原子且可能具有取代基的环烷基；所述工艺包括在水含量为 5 wt.-% 或更低的酸性离子交换树脂存在下使脂环族烯烃与醇反应。优选地，该工艺包括在含水量为 5 wt.-% 或以下的酸性离子交换树脂存在下，使气态脂环族烯烃与气态醇反应。