2,2'-di-(2"-[1",10"]phenathrolinyl)-[5,5]spirobifluorylidene | 252878-73-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: 2,2'-di-(2"-[1",10"]phenathrolinyl)-[5,5]spirobifluorylidene
• 英文别名: 2,2'-di(1,10-phenanthrolin-2-yl)-9,9'-spirobifluorene；2-[2'-(1,10-Phenanthrolin-2-yl)-9,9'-spirobi[fluorene]-2-yl]-1,10-phenanthroline
• CAS: 252878-73-2
• 化学式: C₄₉H₂₈N₄
• 分子量: 672.788
• InChiKey: GSTYFTJPZHKHJV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.8
• 重原子数：
  53
• 可旋转键数：
  2
• 环数：
  12.0
• sp3杂化的碳原子比例：
  0.02
• 拓扑面积：
  51.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  六氟磷酸钾 、 cis-dichlorobis(1,10-phenanthroline)ruthenium(II) dihydrate 、 2,2'-di-(2"-[1",10"]phenathrolinyl)-[5,5]spirobifluorylidene 以 乙醇 、 水 、 乙腈 为溶剂， 以52%的产率得到
  参考文献：
  名称：

  围绕螺桥双（菲咯啉）配体构建的单核和双核钌（II）和（II）聚吡啶配合物：合成，电化学和光物理。

  摘要：

  已经合成了两个新的二元组，其中末端Ru（II）和Os（II）多吡啶复合物被空间受限的螺桥隔开。相应的单核络合物的光物理性质表明，通过高能金属居中的激发态，位于金属碎片上的最低能三重态衰减的重要性。在77 K（三重态寿命相对较长）以及基于Os（II）的系统相对于基于Ru（II）的同类系统中，此影响最小。分子内三重态能量转移从基于Ru（II）的片段转移到附加的基于Os（II）的单元，速率常数取决于分子结构和温度。在所有情况下，实验速率常数与为Förster型偶极-偶极能量转移计算的速率常数惊人地匹配。这样，两种化合物显示的不同速率可以归因于立体化学因素。进一步得出的结论是，螺旋桥联单元不支持通过键的电子交换相互作用，这种情况已通过循环伏安法得到证实。

  DOI：

  10.1021/ic0000202
• 作为产物：
  描述：

  2,2'-diacetyl-9,9'-spirobifluorene 、 8-胺基-7-醛基喹啉 在 potassium hydroxide 作用下， 以 乙醇 为溶剂， 反应 5.0h， 以82%的产率得到2,2'-di-(2"-[1",10"]phenathrolinyl)-[5,5]spirobifluorylidene
  参考文献：
  名称：

  2,2'-二(杂芳基)-9,9'-螺二芴的合成与性质

  摘要：

  通过使用 2,2'-二乙酰-9,9'-螺二芴与一系列邻氨基芳烃甲醛的弗里德兰德反应制备了一系列 2,2'-二(杂芳基)-9,9'-螺二芴。化合物 2,2'-di(benzo[b]-1,10-phenanthrolin-2-yl)-9,9'-spirofluorene (4e) 在 374 nm 而 2,2'-di(benzo[h]quinolin-2-yl)-9,9'-spirofluorene (4c), 2,2'-di(1,10-phenanthrolin-2-yl)-9, 9'-螺芴 (4d), 2-(benzo[h]quinolin-2-yl)-2'-(benzo[b]-1,10-phenanthrolin-2-yl)-9,9'-spirofluorene (4g) )，和 2-(1,10-phenanthrolin-2-yl)-2'-(benzo[b]-1,10-phenanthrolin-2-yl)-9

  DOI：

  10.1246/bcsj.20090121

文献信息

• POLYMER ELECTROLYTE COMPOSITION, AND POLYMER ELECTROLYTE MEMBRANE, MEMBRANE ELECTRODE COMPLEX AND SOLID POLYMER-TYPE FUEL CELL EACH PRODUCED USING SAME
  申请人：TORAY INDUSTRIES, INC.

  公开号：US20150295262A1

  公开（公告）日：2015-10-15

  The present invention provides: a polymer electrolyte composition which can achieve excellent proton conductivity under slightly humidified conditions, excellent mechanical strength and excellent physical durability, has excellent practicality, and can be produced using a nitrogen-containing additive, wherein the nitrogen-containing additive can prevent the elution of the additive under a strongly acidic atmosphere during the operation of a fuel cell, has excellent chemical stability so as to tolerate a strongly acidic atmosphere, can be dissolved in various general-purpose organic solvents, has superior processability, can be mixed with an ionic-group-containing polymer, can prevent the occurrence of phase separation during the formation of a film, and can prevent the formation of an island-in-sea-like phase separation structure or the occurrence of bleeding out during the formation of a film; and a polymer electrolyte membrane, a membrane electrode assembly and a polymer electrolyte fuel cell, each of which is produced using the polymer electrolyte composition. The polymer electrolyte composition according to the present invention comprises at least an ionic-group-containing polymer (A) and a nitrogen-containing additive (B), said polymer electrolyte composition being characterized in that the nitrogen-containing additive (B) is represented by a specific structural formula.

  本发明提供了一种聚合物电解质组成物，该组成物在轻微湿润条件下能够实现优异的质子导电性能、优异的机械强度和优异的物理耐久性，具有优异的实用性，并且可以使用含氮添加剂进行制备，其中，该含氮添加剂可以在燃料电池运行时防止添加剂在强酸性气氛下析出，具有优异的化学稳定性以耐受强酸性气氛，可以溶解在各种通用有机溶剂中，具有优越的加工性能，可以与含离子基聚合物混合，并且可以防止在膜形成期间发生相分离，并且可以防止在膜形成期间形成类似于海岛-海洋的相分离结构或者出现出血现象；以及使用该聚合物电解质组成物制备的聚合物电解质膜、膜电极组件和聚合物电解质燃料电池。本发明的聚合物电解质组成物包括至少一种含离子基的聚合物(A)和一种含氮添加剂(B)，所述聚合物电解质组成物的特点是该含氮添加剂(B)由一种特定的结构式表示。
• Luminescent element material and luminescent element comprising the same
  申请人：TORAY INDUSTRIES INC.

  公开号：EP2365735A2

  公开（公告）日：2011-09-14

  A light emitting device is characterised in that it is a device having a structure in which at least an anode, an emissive layer, an electron transporting layer and a cathode are provided as layers in turn, and which emits light by means of electrical energy, and said device has a benzoquinoline derivative. The benzoquinoline derivative may have a plurality of benzoquinone skeletal structures, including a plurality of benzoquinone skeletal structures connected by conjugated bonds, an aromatic hydrocarbon, an aromatic heterocycle or mixture thereof. Example light emitting devices have a structure in which at least an anode, an emissive layer, an electron transporting layer and a cathode are provided as layers in turn and which emits light by means of electrical energy, and the organic compound is an organic compound of molecular weight at least 400, glass transition temperature at least 90°C, ionization potential at least 5.9 eV and having a benzoquinoline skeletal structure.

  一种发光器件，其特征在于它是一种具有至少阳极、发射层、电子传输层和阴极依次作为层的结构，并通过电能发光的器件，所述器件具有苯并喹啉衍生物。苯并喹啉衍生物可具有多个苯醌骨架结构，包括通过共轭键连接的多个苯醌骨架结构、芳香烃、芳香杂环或它们的混合物。 示例发光器件具有至少阳极、发射层、电子传输层和阴极作为层依次设置的结构，该结构通过电能发光，而有机化合物是分子量至少为 400、玻璃化温度至少为 90°C、电离电位至少为 5.9 eV 且具有苯并喹啉骨架结构的有机化合物。
• LIGHT EMITTING ELEMENT
  申请人：Toray Industries, Inc.

  公开号：EP2595208A1

  公开（公告）日：2013-05-22

  Provided is an organic thin film light emitting element which has achieved all of improved luminous efficiency, improved driving voltage and improved durability life. Specifically provided is a light emitting element which comprises a hole transport layer and an electron transport layer between a positive electrode and a negative electrode and emits light by means of electrical energy. The light emitting element is characterized in that: the hole transport layer of the light emitting element contains a compound represented by general formula (1); the electron transport layer contains a donor compound; and the donor compound is an alkali metal, an inorganic salt containing an alkali metal, a complex of an alkali metal and an organic substance, an alkaline earth metal, an inorganic salt containing an alkaline earth metal, or a complex of an alkaline earth metal and an organic substance. (In the formula, R1-R20 each represents one group selected from the group consisting of hydrogen, deuterium, an alkyl group, a cycloalkyl group, an amino group, an aryl group, a heterocyclic group, a heteroaryl group, an alkenyl group, a cycloalkenyl group, an alkynyl group, analkoxy group, an alkylthio group, an arylether group, an arylthioethergroup, a halogen, a cyano group, a -P(=O)R24R25 group and a silyl group;R24 and R25 each represents an aryl group or a heteroaryl group; and these substituents may be further substituted, or adjacent two substituents may combine together to form a ring. Meanwhile, R21-R23 may be the same or different and each represents one group selected from the group consisting of an alkyl group, a cycloalkyl group, an aryl group and a heteroaryl group; and these substituents maybe further substituted.)

  本发明提供了一种有机薄膜发光元件，它实现了发光效率的提高、驱动电压的提高和耐用寿命的提高。具体地说，本发明提供了一种发光元件，它包括位于正极和负极之间的空穴传输层和电子传输层，并通过电能发光。该发光元件的特征在于：发光元件的空穴传输层含有通式（1）表示的化合物；电子传输层含有供体化合物；供体化合物是碱金属、含碱金属的无机盐、碱金属和有机物的复合物、碱土金属、含碱土金属的无机盐或碱土金属和有机物的复合物。(式中，R1-R20 各代表一个选自氢、氘、烷基、环烷基、氨基、芳基、杂环基、杂芳基、烯基、环烯基、炔基、烷氧基、烷硫基、芳醚基、芳硫醚基、卤素、氰基、-P(=O)R24R25 基和硅烷基的基团；R24 和 R25 分别代表芳基或杂芳基；这些取代基可以进一步被取代，或者相邻的两个取代基可以结合在一起形成一个环。同时，R21-R23 可以相同或不同，各自代表一个选自烷基、环烷基、芳基和杂芳基的基团；这些取代基可能被进一步取代）。
• ORGANIC ELECTROLUMINESCENT ELEMENT
  申请人：Sony Corporation

  公开号：EP2833700A1

  公开（公告）日：2015-02-04

  An organic electroluminescence device including: an anode; a cathode; two or more emitting units that are disposed between the anode and the cathode, each unit having an emitting layer; and a charge-generating layer that is disposed between the emitting units, wherein the charge-generating layer includes an N layer nearer to the anode and a P layer nearer to the cathode, and the N layer includes a compound represented by the following formula (I) or (II):

  一种有机电致发光器件，包括：一个阳极；一个阴极；两个或两个以上设置在阳极和阴极之间的发光单元，每个单元都有一个发光层；以及一个设置在发光单元之间的电荷发生层，其中电荷发生层包括一个靠近阳极的 N 层和一个靠近阴极的 P 层，N 层包括下式（I）或（II）所代表的化合物：
• Organic electroluminescent device
  申请人：JOLED INC

  公开号：US10573823B2

  公开（公告）日：2020-02-25

  An organic electroluminescence device including: an anode; a cathode; two or more emitting units that are disposed between the anode and the cathode, each unit having an emitting layer; and a charge-generating layer that is disposed between the emitting units, wherein the charge-generating layer includes an N layer nearer to the anode and a P layer nearer to the cathode, and the N layer includes a compound represented by the following formula (I) or (II):

  一种有机电致发光器件，包括：一个阳极；一个阴极；两个或两个以上设置在阳极和阴极之间的发光单元，每个单元都有一个发光层；以及一个设置在发光单元之间的电荷发生层，其中电荷发生层包括一个靠近阳极的 N 层和一个靠近阴极的 P 层，N 层包括下式（I）或（II）所代表的化合物：