Ethyl-phosphonsaeure-ethylester-(2-methacryloyloxy-ethylester) | 814-36-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机膦酸及其衍生物
• 英文名称: Ethyl-phosphonsaeure-ethylester-(2-methacryloyloxy-ethylester)
• 英文别名: 2-[Ethoxy(ethyl)phosphoryl]oxyethyl 2-methylprop-2-enoate；2-[ethoxy(ethyl)phosphoryl]oxyethyl 2-methylprop-2-enoate
• CAS: 814-36-8
• 化学式: C₁₀H₁₉O₅P
• 分子量: 250.232
• InChiKey: GMPZFFCPGSBTLO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  16
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  61.8
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  甲基丙烯酸羟乙酯 在 三乙胺 作用下， 生成 Ethyl-phosphonsaeure-ethylester-(2-methacryloyloxy-ethylester)
  参考文献：
  名称：

  Pudovik,A.N. et al., Journal of general chemistry of the USSR, 1964, vol. 34, p. 3283 - 3285

  摘要：

  DOI：

文献信息

• COPOLYMER AND MOLDED BODY
  申请人：Kuraray Co., Ltd.

  公开号：EP2957579A1

  公开（公告）日：2015-12-23

  A copolymer comprising a structural unit (I) derived from a phosphonate monomer (1) such as diethyl methacryloyloxymethyl phosphonate, diethyl 2-methacryloyloxyethyl phosphonate and the like, and a structural unit (II) derived from a radical polymerizable monomer (2) such as methacrylic acid, acrylic acid, 8-tricyclo[5.2.1.02,6]decanyl methacrylate, t-butyl methacrylate and the like, wherein the content of phosphorus atoms from the phosphonate monomer (1) is 2.0 to 6.0 % by mass relative to the mass of the copolymer. A formed article comprising the copolymer.

  一种共聚物，其结构单元（I）来自膦酸盐单体（1），如甲基丙烯酰氧甲基膦酸二乙酯、2-甲基丙烯酰氧乙基膦酸二乙酯等，结构单元（II）来自可自由基聚合的单体（2），如甲基丙烯酸、丙烯酸、8-三环[5.2.1.02,6]癸基甲基丙烯酸酯、甲基丙烯酸叔丁酯等，其中膦酸酯单体（1）的磷原子含量相对于共聚物的质量为 2.0% 至 6.0%。由该共聚物组成的成型制品。
• COPOLYMER AND MOLDED ARTICLE
  申请人：Kuraray Co., Ltd.

  公开号：EP3181602A1

  公开（公告）日：2017-06-21

  A copolymer comprising a structural unit (I) derived from a phosphonate monomer (1) such as diethyl methacryloyloxymethyl phosphonate and diethyl 2-methacryloyloxyethyl phosphonate, a structural unit (II) derived from a radical polymerizable monomer (2) such as methacrylic acid, acrylic acid, 8-tricyclo[5.2.1.02,6]decanyl methacrylate, and t-butyl methacrylate, and a structural unit (III) derived from methyl methacrylate, the content of phosphorus atoms derived from the phosphonate monomer (1) being not less than 1.0% by mass and less than 2.0% by mass relative to the mass of the copolymer, and a formed article comprising the copolymer.

  一种共聚物，其结构单元(I)来自膦酸酯单体(1)，如甲基丙烯酰氧甲基膦酸二乙酯和 2-甲基丙烯酰氧乙基膦酸二乙酯；结构单元(II)来自可自由基聚合的单体(2)，如甲基丙烯酸、丙烯酸、8-三环[5.2.1.02,6]癸基甲基丙烯酸酯和甲基丙烯酸 t-丁酯，以及由甲基丙烯酸甲酯衍生的结构单元（III），相对于共聚物的质量，由膦酸酯单体（1）衍生的磷原子的含量不小于 1.0%（以质量计）且小于 2.0%（以质量计），以及由该共聚物组成的成型制品。
• COPOLYMER COMPOSITION HAVING PHOSPHONATE GROUP
  申请人：Kuraray Co., Ltd.

  公开号：EP3521364A1

  公开（公告）日：2019-08-07

  A copolymer composition comprising 100 parts by mass of a copolymer comprising a structural unit derived from a monomer represented by a formula (1) and a structural unit derived from another radical polymerizable monomer, and having a content of a phosphorus atom derived from the monomer represented by the formula (1) of 0.5 to 6.0% by mass, and 0.01 to 7.0 parts by mass of a compound represented by a formula (2), wherein in the formula (1), R1 represents a hydrogen atom or a methyl group, R2 represents an alkylene group having 1 to 4 carbon atoms, and R3 and R4 each independently represent a hydrogen atom or an alkyl group having 1 to 10 carbon atoms, wherein in the formula (2), R2 represents an alkylene group having 1 to 4 carbon atoms, R3 and R4 each independently represent a hydrogen atom or an alkyl group having 1 to 10 carbon atoms, and R5 represents an alkyl group having 1 to 10 carbon atoms.

  一种共聚物组合物，包括 100 质量份的共聚物，该共聚物的结构单元由式（1）所代表的单体和另一种可自由基聚合的单体所衍生的结构单元组成，且由式（1）所代表的单体衍生的磷原子含量为 0.5 至 6.0%（质量份），以及 0.01 至 7.0 质量份的式（2）所代表的化合物、 式（1）中，R1 代表氢原子或甲基，R2 代表具有 1 至 4 个碳原子的亚烷基，R3 和 R4 各自独立地代表氢原子或具有 1 至 10 个碳原子的烷基、 式（2）中，R2 代表具有 1 至 4 个碳原子的亚烷基，R3 和 R4 各自独立地代表氢原子或具有 1 至 10 个碳原子的烷基，R5 代表具有 1 至 10 个碳原子的烷基。
• Copolymer and molded article
  申请人：KURARAY Co., Ltd.

  公开号：US10407524B2

  公开（公告）日：2019-09-10

  A copolymer comprising a structural unit (I) derived from a phosphonate monomer (1) such as diethyl methacryloyloxymethyl phosphonate and diethyl 2-methacryloyloxyethyl phosphonate, a structural unit (II) derived from a radical polymerizable monomer (2) such as methacrylic acid, acrylic acid, 8-tricyclo[5.2.1.02,6]decanyl methacrylate, and t-butyl methacrylate, and a structural unit (III) derived from methyl methacrylate, the content of phosphorus atoms derived from the phosphonate monomer (1) being not less than 1.0% by mass and less than 2.0% by mass relative to the mass of the copolymer, and a formed article comprising the copolymer.

  一种共聚物，其结构单元(I)来自膦酸酯单体(1)，如甲基丙烯酰氧甲基膦酸二乙酯和 2-甲基丙烯酰氧乙基膦酸二乙酯；结构单元(II)来自可自由基聚合的单体(2)，如甲基丙烯酸、丙烯酸、8-三环[5.2.1.02,6]癸基甲基丙烯酸酯和甲基丙烯酸 t-丁酯，以及由甲基丙烯酸甲酯衍生的结构单元（III），相对于共聚物的质量，由膦酸酯单体（1）衍生的磷原子的含量不小于 1.0%（以质量计）且小于 2.0%（以质量计），以及由该共聚物组成的成型制品。
• US5523367A
  申请人：——

  公开号：US5523367A

  公开（公告）日：1996-06-04