Cyclohexyl-[1-methyl-prop-(E)-ylidene]-amine | 55969-52-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Cyclohexyl-[1-methyl-prop-(E)-ylidene]-amine
• CAS: 55969-52-3
• 化学式: C₁₀H₁₉N
• 分子量: 153.268
• InChiKey: CUXHBAFLKMXGRL-PKNBQFBNSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.19
• 重原子数：
  11.0
• 可旋转键数：
  2.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.9
• 拓扑面积：
  12.36
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  Cyclohexyl-[1-methyl-prop-(E)-ylidene]-amine 、 lithium diisopropyl amide 生成 lithium;but-1-en-2-yl(cyclohexyl)azanide
  参考文献：
  名称：

  SMITH, J. K.;NEWCOMB, M.;BERGBREITER, D. E.;WILLIAMS, D. R.;MEYERS, A. I., TETRAHEDRON LETT., 1983, 24, N 34, 3559-3562

  摘要：

  DOI：
• 作为产物：
  描述：

  环己胺 、 丁酮 生成 Cyclohexyl-[1-methyl-prop-(E)-ylidene]-amine
  参考文献：
  名称：

  LARCHEVEQUE M.; VALETTE G.; CUVIQNY TH., TETRAHEDRON, 1979, 35, NO 14, 1745-9

  摘要：

  DOI：

文献信息

• New Strategies for the Synthesis of Fluorinated Vinylogous Amidines and β-Enamino Ketones
  作者：Santos Fustero、Marta García de la Torre、Belén Pina、Antonio Simón Fuentes

  DOI：10.1021/jo990392w

  日期：1999.7.1

  imidoyl chlorides 3 with ketimines 1a provides fluorinated 1,3-diimines, which were exclusively isolated as vinylogous amidine tautomers 2beta, with good yields. Fluorinated beta-enamino ketones 4 are obtained by regioselective hydrolysis of 2. Complementary methods for the synthesis of regioisomeric beta-enamino ketones 4 and 5 are also reported. These methods include the reaction of azaenolates of

  氟化亚氨酰氯3与酮亚胺1a的反应提供了氟化1，3-二亚胺，其被单独分离为乙烯基og互变异构体2beta，具有良好的收率。氟化的β-烯胺酮4是通过2的区域选择性水解而获得的。还报道了用于合成区域异构的β-烯胺酮4和5的补充方法。这些方法包括酮亚胺的氮杂酸酯与氟化酯6的反应以及酮烯酸酯与氟化亚氨酰氯3的反应。还测试了这些体系在水解反应中的行为。
• ORGANOAMINOSILANES AND METHODS FOR MAKING SAME
  申请人：Air Products and Chemicals, Inc.

  公开号：US20160168169A1

  公开（公告）日：2016-06-16

  Organoaminosilanes, such as without limitation di-iso-propylaminosilane (DIPAS), are precursors for the deposition of silicon containing films such as silicon-oxide and silicon-nitride films. Described herein are methods to make organoaminosilane compounds, or other compounds such as organoaminodisilanes and organoaminocarbosilanes, via the catalytic hydrosilylation of an imine by a silicon source comprising a hydridosilane.

  Organoaminosilanes，例如但不限于二异丙基氨基硅烷（DIPAS），是沉积含硅膜如硅氧化物和硅氮化物膜的前体。本文描述了通过催化氢硅化反应将亚胺与含有氢硅烷的硅源反应制备出有机氨基硅烷化合物，或其他化合物如有机氨基二硅烷和有机氨基碳硅烷的方法。
• Synthesis and Reactivity of New β-Enamino Acid Derivatives:  A Simple and General Approach to β-Enamino Esters and Thioesters
  作者：Santos Fustero、Marta García de la Torre、Viviana Jofré,、Raquel Pérez Carlón、Antonio Navarro、Antonio Simón Fuentes、Juan Server Carrió

  DOI：10.1021/jo9809480

  日期：1998.11.1

  A new strategy has been developed for the synthesis of several beta-enamino acid derivatives. N,N'-Carbonyldiimidazole has been used as C-acylating agent of methyl ketimines, providing a direct and simple route to new beta-enamino carbonyl imidazole derivatives 2. These derivatives 2 were cleanly and efficiently transformed into beta-enamino esters 4 (X = O) and thioesters 4 (X = S) by reaction with a great variety of alcohols and thiols, including tertiary ones. Alternative and complementary routes to compounds 4 were also investigated. In addition, beta-keto esters 6 have been obtained by mild acid hydrolysis of beta-enamino esters 4.
• Organoaminosilanes and methods for making same
  申请人：Versum Materials US, LLC

  公开号：EP2913334B1

  公开（公告）日：2018-12-19
• Regioselectivity in deprotonation of imines derived from 3-pentanone
  作者：J. Kirk Smith、David E. Bergbreiter、Martin Newcomb

  DOI：10.1021/jo00328a044

  日期：1981.7