bis-(4-hydroxy-phenyl)-phosphinic acid | 109962-20-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: bis-(4-hydroxy-phenyl)-phosphinic acid
• 英文别名: Bis-(4-hydroxy-phenyl)-phosphinsaeure；Di-(4-hydroxyphenyl) phosphinic acid；bis(4-hydroxyphenyl)phosphinic acid
• CAS: 109962-20-1
• 化学式: C₁₂H₁₁O₄P
• 分子量: 250.191
• InChiKey: WDYLJDVNEKMXDJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  77.8
• 氢给体数：
  3
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  二(4-硝基苯基)次膦酸 在 盐酸 、 亚硝酸乙酯 、 镍 作用下， 生成 bis-(4-hydroxy-phenyl)-phosphinic acid
  参考文献：
  名称：

  Synthesis of Phosphanilic Acid and Related Compounds¹

  摘要：

  DOI：

  10.1021/ja01123a049

文献信息

• Process for Producing Polyester, Polyester Produced Using Said Process, and Polyester Molded Product
  申请人：Kageyama Katsuhiko

  公开号：US20080249280A1

  公开（公告）日：2008-10-09

  This invention provides a polyester and a polyester molded product, which, while maintaining color tone, transparency, and thermal stability, can realize a high polycondensation rate, are less likely to cause the production of polycondensation catalyst-derived undesired materials, and can simultaneously meet both quality and cost effectiveness requirements, which can exhibit the characteristic features, for example, in the fields of ultrafine fibers, high transparent films for optical use, or ultrahigh transparent molded products. These advantages can be realized by using, in the production of a polyester in the presence of an aluminum compound-containing polyester polycondensation catalyst, an aluminum compound having an absorbance of not more than 0.0132 as measured in the form of an aqueous aluminum compound solution, prepared by dissolving the aluminum compound in pure water to give a concentration of 2.7 g/liter in terms of the amount of aluminum element, under conditions of cell length 1 cm and wavelength 680 nm.

  本发明提供了一种聚酯和聚酯成型产品，可以在保持色调、透明度和热稳定性的同时，实现高聚酯化速率，不太可能引起聚酯化催化剂来源的不良材料的生产，并且可以同时满足质量和成本效益的要求，这些优点可以在超细纤维、用于光学的高透明薄膜或超高透明成型产品等领域展现出特征性能。通过在含有铝化合物聚酯聚合催化剂的聚酯生产中使用具有吸光度不超过0.0132的铝化合物，可以实现这些优点。该吸光度是在细胞长度为1厘米，波长为680纳米的条件下，将铝化合物溶解在纯水中以给定铝元素量浓度为2.7克/升形成的水溶性铝化合物溶液中测量得出的。
• POLYESTER, PROCESS FOR PRODUCTION OF POLYESTER, AND POLYESTER MOLDED ARTICLE
  申请人：Toyo Boseki Kabushiki Kaisha

  公开号：EP1932867A1

  公开（公告）日：2008-06-18

  Disclosed is a polyester produced from an aluminum compound and a phosphorus compound in the presence of a polycondensation catalyst. The polyester contains a polyester-insoluble, aluminum-containing insoluble particle in an amount of 1000 ppm or less as quantified by the method disclosed in the description, and contains an acid terminal group at a ratio of 10 to 50 eq/ton. The polyester can provide a highly transparent molded article produced through drawing (e.g., a film or hollow molded article) and is useful in the fields of highly transparent optical films, ultra-highly transparent molded articles or the like.

  本发明公开了一种在缩聚催化剂存在下由铝化合物和磷化合物制得的聚酯。该聚酯含有聚酯不溶物、含铝不溶物颗粒，按描述中公开的方法定量，其含量为 1000 ppm 或更少，并含有酸性末端基团，其比例为 10 至 50 eq/吨。该聚酯可提供通过拉丝生产的高透明模塑品（如薄膜或中空模塑品），在高透明光学薄膜、超高透明模塑品等领域非常有用。
• POLYESTER FILM FOR PROTECTION OF BACK SURFACES OF SOLAR CELLS
  申请人：Toyo Boseki Kabushiki Kaisha

  公开号：EP2484714A1

  公开（公告）日：2012-08-08

  It is an object of the present invention to provide a polyester film for the protection of a back surface of a solar cell which, when applied to a silicon thin film solar cell, exhibits excellent durability even under high-temperature and high-humidity conditions and long term thermal stability. A polyester film for the protection of a back surface of a solar cell containing a polyester, as a main constituent, obtained by polymerization using a polycondensation catalyst containing aluminum and/or its compound as well as a phosphorus compound having an aromatic group in the molecule; having a whiteness degree of 50 or higher; containing 3 to 50% by mass of fine particles with a mean particle diameter of 0.1 to 3 µm; and having an acid value from not lower than 1 (eq/ton) and not higher than 30 (eq/ton).

  本发明的目的是提供一种用于保护太阳能电池背面的聚酯薄膜，这种薄膜在应用于硅薄膜太阳能电池时，即使在高温高湿条件下也能表现出极佳的耐久性和长期热稳定性。 一种用于保护太阳能电池背面的聚酯薄膜，其主要成分为聚酯，该聚酯通过使用含铝和/或其化合物以及分子中含有芳香基的磷化合物的缩聚催化剂聚合而成；白度为 50 或更高；含有 3 至 50%（按重量计）的细颗粒，其平均颗粒直径为 0.1 至 3 微米；酸值不低于 1（当量/吨），不高于 30（当量/吨）。
• COPOLYESTER RESIN, MOLDED PRODUCT, AND HEAT-SHRINKABLE FILM
  申请人：TOYOBO CO., LTD.

  公开号：EP3875514A1

  公开（公告）日：2021-09-08

  The present invention aims to provide a copolymerized polyester resin which solves the problem of die staining and foreign matter adhesion to the film or molded product in the continuous production of the film or molded product. According to the present invention, there is provided a copolymerized polyester resin which contains terephthalic acid as a main component of a dicarboxylic acid component, contains ethylene glycol as a main component of a diol component, wherein a content of neopentyl glycol is more than 15% by mole and not more than 40% by mole and a content of diethylene glycol is from 6 to 20% by mole when a total amount of the whole diol component is taken as 100% by mole, wherein a content of a cyclic dimer consisting of terephthalic acid, neopentyl glycol and diethylene glycol is 5000 ppm or less, and wherein a content of a cyclic trimer consisting of terephthalic acid and ethylene glycol is 5000 ppm or less.

  本发明旨在提供一种共聚聚酯树脂，它可以解决在连续生产薄膜或模塑产品时模 头染色和异物附着在薄膜或模塑产品上的问题。根据本发明，提供了一种共聚聚酯树脂，它含有作为二羧酸组分主要成分的对苯二甲酸，含有作为二元醇组分主要成分的乙二醇，其中新戊二醇的含量大于 15%（摩尔）但不大于 40%（摩尔），当整个二元醇组分的总量为 100%（摩尔）时，二乙二醇的含量为 6%至 20%（摩尔）、其中对苯二甲酸、新戊二醇和二乙二醇组成的环状二聚体的含量为 5000 ppm 或以下，对苯二甲酸和乙二醇组成的环状三聚体的含量为 5000 ppm 或以下。
• BIAXIALLY STRETCHED POLYESTER FILM ROLL
  申请人：TOYOBO CO., LTD.

  公开号：EP3928956A1

  公开（公告）日：2021-12-29

  To provide a biaxially-oriented polyester film roll that is excellent in transparency and heat resistance and has less defects. A biaxially oriented polyester film roll of the present invention characterized by satisfying requirements (1) a winding length of the film roll, (2) a width of the film roll, (3) an average hardness of an outermost surface layer of the polyester film roll, (4) a variation in hardness, (5) a thickness of a polyester film of the polyester film roll, and (6) an irregularity of thickness in the maximum concave portion.

  提供一种透明性和耐热性极佳且缺陷较少的双向拉伸聚酯薄膜卷。本发明的一种双轴定向聚酯薄膜卷，其特征在于满足以下要求：（1）薄膜卷的卷绕长度；（2）薄膜卷的宽度；（3）聚酯薄膜卷最外层表面的平均硬度；（4）硬度变化；（5）聚酯薄膜卷的聚酯薄膜厚度；以及（6）最大凹陷部分的厚度不规则性。