3,4-Dihydro-2-methyl-1-methylenenaphthalene-2-ol | 82482-43-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 四氢化萘
• 英文名称: 3,4-Dihydro-2-methyl-1-methylenenaphthalene-2-ol
• 英文别名: 2-Methyl-1-methylidene-3,4-dihydronaphthalen-2-ol
• CAS: 82482-43-7
• 化学式: C₁₂H₁₄O
• 分子量: 174.243
• InChiKey: MZZYTZLLJZZKMM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  13
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  (+)-3,4-Dihydro-1,2-dimethylnaphthalene-1,2-oxide 在 lithium bromide 作用下， 以 乙腈 为溶剂， 反应 1.0h， 生成 3,4-Dihydro-2-methyl-1-methylenenaphthalene-2-ol
  参考文献：
  名称：

  Effect of ring size and methyl substituents on lithium bromide-catalyzed rearrangements of aryloxiranes

  摘要：

  DOI：

  10.1021/jo00140a029

文献信息

• Asymmetric Epoxidation with a Photoactivated [Ru(salen)] Complex
  作者：Kenya Nakata、Tsuyoshi Takeda、Jun Mihara、Tetsuya Hamada,、Ryo Irie、Tsutomu Katsuki

  DOI：10.1002/1521-3765(20010903)7:17<3776::aid-chem3776>3.0.co;2-m

  日期：2001.9.3

  (Nitrosyl)(salen)ruthenium(II) complex 1 was found to serve as an efficient catalyst for the epoxidation of conjugated olefins under photoirradiation, with 2,6-dichloropyridine N-oxide (2) or tetramethylpyrazine N,N'-dioxide as a stoichiometric oxidant. High enantioselectivity was achieved irrespective of the substitution pattern of olefins. The choice of solvent depends on stability of the resulting epoxides: high enantioselectivity is generally observed in the reaction with ethereal solvents, but use of benzene is recommended when the resulting epoxides are acid-sensitive.
• BANKS, H.;ZIFFER, H., J. ORG. CHEM., 1982, 47, N 19, 2743-3747
  作者：BANKS, H.、ZIFFER, H.

  DOI：——

  日期：——
• Effect of ring size and methyl substituents on lithium bromide-catalyzed rearrangements of aryloxiranes
  作者：Harold Banks、Herman Ziffer

  DOI：10.1021/jo00140a029

  日期：1982.9