4-methylthio-6-phenyl-1,3,5-triazin-2(1H)-thione | 15998-30-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: 4-methylthio-6-phenyl-1,3,5-triazin-2(1H)-thione
• 英文别名: 4-methylsulfanyl-6-phenyl-1H-1,3,5-triazine-2-thione
• CAS: 15998-30-8
• 化学式: C₁₀H₉N₃S₂
• 分子量: 235.334
• InChiKey: FGLAFVWISSMEEI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  94.1
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  4-methylthio-6-phenyl-1,3,5-triazin-2(1H)-thione 在 sodium hydroxide 作用下， 以 二甲基亚砜 为溶剂， 反应 12.0h， 生成 2-methylthio-4-phenyl-6-phenylamino-1,3,5-triazine
  参考文献：
  名称：

  Synthesis of 1,3,5-Triazine Derivatives by the Reaction of S,S'-Dimethyl N-Cyanocarbonimidodithioate with Amides

  摘要：

  S,S'-Dimethyl N-cyanocarbonimidodithioate (1) reacted with amides (2) in the presence of sodium hydride in a mixture of benzene and N,N-dimethylacetamide to give the corresponding N-acyl-N'-carbamoyl-S-methylisothioureas (3). Refluxing of 3 in methanol gave the corresponding cyclized product, 1,3,5-triazin-2(1H)-one derivatives (4). Compounds (4) were found to be useful intermediates for the synthesis of trisubstituted 1,3,5-triazines.

  DOI：

  10.3987/com-95-7374
• 作为产物：
  描述：

  N-Benzoyl-dithiocarbaminsaeure-methylester 在 sodium hydride 作用下， 以 N,N-二甲基甲酰胺 、 苯 为溶剂， 反应 6.0h， 生成 4-methylthio-6-phenyl-1,3,5-triazin-2(1H)-thione
  参考文献：
  名称：

  Augustin, M.; Richter, M.; Salas, S., Journal fur praktische Chemie (Leipzig 1954), 1980, vol. 322, # 1, p. 55 - 68

  摘要：

  DOI：

文献信息

• Organic-inorganic hybrid composition, and article and optical component including the same
  申请人：Samsung Electronics Co., Ltd.

  公开号：US10717866B2

  公开（公告）日：2020-07-21

  Disclosed an organic-inorganic hybrid composition including a polymer (A) including a triazine ring structure represented by General Formula (1) in a polymer main chain structure; wherein, in the formula, R1 is a substituted or unsubstituted alkyl group, aryl group, aralkyl group, amino group, arylamino group, alkylthio group, or arylthio group, an inorganic particulate (B); and a surface-treatment agent (C) including an acidic functional group wherein the polymer (A) is a thermoplastic polymer having a glass transition temperature (Tg) and a number median diameter (Dn50) of the inorganic particulate (B) is greater than or equal to about 1 nm and less than or equal to about 20 nm, and an article and an optical component including the organic-inorganic hybrid composition.

  本发明公开了一种有机-无机杂化组合物，包括聚合物（A），聚合物主链结构中包含通式（1）表示的三嗪环结构； 其中，在式中，R1 是取代或未取代的烷基、芳基、芳烷基、氨基、芳胺基、烷硫基或芳硫基、 无机微粒（B）；以及 包括酸性官能团的表面处理剂 (C) 其中聚合物 (A) 是热塑性聚合物，具有玻璃化转变温度 (Tg)，无机微粒 (B) 的数中直径 (Dn50) 大于或等于约 1 nm 且小于或等于约 20 nm，以及包括有机-无机杂化组合物的物品和光学元件。
• AUGUSTIN M.; RICHTER M.; SALAS S., J. PRAKT. CHEM., 1980, 322, NO 1, 55-68
  作者：AUGUSTIN M.、 RICHTER M.、 SALAS S.

  DOI：——

  日期：——
• US4016159A
  申请人：——

  公开号：US4016159A

  公开（公告）日：1977-04-05
• Augustin, M.; Richter, M.; Salas, S., Journal fur praktische Chemie (Leipzig 1954), 1980, vol. 322, # 1, p. 55 - 68
  作者：Augustin, M.、Richter, M.、Salas, S.

  DOI：——

  日期：——
• Synthesis of 1,3,5-Triazine Derivatives by the Reaction of S,S'-Dimethyl N-Cyanocarbonimidodithioate with Amides
  作者：Shinya Kohra、Kazuo Ueda、Yoshinori Tominaga

  DOI：10.3987/com-95-7374

  日期：——

  S,S'-Dimethyl N-cyanocarbonimidodithioate (1) reacted with amides (2) in the presence of sodium hydride in a mixture of benzene and N,N-dimethylacetamide to give the corresponding N-acyl-N'-carbamoyl-S-methylisothioureas (3). Refluxing of 3 in methanol gave the corresponding cyclized product, 1,3,5-triazin-2(1H)-one derivatives (4). Compounds (4) were found to be useful intermediates for the synthesis of trisubstituted 1,3,5-triazines.