3-Phenaethyl-phthalsaeure | 35157-38-1

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 3-Phenaethyl-phthalsaeure
• 英文别名: 3-phenethylphthalic acid；3-(2-Phenylethyl)phthalic acid
• CAS: 35157-38-1
• 化学式: C₁₆H₁₄O₄
• 分子量: 270.285
• InChiKey: QOTROWHFEYSFNG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  20
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  74.6
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  一氧化碳 、 2-苯乙基苯甲酸 在 sodium acetate 、 palladium diacetate 、 silver carbonate 作用下， 以 1,4-二氧六环 为溶剂， 130.0 ℃ 、101.33 kPa 条件下， 反应 18.0h， 以93%的产率得到3-Phenaethyl-phthalsaeure
  参考文献：
  名称：

  通过 Pd(II)-催化芳基和乙烯基 C-H 键的羧化合成 1,2- 和 1,3-二羧酸

  摘要：

  已经开发了用于苯甲酸和苯乙酸衍生物直接羧化以形成二羧酸的 Pd(II) 催化反应方案。反应条件也适用于乙烯基 CH 键的羧化。来自羧酸的第一个 CH 插入 Pd-芳基配合物已通过 X 射线晶体学表征。

  DOI：

  10.1021/ja8063827

文献信息

• Surface protection film
  申请人：NITTO DENKO CORPORATION

  公开号：EP2657277A1

  公开（公告）日：2013-10-30

  The invention provides a surface protection film 1 comprising a top coat layer 14 on a first face 12A of a substrate 12, and a pressure-sensitive adhesive layer 20 on a second face 12B. The top coat layer 14 comprises a wax as a slip agent, and a polyester resin as a binder. Here, the wax is an ester of a higher fatty acid and a higher alcohol.

  本发明提供了一种表面保护膜 1，它包括位于基材 12 第一面 12A 上的表层 14 和位于第二面 12B 上的压敏胶层 20。表层 14 包括作为滑爽剂的蜡和作为粘合剂的聚酯树脂。在这里，蜡是一种高级脂肪酸和高级醇的酯。
• Sustained release compositions from cellulose ethers
  申请人：THE DOW CHEMICAL COMPANY

  公开号：EP0121712B1

  公开（公告）日：1987-04-22
• SURFACE PROTECTION FILM
  申请人：NITTO DENKO CORPORATION

  公开号：US20130280527A1

  公开（公告）日：2013-10-24

  The invention provides a surface protection film including a top coat layer on a first face of a substrate, and a pressure-sensitive adhesive layer on a second face. The top coat layer includes a wax as a slip agent, and a polyester resin as a binder. Here, the wax is an ester of a higher fatty acid and a higher alcohol.
• SURFACE PROTECTIVE FILM AND OPTICAL COMPONENT
  申请人：NITTO DENKO CORPORATION

  公开号：US20150037573A1

  公开（公告）日：2015-02-05

  Provided is a surface protective film, which has a substrate having a topcoat layer containing a lubricating property-imparting component and rarely whitened and an adhesive layer formed of a water dispersible acrylic adhesive composition, and which is excellent in appearance characteristics, etc. A surface protective film has a substrate; and a topcoat layer and an acrylic adhesive layer formed on respective faces of the substrate, in which the topcoat layer contains a lubricant wax composed of a higher fatty acid/higher alcohol ester and a polyester binder resin, the acrylic adhesive layer is formed of a water dispersible acrylic adhesive composition containing an acrylic emulsion polymer (A) obtained by polymerization of an alkyl(meth)acrylate and a carboxyl group-containing unsaturated monomer with a reactive emulsifier having a radical polymerizable functional group; and a compound (B) represented by formula (I): R 1 O—(PO) a -(EO) b —(PO) c —R 2 (I).
• PRESSURE-SENSITIVE ADHESIVE SHEET AND OPTICAL MEMBER
  申请人：NITTO DENKO CORPORATION

  公开号：US20150037576A1

  公开（公告）日：2015-02-05

  A pressure-sensitive adhesive sheet having a supporting film, a pressure-sensitive adhesive layer formed from a pressure-sensitive adhesive composition on one surface of the supporting film, and a top coat layer on the other surface opposite to the surface having the pressure-sensitive adhesive layer of the supporting film, wherein the top coat layer contains wax as a lubricant and a polyester resin as a binder and having the properties as defined.