2-叔丁基-4-乙氧基苯酚 | 25762-84-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 中文名称: 2-叔丁基-4-乙氧基苯酚
• 英文名称: 2-tert-Butyl-4-ethoxyphenol
• CAS: 25762-84-9
• 化学式: C₁₂H₁₈O₂
• 分子量: 194.274
• InChiKey: OMPBXAWNLAWVJJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  14
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-叔丁基-4-乙氧基苯酚 以 乙醇 、 甲苯 、 xylene 为溶剂， 反应 68.0h， 生成 Spiro<(1-methyl-1,2,3,4-tetrahydrobenzochinolin)-3,1'-(1'H-3'-tert-butyl-5'-ethoxy-cyclohexa-3',5'-dien-2'-on)>
  参考文献：
  名称：

  Moehrle, H.; Schake, D., Zeitschrift fur Naturforschung, B: Chemical Sciences, 1995, vol. 50, # 12, p. 1859 - 1868

  摘要：

  DOI：
• 作为产物：
  描述：

  溴乙烷 、 特丁基对苯二酚 以 N-甲基乙酰胺 为溶剂， 以22%的产率得到2-叔丁基-4-乙氧基苯酚
  参考文献：
  名称：

  Phenol compound having antioxidative activity and the process for

  摘要：

  揭示了一种由以下式（1）表示的酚化合物：##STR1## 其中R.sup.0代表H、烷基或烷氧基；R.sup.1代表烷基；R.sup.2代表烷基或烷氧基；OR.sup.3代表OH；R.sup.4代表H、较低烷基或酰基，上述取代基中的每一个均可被取代；W代表O、S或NR.sup.7；其中R.sup.7代表H、烷基、芳基、OH或烷氧基，式（2）的一个基团：##STR2## 代表一个氨基，该氨基可以是单取代或双取代的，或含有N原子的杂环基团，或其药学上可接受的盐，以及其制备方法。

  公开号：

  US05849732A1

文献信息

• Phenol-derivatives having pharmaceutical activity and process for preparing the same
  申请人：TANABE SEIYAKU CO., LTD.

  公开号：EP0790240A1

  公开（公告）日：1997-08-20

  Disclosed are a phenol compound represented by the formula (1):    wherein R0 represents H, alkyl or alkyloxy; R1 represents alkyl; R2 represents alkyl or alkyloxy; OR3 represents OH; R4 represents H, lower alkyl or acyl, each of the above substituents may be substituted; W represents O, S or NR7; where R7 represents H, alkyl, aryl, OH or alkyloxy; a group of the formula (2): represents an amino which may be mono- or di-substituted or heterocyclic group containing N atom, or a pharmaceutically acceptable salt thereof, and a process for preparing the same. The compounds of formula (1) possess both an ACAT inhibitory activity and an antioxidative activity.

  本发明涉及一种由式（1）表示的酚类化合物：其中，R0表示氢、烷基或烷氧基；R1表示烷基；R2表示烷基或烷氧基；OR3表示羟基；R4表示氢、低级烷基或酰基，上述各取代基均可被取代；W表示O、S或NR7；其中，R7表示氢、烷基、芳基、羟基或烷氧基；式（2）的基团表示一种含有N原子的单取代或双取代氨基或杂环基团，或其药学上可接受的盐，并且提供了制备它们的方法。式（1）的化合物具有ACAT抑制活性和抗氧化活性。
• VULCANIZING FLUORORUBBER COMPOSITION
  申请人：DAIKIN INDUSTRIES, LTD.

  公开号：EP0607457A1

  公开（公告）日：1994-07-27

  A vulcanizing fluororubber composition which comprises: (a) an iodinated and/or brominated fluororubber, (b) a vulcanizing agent comprising an organic peroxide, and (c) a compound represented by general formula (I) in an amount of 0.05 - 5 ppm based on the fluororubber (a), wherein R¹ and R² represent each C₁ to C₃ alkyl, and which can yield colorless transparent vulcanizates.

  一种硫化氟橡胶组合物，它包括：(a) 碘化和/或溴化氟橡胶，(b) 由有机过氧化物组成的硫化剂，以及 (c) 通式 (I) 所代表的化合物，其用量为 0.05 - 5 ppm（基于氟橡胶 (a)），其中 R¹ 和 R² 分别代表 C₁ 至 C₃ 烷基，该组合物可生成无色透明的硫化胶。
• POLYMERIZABLE COMPOSITION, THERMOPLASTIC RESIN COMPOSITION, CROSSLINKED RESIN, AND CROSSLINKED RESIN COMPOSITE MATERIALS
  申请人：ZEON CORPORATION

  公开号：EP1589054A1

  公开（公告）日：2005-10-26

  A polymerizable composition which comprises (i) a cycloolefin monomer, (ii) a metathesis polymerization catalyst, (iii) a chain transfer agent, (iv) a radical crosslinking agent, and (v) a compound (α) selected from the group consisting of compounds having alkoxyphenol structures wherein each aromatic ring has one or more substituents, compounds having aryloxyphenol structures, and compounds having catechol structures wherein each aromatic ring has two or more substituents; a thermoplastic resin composition which comprises (1) a cycloolefin thermoplastic resin, (2) a radical crosslinking agent, and (3) a compound (α) ; a process for the production thereof; a crosslinked resin obtained by crosslinking the thermoplastic resin composition; and crosslinked resin composite materials produced by laminating a substrate with the thermoplastic resin composition and crosslinking the thermoplastic resin composition. The invention provides a polymerizable composition useful as raw material in the production of a thermoplastic resin composition excellent in storage stability and fluidity in heat lamination; a thermoplastic resin composition and a process for the production thereof; a crosslinked resin obtained by crosslinking the thermoplastic resin composition; and crosslinked resin composite materials exhibiting excellent interlayer adhesion.

  一种可聚合组合物，它包括(i)环烯烃单体，(ii)偏聚催化剂，(iii)链转移剂，(iv)自由基交联剂，和(v)选自以下组别的化合物(α)：具有烷氧基苯酚结构的化合物，其中每个芳香环有一个或多个取代基；具有芳氧基苯酚结构的化合物；以及具有邻苯二酚结构的化合物，其中每个芳香环有两个或多个取代基；一种热塑性树脂组合物，它包括：(1) 环烯烃热塑性树脂；(2) 自由基交联剂；(3) 化合物 (α)；其生产工艺；通过交联该热塑性树脂组合物而获得的交联树脂；以及通过将基材与该热塑性树脂组合物层压并交联该热塑性树脂组合物而生产的交联树脂复合材料。本发明提供了一种可聚合组合物，可作为生产热塑性树脂组合物的原料，该组合物具有优异的储存稳定性和热层压流动性；一种热塑性树脂组合物及其生产工艺；一种通过交联该热塑性树脂组合物而获得的交联树脂；以及具有优异层间粘合性的交联树脂复合材料。
• Polymerizable Composition, Thermoplastic Resin Composition, Crosslinked Resin, And Crosslinked Resin Composite Materials
  申请人：Sugawara Tomoo

  公开号：US20080125531A1

  公开（公告）日：2008-05-29

  A polymerizable composition which comprises (i) a cycloolefin monomer, (ii) a metathesis polymerization catalyst, (iii) a chain transfer agent, (iv) a radical crosslinking agent, and (v) a compound (α) selected from the group consisting of compounds having alkoxyphenol structures wherein each aromatic ring has one or more substituents, compounds having aryloxyphenol structures, and compounds having catechol structures wherein each aromatic ring has two or more substituents; a thermoplastic resin composition which comprises (1) a cycloolefin thermoplastic resin, (2) a radical crosslinking agent, and (3) a compound (α); a process for the production thereof; a crosslinked resin obtained by crosslinking the thermoplastic resin composition; and crosslinked resin composite materials produced by laminating a substrate with the thermoplastic resin composition and crosslinking the thermoplastic resin composition. The invention provides a polymerizable composition useful as raw material in the production of a thermoplastic resin composition excellent in storage stability and fluidity in heat lamination; a thermoplastic resin composition and a process for the production thereof; a crosslinked resin obtained by crosslinking the thermoplastic resin composition; and crosslinked resin composite materials exhibiting excellent interlayer adhesion.
• US5399623A
  申请人：——

  公开号：US5399623A

  公开（公告）日：1995-03-21