6-碘-2,3-二甲基-苯酚 | 17938-67-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 中文名称: 6-碘-2,3-二甲基-苯酚
• 英文名称: 6-iodo-2,3-dimethyl-phenol
• 英文别名: 2-iodo-5,6-dimethylphenol；2,3-Dimethyl-6-iod-phenol；6-Iodo-2,3-dimethylphenol
• CAS: 17938-67-9
• 化学式: C₈H₉IO
• 分子量: 248.063
• InChiKey: WVMDQTZMUAFNGA-UHFFFAOYSA-N

物化性质

• 沸点：
  229.1±35.0 °C(Predicted)
• 密度：
  1.740±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  6-碘-2,3-二甲基-苯酚 在 铜 作用下， 以 乙醚 为溶剂， 生成 Tetramethyl-2,2'-dimethoxy-biphenyl-3,3',4,4'-tetracarboxylat
  参考文献：
  名称：

  尤利霉素的研究I：尤利霉素B-II的结构

  摘要：

  通过光谱和降解实验，已经确定了一种新的抗病毒抗生素朱利霉素B-II的结构，它是β，β'-蒽硫醌的衍生物。

  DOI：

  10.1016/s0040-4020(01)82482-0
• 作为产物：
  描述：

  二甲酚 在 氢氧化钾 、 碘 、 potassium iodide 作用下， 生成 6-碘-2,3-二甲基-苯酚
  参考文献：
  名称：

  尤利霉素的研究I：尤利霉素B-II的结构

  摘要：

  通过光谱和降解实验，已经确定了一种新的抗病毒抗生素朱利霉素B-II的结构，它是β，β'-蒽硫醌的衍生物。

  DOI：

  10.1016/s0040-4020(01)82482-0

文献信息

• PROCESS FOR SELECTIVELY POLYMERIZING ETHYLENE AND CATALYST THEREFOR
  申请人：Klosin Jerzy

  公开号：US20110282018A1

  公开（公告）日：2011-11-17

  The present invention generally relates to a process that selectively polymerizes ethylene in the presence of an alpha-olefin, and to a metal-ligand complex (precatalyst) and catalyst useful in such processes, and to related compositions. The present invention also generally relates to ligands and intermediates useful for preparing the metal-ligand complex and to processes of their preparation.

  本发明通常涉及在α-烯烃存在的情况下选择性聚合乙烯的过程，以及在这些过程中有用的金属配体复合物（预催化剂）和催化剂，以及相关组合物。本发明还通常涉及用于制备金属配体复合物的配体和中间体，以及它们的制备过程。
• Synthesis of constrained arylpiperidines using intramolecular Heck or radical reactions
  作者：Christophe Morice、Mathias Domostoj、Karin Briner、André Mann、Jean Suffert、Camille-Georges Wermuth

  DOI：10.1016/s0040-4039(01)01191-1

  日期：2001.9

  Two intramolecular routes were experimented to reach the hexahydrobenzofuro[2,3-c]pyridine platform: a Heck and a radical reaction. The radical route was applicable to all substrates, whereas the Heck route was of limited use. The key adducts were obtained via a Mitsunobu condensation between halogenated phenols and an allylic alcohol, the 3-hydroxy-tetrahydropyridine. (C) 2001 Elsevier Science Ltd. All rights reserved.
• Gas-chromatographic identification of products formed in iodination of methyl phenols by retention indices
  作者：I. V. Gruzdev、I. M. Kuzivanov、I. G. Zenkevich、B. M. Kondratenok

  DOI：10.1134/s1070427212090108

  日期：2012.9

  Iodination reaction followed by conversion of iodine-substituted methylphenols to the corresponding trifluoroacetates was suggested for improving the sensitivity of the gas-chromatographic determination of phenol and its methyl-substituted derivatives (al isomers of mono-and diethylphenols, 2,3,5-, 2,3,6-, and 3,4,5-trimethylphenols) in aqueous media. Acylation products of iodo methylphenols (104 compounds) were identified by linear-logarithmic retention indices on a standard nonpolar polydimethylsiloxane stationary phase, and the pattern of their variation with the number and nature of substituents were characterized. A procedure for identification of methyl-substituted phenols in water in their gas-chromatographic determination with an electron-capture detector was developed.
• US8609794B2
  申请人：——

  公开号：US8609794B2

  公开（公告）日：2013-12-17
• US9000108B2
  申请人：——

  公开号：US9000108B2

  公开（公告）日：2015-04-07