ter-butylammonium N-ter-butylcarbamate | 120087-49-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: ter-butylammonium N-ter-butylcarbamate
• 英文别名: tert.-Butylammonium-tert.-butylcarbamat；tert-butylazanium;N-tert-butylcarbamate
• CAS: 120087-49-2
• 化学式: C₄H₁₁N*C₅H₁₁NO₂
• 分子量: 190.286
• InChiKey: ZZBCKOHSSDANJG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.26
• 重原子数：
  13
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  79.8
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  ter-butylammonium N-ter-butylcarbamate 、 碘甲烷 在 18-冠醚-6 作用下， 以 二氯甲烷 为溶剂， 19.9 ℃ 、103.0 kPa 条件下， 反应 28.0h， 生成 methyl N-tert-butylcarbamate
  参考文献：
  名称：

  大环聚醚在冠醚存在下由伯胺，CO 2和烷基卤化物合成N-烷基氨基甲酸酯的作用。

  摘要：

  伯胺RNH 2 1和CO 2容易获得N-烷基氨基甲酸酯单烷基铵[RNH 3 ] [O 2 CNHR] 2，它们在冠醚存在下与卤代烷R'X反应生成有机物氨基甲酸酯收率高。我们在这里报告了一些氨基甲酸烷基铵2的合成和光谱表征，其中R =苄基2a，烯丙基2b，叔丁基2c，环己基2d，并讨论了它们在溶液中的稳定性以及可以与卤代烷反应生成有机氨基甲酸酯RNHC（O）OR'的条件。在修改单烷基氨基甲酸酯的反应性由大环配位起的作用2朝向R'X已经合理化和的参数，如溶剂，温度和CO的影响2压力在通往有机氨基甲酸酯的方法的产率和选择性得到了也解决了。

  DOI：

  10.1016/s0040-4020(01)92239-2
• 作为产物：
  描述：

  N-<2,3-Di-tert.-butyl-carbazoyloxy>-tert.-butylamin 生成 ter-butylammonium N-ter-butylcarbamate
  参考文献：
  名称：

  Diaziridinones (2,3-diazacyclopropanones). II. Synthesis, properties, and reactions

  摘要：

  DOI：

  10.1021/jo01260a005

文献信息

• Trimethylsilylated N- alkyl-substituted carbamates I.preparation and some reactions
  作者：Dezsö Knausz、Aranka Meszticzky、L′aszl′o Szak′acs、B′ela Cs′akv′ari、K′alm′an Ujsz′aszy

  DOI：10.1016/s0022-328x(00)99291-x

  日期：1983.11

  ammonium carbamates with trimethylchlorosilane. Trimethylsilyl NN-dimethylcarbamate can be used for silylation of alcohols,phenols, and carboxylic acids. The silycarbamates react with carboxylic acid halides to give the corresponding acide amides. The reaction of trimethylsilyl carbamates with carboxylic anhydrides give the corresponding silyl carboxylate and acid amide, while the reaction with dicarboxylic

  三甲基甲硅烷Ñ -monoalkyl-和Ñ，Ñ二烷基-氨基甲酸酯已在85-95％的收率由相应的氨基甲酸铵与三甲基氯硅烷的甲硅烷基化制备。三甲基甲硅烷基N N-二甲基氨基甲酸酯可用于醇，酚和羧酸的甲硅烷基化。甲硅烷基氨基甲酸酯与羧酸卤化物反应，得到相应的酸酰胺。氨基甲酸三甲基甲硅烷基酯与羧酸酐的反应生成相应的甲硅烷基羧酸酯和酰胺，而与二羧酸酐的反应生成相应的二羧酸的三甲基甲硅烷基单酰胺，即Me 3 SiO 2 -CCONR 1 R2。
• Ink Composition for Optoelectronic Device
  申请人：Chung Kwang Choon

  公开号：US20110024668A1

  公开（公告）日：2011-02-03

  The present invention relates to an ink composition for printing capable of inking materials for an optoelectronic device and directly applying the inked materials to a patterning process. More particularly, the present invention relates to a printing ink composition for manufacturing an optoelectronic device capable of direct patterning by adjusting the physical property of a core material so as to be suitable for a printing method in the manufacturing of optoelectronic devices, for example, an organic electroluminescent device or an organic thin film transistor.

  本发明涉及一种适用于打印的油墨组合物，能够为光电器件的材料进行上墨，并将上墨材料直接应用于图案化工艺。更具体地说，本发明涉及一种打印油墨组合物，用于制造一种光电器件，通过调整核心材料的物理特性，使其适合于光电器件制造中的打印方法，例如有机电致发光器件或有机薄膜晶体管的直接图案化。
• 1,3-Dialkyl-2-imidazolidinones and a manufacturing process therefor
  申请人：MITSUI CHEMICALS, INC.

  公开号：EP0992497A1

  公开（公告）日：2000-04-12

  1,3-dialkyl-2-imidazolidinones are made by a process involving a direct one-step reaction from industrially available alkylene carbonate, N-alkylethanolamine or 1,2-diol; the process can minimize formation of solid material and can be readily conducted in a large-scale industrial production with high yield and few byproducts. The process is characterized in that alkylene carbonate, N-alkylethanolamine or 1,2-diol is reacted with monoalkylamine and carbon dioxide, alkylcarbamate alkylamine salt, and/or 1,3-dialkyurea, by heating them at 50°C or higher in a reactor whose area in contact with at least part of the reactants and/or products is made of a metal comprising titanium or zirconium and/or an oxide thereof, or an inorganic glass.

  1,3-二烷基-2-咪唑烷酮是由工业上可获得的碳酸亚烷基酯、N-烷基乙醇胺或 1,2-二醇直接一步反应制得的；该工艺可最大限度地减少固体物质的形成，并易于进行大规模工业生产，产量高，副产品少。该工艺的特点是：碳酸亚烷基酯、N-烷基乙醇胺或 1,2-二醇与单烷基胺和二氧化碳、烷基氨基甲酸酯烷基胺盐和/或 1,3-二基脲在 50°C 或更高温度下在反应器中加热反应，反应器与至少部分反应物和/或产物接触的区域由钛或锆和/或其氧化物组成的金属或无机玻璃制成。
• 1,3-dialkyl-2-imidazolidinones and a manufacturing process therefor
  申请人：MITSUI CHEMICALS, INC.

  公开号：EP1148051A2

  公开（公告）日：2001-10-24

  1,3-dialkyl-2-imidazolidinones are made by a process involving a direct one-step reaction from industrially available alkylene carbonate, N-alkylethanolamine or 1,2-diol; the process can minimize formation of solid material and can be readily conducted in a large-scale industrial production with high yield and few byproducts. The process is characterized in that alkylene carbonate, N-alkylethanolamine or 1,2-diol is reacted with monoalkylamine and carbon dioxide, alkylcarbamate alkylamine salt, and/or 1,3-dialkyurea, by heating them at 50°C or higher in a reactor whose area in contact with at least part of the reactants and/or products is made of a metal comprising titanium or zirconium and/or an oxide thereof, or an inorganic glass.

  1,3-二烷基-2-咪唑烷酮是由工业上可获得的碳酸亚烷基酯、N-烷基乙醇胺或 1,2-二醇直接一步反应制得的；该工艺可最大限度地减少固体物质的形成，并易于进行大规模工业生产，产量高，副产品少。该工艺的特点是：碳酸亚烷基酯、N-烷基乙醇胺或 1,2-二醇与单烷基胺和二氧化碳、烷基氨基甲酸酯烷基胺盐和/或 1,3-二基脲在 50°C 或更高温度下在反应器中加热反应，反应器与至少部分反应物和/或产物接触的区域由钛或锆和/或其氧化物组成的金属或无机玻璃制成。
• Process for preparation of silver nanoparticles, and the compositions of silver ink containing the same
  申请人：Inktec Co., Ltd.

  公开号：EP2752470A1

  公开（公告）日：2014-07-09

  The present invention relates to a process for preparation of silver complex compound and the compositions of silver ink containing the same. The present invention includes a) preparing silver complex compound with special structure by reacting silver compound with at least one or two mixtures selected from ammonium carbamate compound, ammonium carbonate compound or ammonium bicarbonate compound and b) preparing silver nanoparticles by reacting the silver complex compound with reducer or reducing or pyrolyzing the silver complex compound by applying heat thereto. The preparing method according to the present invention can prepare the silver nanoparticles with various shapes through a simple preparation process, improve the selectivity of the size of the silver complex compound, fire the silver complex compound even when it is fired at a low temperature of 150 °C or less during a short time, provide the ink compositions capable of forming the coating or the fine pattern showing the high conductivity while facilitating the thickness control of the coating, and provide the ink compositions capable of being applied to the reflective film material, the electromagnetic wave shield, and the antimicrobial agent, etc.

  本发明涉及一种制备银络合物和含有银络合物的银墨组合物的工艺。 本发明包括 a) 通过银化合物与至少一种或两种选自氨基甲酸铵化合物、碳酸铵化合物或碳酸氢铵化合物的混合物反应，制备具有特殊结构的银络合物；b) 通过银络合物与还原剂反应，或通过加热还原或热解银络合物，制备银纳米粒子。 根据本发明的制备方法，可以通过简单的制备工艺制备出各种形状的银纳米粒子，提高了银络合物尺寸的选择性，即使在 150 ℃ 或更低的低温下短时间内烧制银络合物，也能使油墨组合物形成涂层或显示高导电性的精细图案，同时便于控制涂层的厚度，并使油墨组合物能够应用于反射膜材料、电磁波屏蔽和抗菌剂等。