1,8-Diacetylnaphthalin | 10371-76-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1,8-Diacetylnaphthalin
• 英文别名: 1,8-diacetylnaphthalene；1-(8-acetylnaphthalen-1-yl)ethanone
• CAS: 10371-76-3
• 化学式: C₁₄H₁₂O₂
• 分子量: 212.248
• InChiKey: FQORHEMAUBKTGC-UHFFFAOYSA-N

物化性质

• 熔点：
  169-172 °C
• 沸点：
  374.6±15.0 °C(Predicted)
• 密度：
  1.137±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,8-Diacetylnaphthalin 在 lithium aluminium tetrahydride 作用下， 生成 2.6-Dimethyl-2-hydroxy-3.4.5-(1.8-naphtho)-oxacyclohexan
  参考文献：
  名称：

  Synthesis and Cyclopolymerization of 1,8-Divinylnaphthalene

  摘要：

  DOI：

  10.1021/jo01045a050
• 作为产物：
  描述：

  1,2-dimethylacenaphthylene-1,2-diol 在 lead(IV) acetate 、 苯 作用下， 生成 1,8-Diacetylnaphthalin
  参考文献：
  名称：

  Criegee; Kraft; Rank, Justus Liebigs Annalen der Chemie, 1933, vol. 507, p. 159,167

  摘要：

  DOI：

文献信息

• AROMATIC IMIDE COMPOUND AND METHOD FOR PRODUCING SAME
  申请人：AZ ELECTRONIC MATERIALS (LUXEMBOURG) S.A.R.L.

  公开号：US20150299132A1

  公开（公告）日：2015-10-22

  [Problem] to provide an aromatic imide compound wherein the sensitivity for visible light such as g-line, h-line etc. is increased and solubility is also improved. [Means for solving problem] The aromatic imide compound of the invention is a compound represented by the formula (1) below (in the formula, R 1 represents a haloalkyl group having 1 to 7 carbon atoms or a haloaryl group, R 2 represents a group containing a substituted or unsubstituted, aliphatic or aromatic group which may have a heteroatom, and adjacent R 2 s may form an imido group by connecting each other, R 3 represent a halogen atom or a hydrocarbon group, m is zero or an integer of 1 or more, n is zero or an integer of 1 or more, and a sum of n and m is 1 to 6). These compounds are obtained by following processes. A halogenated naphtharic anhydride is reacted with an aromatic group-containing hydrocarbon such as ethynylbenzene to prepare a naphthalic anhydride substituted by an aromatic group-containing group. The obtained compound is then reacted with hydroxylamine hydrochloride to be made N-hydoxyimidization. Finally, the resultant compound is reacted with a sulfonyl halide such as trifluoromethylsulfonyl chloride to obtain the objective compound.

  [问题] 提供一种芳香酰亚胺化合物，其中对于可见光如g线、h线等的敏感性增加，溶解度也得到改善。 [解决问题的方法] 本发明的芳香酰亚胺化合物是以下式(1)所表示的化合物(在该式中，R1表示具有1至7个碳原子的卤代烷基或卤代芳基，R2表示含有取代或未取代的脂肪族或芳香族基团，该基团可能具有杂原子，相邻的R2可以通过连接形成亚胺基团，R3表示卤素原子或碳氢基团，m为0或1或更多的整数，n为0或1或更多的整数，n和m的总和为1至6)。这些化合物是通过以下过程获得的。将卤代萘酐与含芳香族基团的烃类化合物如乙炔基苯反应，制备出被芳香族基团取代的萘酐。然后将获得的化合物与盐酸羟胺反应，得到N-羟基亚胺。最后，将所得化合物与三氟甲磺酰卤如三氟甲磺酰氯反应，得到目标化合物。
• Photosensitizers and polymerizable compositions
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0260877A2

  公开（公告）日：1988-03-23

  This invention describes the preparation of some new Mannich polymers and copolymers and teaches their general use as photosensitizers for onium salts for use in the initiation of free radical polymerization of vinyl monomers. These Mannich polymers are unexpectedly more efficient as photosensitizers than are the non-polymeric photosensitizers.

  本发明描述了一些新型曼尼希聚合物和共聚物的制备方法，并教授了它们作为鎓盐光敏剂的一般用途，用于引发乙烯基单体的自由基聚合。这些曼尼希聚合物作为光敏剂的效率出乎意料地高于非聚合物光敏剂。
• Triazine photoinitiators in a ternary system for addition polymerization
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0369645A1

  公开（公告）日：1990-05-23

  Photocurable addition-polymerizable compositions containing a free-radically-polymerizable monomer and a photoinitiator system containing i) a trihalomethyl substituted-s-triazine ii) a sensitizing compound, and iii) an electron donor having an oxidation potential that is greater than zero and less than or equal to that of p-dimethoxybenzene (1.32 volts vs. S.C.E.). The compositions cure rapidly and deeply under ultraviolet or visible light.

  可光固化的加成聚合组合物，含有可自由基聚合的单体和光引发剂体系，光引发剂体系含有 i) 三卤甲基取代-s-三嗪 ii) 增感化合物和 iii) 电子供体，电子供体的氧化电位大于零，小于或等于对二甲氧基苯的氧化电位（1.32 伏对 S.C.E.）。在紫外线或可见光的照射下，组合物可以快速而深入地固化。
• High speed photopolymerizable printing plate with initiator in a topcoat
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0403096A2

  公开（公告）日：1990-12-19

  A high speed photopolymerization negative-acting printing plate containing a layer comprising a photo­sensitized polymerization initiator and polymerizable ethylenically unsaturated compound, exhibits higher speed and good shelf life when at least 20% by weight of the total initiator is situated in an oxygen barrier top coat. Addition of p-substituted-N-disubstituted-anilines to the polymerizable layer gives further improvement in stability.

  一种高速光聚合负作用印版含有一层由光敏化聚合引发剂和可聚合乙烯基不饱和化合物组成的层，当总引发剂重量的至少 20% 位于隔氧层表层时，该印版的速度更快，保存期更长。在可聚合层中加入对取代-N-二取代苯胺可进一步提高稳定性。
• Radiation curable composition, process of production and use thereof
  申请人：3M Innovative Properties Company

  公开号：EP2380925A1

  公开（公告）日：2011-10-26

  The present invention relates to a radiation curable composition comprising (A) a cationically hardenable compound comprising at least one aziridine moiety, and (B) a radiation sensitive starter, the radiation sensitive starter comprising an onium salt, a ferrocenium salt, a combination or mixture thereof.

  本发明涉及一种可辐射固化的组合物，该组合物包含（A）阳离子可硬化化合物，该化合物包含至少一个氮丙啶分子；以及（B）辐射敏感起始剂，该辐射敏感起始剂包含鎓盐、二茂铁盐、它们的组合或混合物。