1,3,3,6,6,8,11,13,13,16,16,18-dodecamethyl-1,2,7,8,11,12,17,18-octaaza-3,6,13,16-tetrasilacycloicosane | 1060689-70-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氮杂环化合物
• 英文名称: 1,3,3,6,6,8,11,13,13,16,16,18-dodecamethyl-1,2,7,8,11,12,17,18-octaaza-3,6,13,16-tetrasilacycloicosane
• CAS: 1060689-70-4
• 化学式: C₂₀H₅₆N₈Si₄
• 分子量: 521.06
• InChiKey: YAZONYCIBXHGLY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.57
• 重原子数：
  32.0
• 可旋转键数：
  0.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  61.08
• 氢给体数：
  4.0
• 氢受体数：
  8.0

反应信息

• 作为反应物：
  描述：

  1,3,3,6,6,8,11,13,13,16,16,18-dodecamethyl-1,2,7,8,11,12,17,18-octaaza-3,6,13,16-tetrasilacycloicosane 、 二氧化碳 反应 2.0h， 以97%的产率得到2,2,5,5,9,12,16,16,19,19,23,26-dodecamethyl-1,6,15,20-tetraoxa-8,9,12,13,22,23,26,27-octaaza-2,5,16,19-tetrasilacyclooctacosane-7,14,21,28-tetraone
  参考文献：
  名称：

  Hydrazine derivatives in the synthesis of linear and heterocyclic compounds

  摘要：

  N-Siloxycarbonylation, transamination, carboxylation, silylation, and condensation of N,N-dimethylhydrazine, 1-methyl-1-[2-(1-methylhydrazino)ethyl]hydrazine, N-methyl-2-(1-methylhydrazino)ethanamine, and some their trimethylsilyl derivatives resulted in the formation of previously unknown linear and heterocyclic compounds.

  DOI：

  10.1134/s1070363207110126
• 作为产物：
  描述：

  1,2-双(氯二甲基硅基)乙烷 、 1-methyl-1-[2-(1-methylhydrazino)ethyl]hydrazine 在 三乙胺 作用下， 以 苯 为溶剂， 以79%的产率得到1,3,3,6,6,8,11,13,13,16,16,18-dodecamethyl-1,2,7,8,11,12,17,18-octaaza-3,6,13,16-tetrasilacycloicosane
  参考文献：
  名称：

  Hydrazine derivatives in the synthesis of linear and heterocyclic compounds

  摘要：

  N-Siloxycarbonylation, transamination, carboxylation, silylation, and condensation of N,N-dimethylhydrazine, 1-methyl-1-[2-(1-methylhydrazino)ethyl]hydrazine, N-methyl-2-(1-methylhydrazino)ethanamine, and some their trimethylsilyl derivatives resulted in the formation of previously unknown linear and heterocyclic compounds.

  DOI：

  10.1134/s1070363207110126