N,N,N',N'-tetrakis(3-aminopropyl)-3,9-bis(aminopropyl)-2,4,8,10-tetraoxaspiro[5.5]undecane | 901792-16-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二恶烷
• 英文名称: N,N,N',N'-tetrakis(3-aminopropyl)-3,9-bis(aminopropyl)-2,4,8,10-tetraoxaspiro[5.5]undecane
• 英文别名: N'-(3-aminopropyl)-N'-[3-[3-[3-[bis(3-aminopropyl)amino]propyl]-2,4,8,10-tetraoxaspiro[5.5]undecan-9-yl]propyl]propane-1,3-diamine
• CAS: 901792-16-3
• 化学式: C₂₅H₅₄N₆O₄
• 分子量: 502.742
• InChiKey: NKGDUTBQEDWYOH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.2
• 重原子数：
  35
• 可旋转键数：
  20
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  148
• 氢给体数：
  4
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  2-chloro-4,6-bis(N-butyl-2,2,6,6-tetramethyl-4-piperidinylamino)-1,3,5-triazine 、 N,N,N',N'-tetrakis(3-aminopropyl)-3,9-bis(aminopropyl)-2,4,8,10-tetraoxaspiro[5.5]undecane 以 1,3-二甲基-2-咪唑啉酮 为溶剂， 反应 5.0h， 生成 6-N-[3-[3-[3-[3-[bis[3-[[4,6-bis[butyl-(2,2,6,6-tetramethylpiperidin-4-yl)amino]-1,3,5-triazin-2-yl]amino]propyl]amino]propyl]-2,4,8,10-tetraoxaspiro[5.5]undecan-9-yl]propyl-[3-[[4,6-bis[butyl-(2,2,6,6-tetramethylpiperidin-4-yl)amino]-1,3,5-triazin-2-yl]amino]propyl]amino]propyl]-2-N,4-N-dibutyl-2-N,4-N-bis(2,2,6,6-tetramethylpiperidin-4-yl)-1,3,5-triazine-2,4,6-triamine
  参考文献：
  名称：

  EP1840127

  摘要：

  公开号：
• 作为产物：
  描述：

  N,N,N',N'-tetrakis(2-cyanoethyl)-3,9-bis(aminopropyl)-2,4,8,10-tetraoxaspiro[5.5]undecane 在 Raney Co 氢气 作用下， 以 1,4-二氧六环 为溶剂， 180.0 ℃ 、8.0 MPa 条件下， 反应 2.0h， 生成 N,N,N',N'-tetrakis(3-aminopropyl)-3,9-bis(aminopropyl)-2,4,8,10-tetraoxaspiro[5.5]undecane
  参考文献：
  名称：

  EP1840127

  摘要：

  公开号：

文献信息

• Polyamine Derivative and Polyol Derivative
  申请人：Mita Naruyoshi

  公开号：US20080230743A1

  公开（公告）日：2008-09-25

  A novel polyamine derivative, or polyol derivative, having a piperidylaminotriazine skeleton; salts of such compounds; a process for producing them; an organic material stabilizer comprising any of such compounds; a method of stabilizing an organic material; and a stabilized organic material. Compounds of the general formula: (1) (wherein X is N(R 4 ) or an oxygen atom; R 1 is an n-valent hydrocarbon group; R 2 is a hydrogen atom or an alkyl; R 3 is a hydrogen atom, an alkyl, an alkoxy or an acyl; R 4 is a hydrogen atom or an alkyl; and n is an integer of 3 to 16) are effective in the stabilization of an organic material against deterioration by light, heat, oxygen, ozone and electromagnetic waves, such as X-rays and γ-rays.

  一种新型的聚胺衍生物或聚醇衍生物，具有哌啶基氨基三嗪骨架；这些化合物的盐；一种生产它们的过程；包括上述任何一种化合物的有机材料稳定剂；一种稳定有机材料的方法；以及稳定的有机材料。通式（1）的化合物：（其中X是N（R4）或氧原子；R1是n价碳氢基团；R2是氢原子或烷基；R3是氢原子，烷基，烷氧基或酰基；R4是氢原子或烷基；n是3至16的整数）对于稳定有机材料免受光，热，氧，臭氧和电磁波（如X射线和γ射线）的损害非常有效。
• Polyamine derivative and polyol derivative
  申请人：BASF SE

  公开号：US08076478B2

  公开（公告）日：2011-12-13

  A novel polyamine derivative, or polyol derivative, having a piperidylaminotriazine skeleton; salts of such compounds; a process for producing them; an organic material stabilizer comprising any of such compounds; a method of stabilizing an organic material; and a stabilized organic material. Compounds of the general formula: (1) (wherein X is N(R4) or an oxygen atom; R1 is an n-valent hydrocarbon group; R2 is a hydrogen atom or an alkyl; R3 is a hydrogen atom, an alkyl, an alkoxy or an acyl; R4 is a hydrogen atom or an alkyl; and n is an integer of 3 to 16) are effective in the stabilization of an organic material against deterioration by light, heat, oxygen, ozone and electromagnetic waves, such as X-rays and γ-rays.

  一种新型的聚胺衍生物或聚醇衍生物，具有哌啶基氨基三嗪骨架；这些化合物的盐；一种生产它们的过程；包括任何这些化合物的有机材料稳定剂；一种稳定有机材料的方法；以及稳定的有机材料。一般式化合物：(1)（其中X是N（R4）或氧原子；R1是n价碳氢基团；R2是氢原子或烷基；R3是氢原子，烷基，烷氧基或酰基；R4是氢原子或烷基；n是3至16的整数）对于通过光，热，氧气，臭氧和电磁波（如X射线和γ射线）的恶化稳定有机材料有效。
• POLYAMINE DERIVATIVE AND POLYOL DERIVATIVE
  申请人：MITA NARUYOSHI

  公开号：US20120053270A1

  公开（公告）日：2012-03-01

  A novel polyamine derivative, or polyol derivative, having a piperidylaminotriazine skeleton; salts of such compounds; a process for producing them; an organic material stabilizer comprising any of such compounds; a method of stabilizing an organic material; and a stabilized organinc material. Compounds of the general formula: (1) (wherein X is N(R 4 ) or an oxygen atom; R 1 is an n-valent hydrocarbon group; R 2 is an hydrogen atom or an alkyl; R 3 is a hydrogen atom, an alkyl, an alkoxy or an acyl; R 4 is a hydrogen atom or an alkyl; and n is an integer of 3 to 16) are effective in the stabilization of an organic material against deterioration by light, heat, oxygen, ozone and electromagnetic waves, such as X-rays and γ-rays.

  一种新型的聚胺衍生物或聚醇衍生物，具有哌啶基氨基三嗪骨架；这些化合物的盐；一种生产它们的过程；包括任何此类化合物的有机材料稳定剂；一种稳定有机材料的方法；以及一种稳定的有机材料。通式为（1）的化合物：（其中X是N（R4）或氧原子；R1是n价碳氢基团；R2是氢原子或烷基；R3是氢原子、烷基、烷氧基或酰基；R4是氢原子或烷基；n是3到16的整数）对于通过光、热、氧、臭氧和电磁波（如X射线和γ射线）恶化的有机材料的稳定化是有效的。
• Polyamine derivative
  申请人：BASF SE

  公开号：EP2484677A1

  公开（公告）日：2012-08-08

  A compound represented by general formula (1) wherein X represents N(R4), R1 is a group selected from a general formula (2-2): wherein R5 represents a m-valent hydrocarbon group, provided that a nitrogen atom or an oxygen atom may be contained in the hydrocarbon group R5, m represents an integer of from 2 to 8 and d represents an integer of from 1 to 6, R2 represents a hydrogen atom or an alkyl group having from 1 to 9 carbon atoms, R3 represents a hydrogen atom, an alkyl group having from 1 to 9 carbon atoms, an alkoxy group having from 1 to 9 carbon atoms or an acyl group having from 2 to 9 carbon atoms, R4 represents a hydrogen atom or an alkyl group having from 1 to 9 carbon atoms and n represents an integer of from 3 to 16, or its salt is suitable as stabilizer for organic material.

  通式(1)代表的化合物 其中 X 代表 N(R4)，R1 是选自通式（2-2）的基团： 其中 R5 代表 m 价烃基，条件是烃基 R5 中可能含有氮原子或氧原子，m 代表 2 至 8 的整数，d 代表 1 至 6 的整数、 R2 代表氢原子或具有 1 至 9 个碳原子的烷基，R3 代表氢原子、具有 1 至 9 个碳原子的烷基、具有 1 至 9 个碳原子的烷氧基或具有 2 至 9 个碳原子的酰基，R4 代表氢原子或具有 1 至 9 个碳原子的烷基，n 代表 3 至 16 的整数、 或其盐类可用作有机材料的稳定剂。
• US8076478B2
  申请人：——

  公开号：US8076478B2

  公开（公告）日：2011-12-13