9-丁基-10-氯甲基蒽 | 102019-49-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 中文名称: 9-丁基-10-氯甲基蒽
• 英文名称: 9-Butyl-10-chlormethyl-anthracen
• 英文别名: 9-butyl-10-(chloromethyl)anthracene
• CAS: 102019-49-8
• 化学式: C₁₉H₁₉Cl
• 分子量: 282.813
• InChiKey: FZOQHAMKTBGTPN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.07
• 重原子数：
  20.0
• 可旋转键数：
  4.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.26
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  9-丁基-10-氯甲基蒽 在 硫酸 作用下， 生成 3-<9-Butyl-10-anthryl>-propionsaeure-methylester
  参考文献：
  名称：

  Stewart,F.H.C., Australian Journal of Chemistry, 1960, vol. 13, p. 478 - 487

  摘要：

  DOI：
• 作为产物：
  描述：

  10-丁基-9-甲醛-蒽 在 sodium tetrahydroborate 、 氯化亚砜 作用下， 以 乙二醇乙醚 为溶剂， 生成 9-丁基-10-氯甲基蒽
  参考文献：
  名称：

  Stewart,F.H.C., Australian Journal of Chemistry, 1960, vol. 13, p. 478 - 487

  摘要：

  DOI：

文献信息

• Synthesis and characterization of anthracene-clustering dendrimers: observation of fluorescence resonance energy transfer in the multichromophoric system
  作者：Masaki Takahashi、Hironao Morimoto、Yousuke Suzuki、Tomoya Odagi、Mitsuji Yamashita、Hideki Kawai

  DOI：10.1016/j.tet.2004.09.096

  日期：2004.12

  A series of anthracene-clustering dendrimers bearing various aliphatic substituents at the terminal positions were synthesized using a direct coupling strategy. A remarkable effect of the side chains was imparted to chemical properties of the dendrimers such as drastically increased solubility. Although the multibranched anthracene arrays in the dendritic architectures exhibited no cooperativity in terms of the absorption feature and behaved as single chromophoric systems, investigations focusing on fluorescence properties revealed that a type of cooperativity was present as expressed in the reduced quantum yields of fluorescence. An alternative approach utilizing time-resolved fluorescence decay measurements clearly demonstrated that the most reasonable mechanism of the cooperative action should involve two discernible channels of intramolecular fluorescence resonance energy transfer (FRET) occurring from one chromophore to the others within and across junctions of the branching units. (C) 2004 Elsevier Ltd. All rights reserved.
• The Action of Methylmagnesium Iodide on some Chloromethyl Substituted Anthracenes
  作者：FHC Stewart

  DOI：10.1071/ch9610177

  日期：——