2-Trichlorsilylbicyclo<2.2.1>hepta-2.5-dien | 27544-86-1

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 英文名称: 2-Trichlorsilylbicyclo<2.2.1>hepta-2.5-dien
• 英文别名: 2-bicyclo[2.2.1]hepta-2,5-dienyl(trichloro)silane
• CAS: 27544-86-1
• 化学式: C₇H₇Cl₃Si
• 分子量: 225.577
• InChiKey: VKZYEQCVOLNWLV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.31
• 重原子数：
  11.0
• 可旋转键数：
  1.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  2-Trichlorsilylbicyclo<2.2.1>hepta-2.5-dien 在 copper (II)-fluoride 作用下， 以27%的产率得到2-trifluorosilylnorbornadiene
  参考文献：
  名称：

  有机合成中的硅官能化合物：XVIII。烯基氟硅烷中硅碳键的氧化裂解为羰基化合物：合成和机理方面

  摘要：

  烯基三氟硅烷很容易在DMF中被一当量的MCPBA氧化，即使在-50°C下也可以通过碳-硅键的断裂得到相应的羰基化合物。在三当量的MCPBA的作用下，碳碳键随之断裂。已经讨论了这些新型氧化的合理机理。还描述了用DABCO·2H 2 O 2氧化。

  DOI：

  10.1016/0022-328x(83)85112-2
• 作为产物：
  描述：

  trichlorosilylacetylene 、 环戊二烯 以60%的产率得到2-Trichlorsilylbicyclo<2.2.1>hepta-2.5-dien
  参考文献：
  名称：

  Highly permeable polymer materials based on silicon-substituted norbornenes

  摘要：

  An approach to the manufacture of highly permeable polymers based on the synthesis and polymerization of norbornenes, norbornadienes, and tricyclononenes with different numbers and different positions of silicon-containing substituents has been developed. It has been found that these monomers are readily involved in metathesis polymerization yielding high-molecular-mass polymers possessing good filmforming properties. The addition (vinyl) polymerization of norbornenes is a more complex process; however, the product silylated polynorbornenes exhibit a higher gas permeability than the corresponding metathesis polynorbornenes. By the level of the gas-transport parameters, the silylated addition polynorbornenes obtained in the study are grouped with the most advanced high-permeability polymers. It has been shown that the presence of Me3Si substituent groups, their amount, and the main-chain structure are responsible for the enhancement of the gas permeability of polynorbornenes. Thus, a series of polymers with a regularly changing structure has been obtained, a result that makes it possible to reveal the polymer structure-property relations.

  DOI：

  10.1134/s0965544110050063

文献信息

• Diels--Alder reaction of .alpha.,.beta.-unsaturated trihalosilanes with cyclopentadiene
  作者：Robert F. Cunico

  DOI：10.1021/jo00806a015

  日期：1971.4
• TAMAO, KOHEI;AKITA, MUNETAKA;KUMADA, MAKOTO, J. ORGANOMET. CHEM., 1983, 254, N 1, 13-22
  作者：TAMAO, KOHEI、AKITA, MUNETAKA、KUMADA, MAKOTO

  DOI：——

  日期：——