diethylamino-3 thiophene | 106943-95-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: diethylamino-3 thiophene
• 英文别名: 3-(diethylamino)thiophene；N,N-diethylthiophen-3-amine
• CAS: 106943-95-7
• 化学式: C₈H₁₃NS
• 分子量: 155.264
• InChiKey: ZVYOEIHDJVMPHT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  10
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  31.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  N-(3-噻吩基)乙酰胺 在 lithium aluminium tetrahydride 作用下， 以 乙醚 为溶剂， 反应 19.0h， 生成 diethylamino-3 thiophene
  参考文献：
  名称：

  Outurquin, Francis; Lerouge, Patrice; Paulmier, Claude, Bulletin de la Societe Chimique de France, 1986, # 2, p. 259 - 266

  摘要：

  DOI：

文献信息

• Electrically conductive material and a process for the preparation of same and secondary battery using the electrically conductive material
  申请人：SANYO ELECTRIC CO., LTD.

  公开号：EP0261837A2

  公开（公告）日：1988-03-30

  New electrically conductive material suitable particularly for a secondary battery and a process for preparing the electrically conductive material are provided. The process for the preparation of the electrically conductive material comprises the steps of reacting a compound having conjugated double bonds with an oxidizing agent wherein the oxidizing agent comprises a cupric compound and a nitrile compound. The electrically conductive material comprises grainy polypyrrole obtained by reacting a pyrrole compound with an oxidizing agent which is constituted by primary particles having an average particle size of 0.01 to 0.4 µm and has a press molding density of 1 to 1.6 g/cm³.

  本发明提供了特别适用于二次电池的新型导电材料以及制备该导电材料的工艺。 制备该导电材料的工艺包括以下步骤：使具有共轭双键的化合物与氧化剂反应，其中氧化剂包括铜化合物和腈化合物。 该导电材料包括通过使吡咯化合物与氧化剂反应而获得的粒状聚吡咯，该聚吡咯由平均粒径为 0.01 至 0.4 微米的初级颗粒构成，其压制成型密度为 1 至 1.6 克/立方厘米。
• A mild and practical copper catalyzed amination of halothiophenes
  作者：Zhikuan Lu、Robert J. Twieg

  DOI：10.1016/j.tet.2004.11.017

  日期：2005.1

  We have found that N,N-dimethylethanolamine (deanol) is a useful solvent and ligand for copper catalyzed amination of a variety of unactivated and activated 2- or 3-halothiophenes. Primary amines, acyclic secondary amines, cyclic secondary amines and acyclic secondary amines with 2-hydroxyethyl functionality react with halothiophenes in moderate to excellent yields. The mildly basic conditions utilized are compatible with many functional groups. The animation of halobithiophenes has also been examined. The aminothiophenes produced by this method are important intermediates in a variety of electronic and optoelectronic materials. (C) 2004 Elsevier Ltd. All rights reserved.
• OUTURQUIN, F.;LEROUGE, P.;PAULMIER, C., BULL. SOC. CHIM. FR., 1986, N 2, 259-266
  作者：OUTURQUIN, F.、LEROUGE, P.、PAULMIER, C.

  DOI：——

  日期：——
• Process for the preparation of electrically conductive material
  申请人：SANYO ELECTRIC CO., LTD.

  公开号：EP0261837B1

  公开（公告）日：2001-07-11
• US4795687A
  申请人：——

  公开号：US4795687A

  公开（公告）日：1989-01-03