2,3-Dihydro-1H-benzinden-1-ol | 16194-92-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 2,3-Dihydro-1H-benzinden-1-ol
• 英文别名: 6,7-Benzo-indanol-(1)；Benzindanol；2,3-dihydro-1H-cyclopenta[a]naphthalen-1-ol
• CAS: 16194-92-6
• 化学式: C₁₃H₁₂O
• 分子量: 184.238
• InChiKey: HMDUFJHTFREFSA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.23
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2,3-Dihydro-1H-benzinden-1-ol 在 4-甲基苯磺酸吡啶 作用下， 以 1,2-二氯乙烷 为溶剂， 反应 12.0h， 以1.0 g的产率得到3H-苯并[E]茚
  参考文献：
  名称：

  铜催化对苯二酚盐对烯丙醇的对映体选择性多米诺烯化/ Semipinacol重排

  摘要：

  选择性芳基化和转移：铜催化的烯丙醇与二芳基碘鎓盐的对映选择性芳基半频醇重排提供了螺环烷酮，产率高至高，非对映选择性和对映选择性高。

  DOI：

  10.1002/chem.201703563
• 作为产物：
  描述：

  1-oxo-2,3-dihydro-1H-cyclopenta[a]naphthalene-3-carboxylic acid 在 lithium aluminium tetrahydride 作用下， 生成 2,3-Dihydro-1H-benzinden-1-ol
  参考文献：
  名称：

  Marechal,E.; Chaintron,G., Bulletin de la Societe Chimique de France, 1967, p. 987 - 992

  摘要：

  DOI：

文献信息

• [EN] LIGANDS AND CATALYSTS FOR PRODUCING ELASTOMERIC PROPYLENE POLYMERS<br/>[FR] LIGANDS ET CATALYSEURS DESTINES A LA PRODUCTION DE POLYMERES DE PROPYLENE ELASTOMERES
  申请人：BP AMOCO CORP

  公开号：WO2000035975A1

  公开（公告）日：2000-06-22

  A ligand useful to form a metallocene olefin polymerization catalyst comprises formula (I), wherein at least R3 and R4 are substituents having at least a bulk of a t-butyl group and, optionally, wherein R1 or R2 may be a bulky substituent group.

  一种用于形成金属茂咯烯催化剂的配体包括公式（I），其中至少R3和R4是具有至少一个叔丁基团体积的取代基，而且可选地，R1或R2可能是一个笨重的取代基团体。
• Catalysts for olefin polymerization and a process for preparing olefin
  申请人：Mitsubishi Chemical Corporation

  公开号：US05942459A1

  公开（公告）日：1999-08-24

  The object of the present invention is to provide a polyolefin having a good particle property in a high yield without use of an expensive alumoxane. The present invention comprises a catalyst for olefin polymerization comprising the following ingredients (A), (B) and (C), and a process for preparing an olefin polymer with use of the catalyst: Component (A): a transition metal compound having at least one conjugated five-membered ring ligand, the transition metal being in the Groups IV-VI of the Periodic Table, Component (B): an organoaluminum compound, and Component (C): a finely divided particle composition comprising 0.1-99.9% by weight of boric acid.

  本发明的目的是提供一种聚烯烃，其具有良好的颗粒特性，且不需要使用昂贵的氧化铝。本发明包括用于烯烃聚合的催化剂，该催化剂包括以下成分（A）、（B）和（C），以及使用该催化剂制备烯烃聚合物的方法：组分（A）：至少具有一个共轭五元环配体的过渡金属化合物，该过渡金属位于周期表的IV-VI族，组分（B）：有机铝化合物，以及组分（C）：包含0.1-99.9重量％硼酸的细粉末组成。
• LIGANDS AND CATALYSTS FOR PRODUCING ELASTOMERIC PROPYLENE POLYMERS
  申请人：BP Corporation North America Inc.

  公开号：EP1157047B1

  公开（公告）日：2003-04-23
• Enediyne- and Tributyltin Hydride-Mediated Aryl Radical Additions onto Various Radical Acceptors
  作者：Janet Wisniewski Grissom、Detlef Klingberg、Sabine Meyenburg、Brenda L. Stallman

  DOI：10.1021/jo00104a053

  日期：1994.12

  Tandem enediyne-radical cyclizations were carried out on substrates that contain nitrile and ketone radical accepters. The products of these cyclizations and the previously reported tandem enediyne-radical cyclizations containing aldehyde and oxime ether radical accepters were compared with tributyltin hydride-mediated aryl radical addition reactions with 1-bromonaphthalene derivatives containing aldehyde, oxime ether, nitrile, and ketone radical accepters, since these substrates go through similar initial radical intermediates. Although many of the same products were observed using either method of aryl radical generation, there were distinct differences in the product composition and identity depending on which method was used. These differences can probably be primarily attributed to the temperature difference of the two modes of radical generation.
• Brown, Roger F. C.; Eastwood, Frank W.; Smith, Cameron J., Australian Journal of Chemistry, 1992, vol. 45, # 8, p. 1315 - 1320
  作者：Brown, Roger F. C.、Eastwood, Frank W.、Smith, Cameron J.

  DOI：——

  日期：——