Natrium-cyclohexanon-oximat | 40398-42-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Natrium-cyclohexanon-oximat
• 英文别名: cyclohexanone oxime ; sodium-compound；Cyclohexanon-oxim; Natrium-Verbindung；sodium;N-oxidocyclohexanimine
• CAS: 40398-42-3
• 化学式: C₆H₁₀NO*Na
• 分子量: 135.141
• InChiKey: YJCLYUSMQCSYHY-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -1.11
• 重原子数：
  9.0
• 可旋转键数：
  0.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  35.42
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  Natrium-cyclohexanon-oximat 、 苯 以55%的产率得到
  参考文献：
  名称：

  SINGHAL, K.;RAJ, P.;JEE, F., SYNTH. AND REACT. INORG. AND METAL-ORG. CHEM., 1986, 16, N 3, 343-359

  摘要：

  DOI：
• 作为产物：
  描述：

  环己酮肟 在 sodium amide 作用下， 生成 Natrium-cyclohexanon-oximat
  参考文献：
  名称：

  Csueroes et al., Acta Chimica Academiae Scientiarum Hungaricae, 1951, vol. 1, p. 83,88

  摘要：

  DOI：

文献信息

• BECKMANN-Umlagerung und Fragmentierung. 1. Teil. Mechanismus sowie Nachweis der Zwischenstufen Fragmentierungsreaktionen. 7. Mitteilung
  作者：C. A. Grob、H. P. Fischer、W. Raudenbusch、J. Zergenyi

  DOI：10.1002/hlca.19640470411

  日期：——

  The mechanism of the BECKMANN rearrangement and the fragmentation of ketoximes 1 has been studied by determining rate constants and products in «80%» ethanol of several anti-alkyl-, -cycloalkyl-, -aralkyl- and -phenyl-ketoxime tosylates with stationary syn-methyl and -phenyl substituents. The ratio of fragmentation to amide formation is not related to reaction rate, but increases with the stability

  贝克曼重排和酮肟1的碎片的机制进行了研究，通过确定在数“80％”乙醇的速率常数和产品抗烷基- ， -环烷基- ，和-aralkyl- -苯基-酮肟甲苯磺酸酯与静止的顺-甲基和-苯基取代基。裂解与酰胺形成的比例与反应速率无关，但随所形成的碳鎓离子R +的稳定性而增加，这由相应的烷基氯化物RC1的溶剂分解速率所反映。因此，在决定速率的迁移步骤之后会发生腈的碎裂。
• Sodium oximates as starting materials for the synthesis of half-sandwich-type arene(oximato) and arene(azavinylidene) osmium complexes
  作者：H. Werner、T. Daniel、M. Müller、N. Mahr

  DOI：10.1016/0022-328x(95)06010-t

  日期：1996.4

  The reaction of [C6H6OsI2((PPr3)-Pr-i)] (1) with Na[ON=CR(2)](R(2)=Ph(2), Me(2), C(CH2)(5)) in the presence of KPF6 leads to the formation of the oximato osmium(II) complexes [C6H6Os(eta(2)-ON=CR(2))((PPr3)-Pr-i)]PF6 (6, 7, 8b) in almost quantitative yield. The mesitylene compounds [(mes)Os(eta(2)-ON=CR'R '')(PR(3))]PF6 (9-14) have been prepared similarly using [(mes)OsCl2(PR(3))] (3-5) as starting materials. The synthesis of [C6H6Os(eta(2)-ON=CMe(t)Bu)((PPr3)-Pr-i)]PF6 (17) has been achieved from [C6H6OsCl2((PPr3)-Pr-i)] (16) which in turn is prepared from [C6H6Os(eta(2)-O2C=O)((PPr3)-Pr-i)] (15) and excess Me(3)SiCl. Reaction of 1, [C6H6OsI2(PMe(t)Bu(2))] (2) and 3 (PR(3) = (PPr3)-Pr-i) with Na[ON=CMe(t)Bu] in the presence of KPF6, in methanol as solvent, unexpectedly yields the azavinylidene complexes [(arene)Os(=N=CMe(t)Bu)(PR(3))]PF6 (18b, 19, 20). The X-ray structural analysis of 18b reveals the presence of a nearly linear Os-N-C fragment with an Os-N distance that is in agreement with typical osmium-nitrogen double bond lengths. Related azavinylideneosmium compounds [(arene)Os(=N=CR'R '')(PR(3))]PF6 (21-26) have been obtained on treatment of the corresponding oximato complexes 7, 10 or 14 with either HN=CR'R '' or, for R'=H and R ''=Ph, the trimethylsilyl derivative.
• SYNTHESIS AND CHARACTERISATION OF STERICALLY HINDERED μ-OXYBIS[TRI(α-NAPHTHYL) ANTIMONY(V)] DERIVATIVES
  作者：Prem Raj、Santosh Agnihotri、Kiran Singhal

  DOI：10.1081/sim-120003796

  日期：2002.4.29

  Several new mu-oxybis[tri(alpha-naphthyl)antimony(V)] derivatives of the general formula (R3SbL)(2)O (where R=alpha-C10H7; L=N-3, CN, SCN; ON=CPh(OH)CHPh, ON=C(CH2)(4)CH2, OOCC6H4NH2-p, OOCC6H5, OOCC6H4Cl-p, and NCO(C6H4)CO have been prepared by the interaction of (R3SbCl)(2)O with the appropriate metal salts of the ligand. (R3SbN3)(2)O could also be obtained by the interaction of R3SbCl2 with NaN3 (1:2 molar ratio) in ether/water solvent mixture. The newly synthesised complexes have been characterised by elemental analyses, IR spectra, molecular weights and conductance measurements. A trigonal-bipyramidal geometry around the antimony atom with a Sb-O-Sb linkage is tentatively suggested.
• Meyer, Uwe; Werner, Helmut, Chemische Berichte, 1990, vol. 123, # 4, p. 697 - 702
  作者：Meyer, Uwe、Werner, Helmut

  DOI：——

  日期：——
• SINGHAL, KIRAN;RASTOGI, RAJIV;RAJ, PREM, INDIAN J. CHEM., 26,(1987) N 2, 146-150
  作者：SINGHAL, KIRAN、RASTOGI, RAJIV、RAJ, PREM

  DOI：——

  日期：——