bis[μ-tert-butylimidodi-tert-butylimidorhenium(VI)] | 126572-61-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: bis[μ-tert-butylimidodi-tert-butylimidorhenium(VI)]
• 英文别名: bis{(di-t-butylimido)(μ-t-butylimido)rhenium(VI)}
• CAS: 126572-61-0
• 化学式: C₂₄H₅₄N₆Re₂
• 分子量: 799.147
• InChiKey: IMNHMLXFJLOSKH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.1
• 重原子数：
  32.0
• 可旋转键数：
  0.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  55.92
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  copper(I) trifluoromethanesulfonate benzene 、 bis[μ-tert-butylimidodi-tert-butylimidorhenium(VI)] 以 二氯甲烷 为溶剂， 以55%的产率得到
  参考文献：
  名称：

  Reactions of electrophiles with [Bu^tN)₂Re^VI(µ-NBu^t)]₂

  摘要：

  The interaction of [(Bu(t)N)(2)Re-VI(mu-NBu(t))](2) 1 with trifluoromethanesulfonic acid gave the amido complex [(Bu(t)N)(Bu(t)HN)Re(mu-NBu(t))(2)Re(NBu(t))(2)][CF3SO3], where the cation has a structure very similar to that of its manganese(VI) analogue. The interaction of 1 with silver triflate differs from the similar reaction with [(Bu(t)N)(2)Mn-VI(mu-NBu(t))](2) in that a silver complex {[(Bu(t)N)Re(mu-NBu(t))](2)(mu-NBu(t))(2)Ag(mu-O3SCF3)}(2) that has NBu(t) groups bridging both rhenium and silver atoms with the latter having mu-O3SCF3 bridges is formed. A similar complex [(Bu(t)N)Re(mu-NBu(t))](2)(mu-NBu(t))(2)Cu-2(O3SCF3)(2) was obtained by interaction of 1 with Cu(O-3-SCF3). 0.5C(6)H(6) but this has Re(mu-NBu(t))Cu(O3SCF3) groups. Interaction of 1 with Al(O3SCF3)(3) . nCF(3)SO(3)H in CH2Cl2 gave a linear molecule (Bu(t)N)(2)Re(mu-NBu(t))(2)Re(NBu(t))(mu-OH)(2)Al(O3SCF3)(3)(H2O). The crystal structures of four compounds have been determined. An improved synthesis of 1 involving Na/Hg reduction of Re(NBu(t))(3)I was elaborated.

  DOI：

  10.1039/dt9960002995
• 作为产物：
  描述：

  tris(tert-butylimido)iodorhenium(VII) 在 Na-Hg 作用下， 以 乙醚 为溶剂， 以80%的产率得到bis[μ-tert-butylimidodi-tert-butylimidorhenium(VI)]
  参考文献：
  名称：

  Reactions of electrophiles with [Bu^tN)₂Re^VI(µ-NBu^t)]₂

  摘要：

  The interaction of [(Bu(t)N)(2)Re-VI(mu-NBu(t))](2) 1 with trifluoromethanesulfonic acid gave the amido complex [(Bu(t)N)(Bu(t)HN)Re(mu-NBu(t))(2)Re(NBu(t))(2)][CF3SO3], where the cation has a structure very similar to that of its manganese(VI) analogue. The interaction of 1 with silver triflate differs from the similar reaction with [(Bu(t)N)(2)Mn-VI(mu-NBu(t))](2) in that a silver complex {[(Bu(t)N)Re(mu-NBu(t))](2)(mu-NBu(t))(2)Ag(mu-O3SCF3)}(2) that has NBu(t) groups bridging both rhenium and silver atoms with the latter having mu-O3SCF3 bridges is formed. A similar complex [(Bu(t)N)Re(mu-NBu(t))](2)(mu-NBu(t))(2)Cu-2(O3SCF3)(2) was obtained by interaction of 1 with Cu(O-3-SCF3). 0.5C(6)H(6) but this has Re(mu-NBu(t))Cu(O3SCF3) groups. Interaction of 1 with Al(O3SCF3)(3) . nCF(3)SO(3)H in CH2Cl2 gave a linear molecule (Bu(t)N)(2)Re(mu-NBu(t))(2)Re(NBu(t))(mu-OH)(2)Al(O3SCF3)(3)(H2O). The crystal structures of four compounds have been determined. An improved synthesis of 1 involving Na/Hg reduction of Re(NBu(t))(3)I was elaborated.

  DOI：

  10.1039/dt9960002995

文献信息

• t-Butylimido compounds of rhenium. X-ray crystal structures of [(ButN)2Re(μ-NBut)]2, (ButN)2ReCl3, (ButN)2ReCl2C6H5, (ButN)3Re(OSiMe3) and (ButN)3ReCl
  作者：Andreas A. Danopoulos、Cindy J. Longley、Geoffrey Wilkinson、Bilquis Hussain、Michael B. Hursthouse

  DOI：10.1016/s0277-5387(00)80436-2

  日期：1989.1

  (ButN)2Re(μ-NBut)2Re(NBut)2. The homoleptic anion [Re(NBut)4]− as the Li(tmed)+ complex has been synthesized via the new intermediates (ButN)3ReCl and (ButN)3Re(NHBut). X-ray crystal structures of the compounds listed in the title have been determined. The homoleptic rhenium(VI) t-butylimide is dimeric with four-coordinate rhenium and almost symmetrical imido bridges; the terminal imido groups have near

  摘要已有关于on的叔丁基亚氨基芳基的研究得到扩展，并合成了化合物（ButN）2RevVII（o-tol）3，（ButN）2ReVIICl2Ph和（BUtN）2ReVI（mes）2。后者的电化学研究显示可逆的单电子氧化和还原，化学氧化导致阳离子[（ButN）2RevVII（mes）2] +分离为PF6-和CF3SO3-盐。尽管中性络合物不与异氰酸酯一起插入，但阳离子确实会产生η2-亚氨基酰基ButN）2Re（mes）[η2-RNC（mes）]} +，R = 2,6-二甲苯基， t-Bu。用钠还原己烷中的（ButN）3Re（OSiMe3）得到桥联的均配化合物（ButN）2Re（μ-NBut）2Re（NBut）2。通过新的中间体（ButN）3ReCl和（ButN）3Re（NHBut）合成了Li（tmed）+络合物的均衡阴离子[Re（NBut）4]-。已确定标题中所列化合物的X射线晶体结构。
• Synthesis and reactions of tert-butylimido complexes of rhenium. X-ray crystal structures of [(ReNBut)2(OSiMe3)]2(μ-O)(μ-OSiMe3)(μ-O2CCF3), Re(NBut)3PPh2 and [Re(NBut)3(NH2But]O3SCF3
  作者：Vahé Saboonchian、Andreas A. Danopoulos、Angel Gutierrez、Geoffrey Wilkinson、David J. Williams

  DOI：10.1016/s0277-5387(00)86148-3

  日期：1991.1

  reactions of Re(NBut)3Cl with NaC5H5, AgX (X = BF4, PF, and CF3CO2) and with SbCl5, lead to the loss of an NButgroup, and the formation of his tert-butylimido compounds, respectively, [Re(NBut)2(η1-C5H5)]2(μ-O)(μ-C5H4), [(ButN)2(Cl)Re(μ-F) (μ-NBut)Re(NBut)(μ-F)]2X (X = BF4 and PF6), [Re(NBut)2]2(μ-OSiMe3)(μ-O2CCF3) and [Re(NBut)2Cl2(MeCN)2]SbCl6. The interaction between Re3(NBut)4(O)5(OSiMe3)3 and AgO2CCF3

  Re（NBu t）3 Cl与NaC 5 H 5，AgX（X = BF 4，PF和CF 3 CO 2）以及与SbCl 5的反应导致NBu t基团的丢失并形成他的叔丁基亚化合物分别[回复（NBU吨）2（η 1 -C 5 ħ 5）] 2（μ-O）（μ-C 5 H ^ 4），[（卜吨N）2（Cl）的的Re（μ-F）（μ-NBU吨）RE（NBU吨）（μ-F）] 2X（X = BF 4和PF 6），[重（NBU吨）2 ] 2（μ-OSiMe 3）（μ-O 2 CCF 3）和[回复（NBU吨）2氯2（MeCN中）2 ]的SbCl 6。Re 3（NBu t）4（O）5（OSiMe 3）3和AgO 2 CCF 3之间的相互作用产生了一种物质[Re（NBu t）2（OSiMe 3）] 2（μ-O）（μ-OSiMe 3）（μ-O 2 CCF 3），其中，所述μ-奥利奥3在起始材料中基团被取代μ-O 2 CCF 3。CF