4-[4'-(5-sulfonaphthylazo)phenyloxy]phthalonitrile potassium salt | 1354966-36-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 4-[4'-(5-sulfonaphthylazo)phenyloxy]phthalonitrile potassium salt
• CAS: 1354966-36-1
• 化学式: C₂₄H₁₃N₄O₄S*K
• 分子量: 492.556
• InChiKey: UPAAXJCCVIUMEA-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  34.0
• 可旋转键数：
  5.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  138.73
• 氢给体数：
  0.0
• 氢受体数：
  8.0

反应信息

• 作为反应物：
  描述：

  4-[4'-(5-sulfonaphthylazo)phenyloxy]phthalonitrile potassium salt 在 cobalt(II) chloride 、 硫酸 作用下， 反应 0.5h， 以50%的产率得到tetra-4-[4'(5-sulfonaphthylazo)phenyloxy]phthalocyanine cobalt
  参考文献：
  名称：

  Synthesis and study of properties of the sulfonaphthylazophenoxyphthalonitrile and related phthalocyanine

  摘要：

  The 4-[4'-(5-sulfonaphthylazo)phenoxy]phthalonitrile potassium salt was synthesized by the reaction of 4-chlorophthalonitrile with 5-(4'-hydroxyphenylazo)-1-naphthalenesulfonic acid, and on its basis was obtained tetra-4-[4'-(5-sulfonaphthylazo)phenoxy]phthalocyanine. The products were characterized by elemental analysis, IR and electron spectroscopy. The effect of the introduced substituent on the spectral and other properties of the synthesized compounds was demonstrated.

  DOI：

  10.1134/s1070363211110235
• 作为产物：
  描述：

  5-(4'-hydroxyphenylazo)-1-naphthalenesulfonic acid 、 4-氯代邻苯二甲腈 在 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 3.0h， 以74.1%的产率得到4-[4'-(5-sulfonaphthylazo)phenyloxy]phthalonitrile potassium salt
  参考文献：
  名称：

  Synthesis and study of properties of the sulfonaphthylazophenoxyphthalonitrile and related phthalocyanine

  摘要：

  The 4-[4'-(5-sulfonaphthylazo)phenoxy]phthalonitrile potassium salt was synthesized by the reaction of 4-chlorophthalonitrile with 5-(4'-hydroxyphenylazo)-1-naphthalenesulfonic acid, and on its basis was obtained tetra-4-[4'-(5-sulfonaphthylazo)phenoxy]phthalocyanine. The products were characterized by elemental analysis, IR and electron spectroscopy. The effect of the introduced substituent on the spectral and other properties of the synthesized compounds was demonstrated.

  DOI：

  10.1134/s1070363211110235