3-[(双环[2.2.1]庚-5-烯-2-基甲氧基)甲基]-3-乙基氧杂环丁烷 | 618380-47-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧杂环丁烷
• 中文名称: 3-[(双环[2.2.1]庚-5-烯-2-基甲氧基)甲基]-3-乙基氧杂环丁烷
• 英文名称: 3-ethyl-3-(5-norbornene-2-methoxy)methyloxetane
• 英文别名: 3-{[(Bicyclo[2.2.1]hept-5-en-2-yl)methoxy]methyl}-3-ethyloxetane；3-(2-bicyclo[2.2.1]hept-5-enylmethoxymethyl)-3-ethyloxetane
• CAS: 618380-47-5
• 化学式: C₁₄H₂₂O₂
• 分子量: 222.327
• InChiKey: HUNPIEFBMYPDES-UHFFFAOYSA-N

物化性质

• 沸点：
  295.5±13.0 °C(Predicted)
• 密度：
  1.026±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  16
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3-[(双环[2.2.1]庚-5-烯-2-基甲氧基)甲基]-3-乙基氧杂环丁烷 、 1H,1H,2H,2H-perfluorohexyl mercaptan 在 偶氮二异丁腈 作用下， 以 甲苯 为溶剂， 反应 8.0h， 以95%的产率得到3-ethyl-3-[[6-(3,3,4,4,5,5,6,6,6-nonafluorohexylsulfanyl)-2-bicyclo[2.2.1]heptanyl]methoxymethyl]oxetane
  参考文献：
  名称：

  含氟阳离子聚合单体及其合成和应用

  摘要：

  本发明涉及式(I)单体化合物，其中各变量如说明书中所定义。该单体通过硫醇与烯烃之间的点击化学反应以高产率、快速合成，而且将基本上全氟化的烷烃链借助于包含降冰片烷结构部分的连接基引入到氧杂环烷烃类单体中，使得由所得单体阳离子光固化得到的光固化薄膜表面硬度高，表面能低，疏水疏油性能优良，尤其是抗油性沾污非常好。本发明还涉及所述单体的制备方法，该单体开环聚合得到的聚合物，包含该单体的可光固化组合物和由该可光固化组合物光固化得到的光固化材料。

  公开号：

  CN111057027B
• 作为产物：
  描述：

  3-(氯甲基)-3-乙基氧杂环丁烷 、 5-降冰片烯-2-甲醇 在 四丁基溴化铵 、 potassium hydroxide 作用下， 以 水 为溶剂， 反应 24.0h， 以81%的产率得到3-[(双环[2.2.1]庚-5-烯-2-基甲氧基)甲基]-3-乙基氧杂环丁烷
  参考文献：
  名称：

  含氟阳离子聚合单体及其合成和应用

  摘要：

  本发明涉及式(I)单体化合物，其中各变量如说明书中所定义。该单体通过硫醇与烯烃之间的点击化学反应以高产率、快速合成，而且将基本上全氟化的烷烃链借助于包含降冰片烷结构部分的连接基引入到氧杂环烷烃类单体中，使得由所得单体阳离子光固化得到的光固化薄膜表面硬度高，表面能低，疏水疏油性能优良，尤其是抗油性沾污非常好。本发明还涉及所述单体的制备方法，该单体开环聚合得到的聚合物，包含该单体的可光固化组合物和由该可光固化组合物光固化得到的光固化材料。

  公开号：

  CN111057027B

文献信息

• Photocationic curable composition and new compound
  申请人：DAINIPPON INK AND CHEMICALS, INC.

  公开号：EP1652886A1

  公开（公告）日：2006-05-03

  The invention is related to a photocationic curable composition comprising c) a compound having (a-1) an epoxy alicyclic structure selected from the group consisting of epoxy norbornene structure and 2,3-epoxy-1,4,5,8-dimethanonaphtalene structure, and (a-2) oxetane structure, wherein the epoxy alicyclic structure(a-1) is bonded to the oxetane structure(a-2) via a polyvalent organic group selected from the group consisting of an alkylene group, an alkylene ether group, and an alkylene thioether group, wherein the atom number between the structure(a-1) and the structure(a-2) is within the range of 1 to 8, or via a phenylene containing divalent organic group, and d) a photoinitiator. The cured product of the present invention exhibits high hardness. Therefore, the composition of the present invention is suitable for UV-inks, coatings, or adhesives.

  本发明涉及一种光致固化组合物，包括 c) 具有以下特性的化合物 (a-1) 环氧脂环结构，选自由环氧降冰片烯结构和 2,3-环氧-1,4,5,8-二甲萘结构组成的组，和 (a-2) 氧杂环丁烷结构、 其中环氧脂环族结构（a-1）通过选自亚烷基、亚烷基醚基和亚烷基硫醚基组成的组的多价有机基团与氧杂环烷结构（a-2）键合，其中结构（a-1）和结构（a-2）之间的原子序数在 1 至 8 的范围内，或通过含亚苯基的二价有机基团键合，以及 d) 光引发剂。 本发明的固化产品具有高硬度。因此，本发明的组合物适用于紫外线墨水、涂料或粘合剂。
• LIQUID CRYSTAL PANEL-USE BASE FILM, LIQUID CRYSTAL PANEL-USE FUNCTIONAL FILM, PRODUCTION METHOD OF FUNCTIONAL FILM, PRODUCTION DEVICE OF FUNCTIONAL FILM
  申请人：Dainippon Printing Co., Ltd.

  公开号：EP1732362A1

  公开（公告）日：2006-12-13

  A conventional liquid crystal display comprises a number of components, so that a manufacturing cost cannot be reduced. Furthermore, a large-area substrate has problems in shipping. According to this invention, a liquid-crystal panel is prepared by forming individual optically functional films, a TFT device and a light-emitting device on a long thin film and then laminating the film by a transfer process. A base film to be a substrate in a liquid-crystal panel preferably has a thickness of 10 µm to 200 µm, a curvature radius of 40 mm or less as a measure of flexibility and a coefficient of thermal expansion of 50 ppm/°C or less. Furthermore, it more preferably gives a variation of ± 5 % or less in mechanical and optical properties to a thermal history at 200 °C.

  传统的液晶显示器由许多组件组成，因此无法降低制造成本。此外，大面积的基板在运输方面也存在问题。 根据本发明，液晶面板的制备方法是在长薄膜上形成单个光学功能薄膜、TFT 器件和发光器件，然后通过转印工艺将薄膜层压。作为液晶面板基板的基膜最好厚度在 10 微米到 200 微米之间，曲率半径在 40 毫米或以下（作为柔韧性的衡量标准），热膨胀系数在 50 ppm/°C 或以下。此外，在 200 °C 的热历史条件下，机械和光学特性的变化最好不超过 ± 5%。
• Process for producing norbornene derivatives
  申请人：DAINIPPON INK AND CHEMICALS, INC.

  公开号：EP1757580B1

  公开（公告）日：2008-06-11
• Base film for liquid-crystal panel, functional film for liquid-crystal panel, manufacturing process for functional film and manufacturing apparatus for functional film
  申请人：Takahashi Tatsumi

  公开号：US20070126966A1

  公开（公告）日：2007-06-07

  A conventional liquid crystal display comprises a number of components, so that a manufacturing cost cannot be reduced. Furthermore, a large-area substrate has problems in shipping. According to this invention, a liquid-crystal panel is prepared by forming individual optically functional films, a TFT device and a light-emitting device on a long thin film and then laminating the film by a transfer process. A base film to be a substrate in a liquid-crystal panel preferably has a thickness of 10 μm to 200 μm, a curvature radius of 40 mm or less as a measure of flexibility and a coefficient of thermal expansion of 50 ppm/° C. or less. Furthermore, it more preferably gives a variation of ±5% or less in mechanical and optical properties to a thermal history at 200° C.
• [EN] PHOTOCATIONIC CURABLE COMPOSITION AND NEW COMPOUND<br/>[FR] COMPOSITION CATIONIQUE DURCISSABLE PAR PHOTOINITIATION ET NOUVEAU COMPOSE
  申请人：DAINIPPON INK & CHEMICALS

  公开号：WO2006030960A1

  公开（公告）日：2006-03-23

  The invention is related to a photocationic curable composition comprising a) a compound having (a-1) an epoxy alicyclic structure selected from the group consisting of epoxy norbornene structure and 2,3 -epoxy- 1,4,5,8-dimethanonaphtalene structure, and (a-2) oxetane structure, wherein the epoxy alicyclic structure(a-1) is bonded to the oxetane structure(a-2) via a polyvalent organic group selected from the group consisting of an alkylene group, an alkylene ether group, and an alkylene thioether group, wherein the atom number between the structure(a-1) and the structure(a-2) is within the range of 1 to 8, or via a phenylene containing divalent organic group, and b) a photoinitiator. The cured product of the present invention exhibits high hardness. Therefore, the composition of the present invention is suitable for UV-inks, coatings, or adhesives.