4,4'-di[3,4-bis(n-dodecyloxy)styryl]benzil | 872089-71-9

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 4,4'-di[3,4-bis(n-dodecyloxy)styryl]benzil
• 英文别名: 1,2-Bis-{4-[2-(3,4-bis-dodecyloxy-phenyl)-vinyl]-phenyl}-ethane-1,2-dione；1,2-bis[4-[2-(3,4-didodecoxyphenyl)ethenyl]phenyl]ethane-1,2-dione
• CAS: 872089-71-9
• 化学式: C₇₈H₁₁₈O₆
• 分子量: 1151.79
• InChiKey: MRWSPBSKTIHOSF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  29.7
• 重原子数：
  84
• 可旋转键数：
  55
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  4,4'-二溴联苯酰 、 3,4-bis(n-dodecyloxy)styrene 在 palladium diacetate 、 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 60.0h， 以76%的产率得到4,4'-di[3,4-bis(n-dodecyloxy)styryl]benzil
  参考文献：
  名称：

  Synthesis of a Nickel Bis(dithiolene) Complex with Strong Near-Infrared Two-Photon Absorption

  摘要：

  The diketones 4,4'-di[3,4-bis(n-dodecyloxy)styryl]benzil and 4,4'-di[3,4-bis(n-dodecyloxy)phenylethynyl]benzil have been synthesized from 4,4'-dibromobenzil using Heck coupling with the appropriate styrene and Sonogashira coupling with the appropriate phenylalkyne, respectively. Treatment of the distyrylbenzil derivative with phosphorus pentasulfide followed by nickel(II) chloride gave the corresponding extended nickel bis(dithiolene) derivative which shows strong near-infrared two-photon absorption with a cross-section of over 440 GM (1 GM = 10(-50) cm(4) S photon(-1) molecule(-1)) throughout the telecommunications range and a peak cross-section of 5300 GM at ca. 1.2 mu m.

  DOI：

  10.1080/15421400801924979

文献信息

• Transition-Metal Charge Transport Materials, Methods Of Fabrication Thereof, And Methods Of Use Thereof
  申请人：Seth Marder

  公开号：US20080121870A1

  公开（公告）日：2008-05-29

  Briefly described, embodiments of this disclosure include transition-metal charge-transport materials, methods of forming transition-metal charge-transport materials, and methods of using the transition-metal charge-transport materials.

  简要描述，本公开的实施例包括过渡金属电荷传输材料，形成过渡金属电荷传输材料的方法以及使用过渡金属电荷传输材料的方法。
• Transition-metal charge-transport materials, methods of fabrication thereof, and methods of use thereof
  申请人：Georgia Tech Research Corporation

  公开号：US07842830B2

  公开（公告）日：2010-11-30

  Briefly described, embodiments of this disclosure include transition-metal charge-transport materials, methods of forming transition-metal charge-transport materials, and methods of using the transition-metal charge-transport materials.

  简要描述，本公开的实施例包括过渡金属电荷传输材料、制备过渡金属电荷传输材料的方法，以及使用过渡金属电荷传输材料的方法。
• Synthesis of a Nickel Bis(dithiolene) Complex with Strong Near-Infrared Two-Photon Absorption
  作者：Jian-Yang Cho、Jie Fu、Lazaro A. Padilha、Stephen Barlow、Eric W. Van Stryland、David J. Hagan、Maximilienne Bishop、Seth R. Marder

  DOI：10.1080/15421400801924979

  日期：2008.4.17

  The diketones 4,4'-di[3,4-bis(n-dodecyloxy)styryl]benzil and 4,4'-di[3,4-bis(n-dodecyloxy)phenylethynyl]benzil have been synthesized from 4,4'-dibromobenzil using Heck coupling with the appropriate styrene and Sonogashira coupling with the appropriate phenylalkyne, respectively. Treatment of the distyrylbenzil derivative with phosphorus pentasulfide followed by nickel(II) chloride gave the corresponding extended nickel bis(dithiolene) derivative which shows strong near-infrared two-photon absorption with a cross-section of over 440 GM (1 GM = 10(-50) cm(4) S photon(-1) molecule(-1)) throughout the telecommunications range and a peak cross-section of 5300 GM at ca. 1.2 mu m.