{(2,2'-bipyridine)(2-(2-mercaptophenyl)iminophenoxy-5-Br)}zinc(II) | 147186-62-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: {(2,2'-bipyridine)(2-(2-mercaptophenyl)iminophenoxy-5-Br)}zinc(II)
• CAS: 147186-62-7
• 化学式: C₂₃H₁₆BrN₃OSZn
• 分子量: 527.76
• InChiKey: PMBCSQUYVKTTHI-OLIKVXRNSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2,2’-(((disulfanediylbis(2,1-phenylene))bis(azaneylylidene))bis(methaneylylidene))bis(4-bromophenol) 、 锌 在 tetramethylammonium perchlorate 、 2,2'-bipyridyl 作用下， 以 乙腈 为溶剂， 生成 {(2,2'-bipyridine)(2-(2-mercaptophenyl)iminophenoxy-5-Br)}zinc(II)
  参考文献：
  名称：

  The synthesis of zinc(II) complexes of 2-(2-mercaptophenyl)-iminophenol by electrochemical cleavage of a disulfide bond; the crystal structure of {(2, 2′-bipyridine)[2-(2-mercaptophenyl)iminophenoxy]}zinc(II)

  摘要：

  The electrochemical oxidation of anodic zinc in an acetonitrile solution of the Schiff base derived from the required salicylaldehyde and bis-(2-aminophenyl)disulfide, L2H-2, yields compounds having the formulation ZnL. When 1,10-phenanthroline (phen) or 2,2'-bipyridine (bipy) is added to the electrolytic phase [ZnLphen] or [ZnLbipy] are obtained. The crystal structure of {2,2'-bipyridine[2-(2-mercaptophenyl)]iminophenoxy}zinc(II) [ZnL1bipy] has been determined. The compound crystallises in the triclinic space group Pl(No. 1) with two molecules in the unit cell and cell constants a = 6.526(2), b = 11.686(3), c = 13.346(4) angstrom; alpha = 107.72(2), beta = 92.08(2), gamma = 91.79(2)-degrees. The zinc atom has a distorted trigonal bipyramidal geometry. The IR and H-1 NMR spectra of complexes are discussed and related to the structure.

  DOI：

  10.1016/s0020-1693(00)82906-0