1-(3,7-二甲基辛基)哌啶 | 56717-15-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 哌啶类
• 中文名称: 1-(3,7-二甲基辛基)哌啶
• 英文名称: N-(3,7-dimethyloctyl)piperidine
• 英文别名: 1-(3,7-Dimethyloctyl)piperidine
• CAS: 56717-15-8
• 化学式: C₁₅H₃₁N
• 分子量: 225.418
• InChiKey: QZCHUAYVJYJZBQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  16
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  碘甲烷 、 1-(3,7-二甲基辛基)哌啶 以 苯 为溶剂， 反应 72.0h， 以94%的产率得到1-(3,7-dimethyloctyl)-1-methylpiperidinium iodide
  参考文献：
  名称：

  Synthesis of New Plant Growth Regulators, Isomeric 1-(Dimethyloctyl)- and 1-Alkylpiperidinium and -morpholinium Halides by Telomerization of Isoprene with Secondary Amines

  摘要：

  The known plant growth regulator, Al'den [1-(3,7-dimethyloctyl)-1-allylpiperidinium bromide], and also 1-(3,7-dimethyloctyl)-1-methylpiperidinium iodide were synthesized by treatment with allyl bromide and methyl iodide, respectively, of exhaustively hydrogenated 1-nerylpiperidine which was obtained by anionic telomerization of isoprene with piperidine. Various quaternary ammonium salts having a terpene substituent with unnatural dimethyloctane skeleton, which effectively stimulate florification of Aster Chinensis L., were prepared by the action of alkyl halides on telomerization products derived from isoprene and piperidine or morpholine in the presence of palladium complexes.

  DOI：

  10.1023/b:rugc.0000016041.29564.e9
• 作为产物：
  描述：

  (Z)-1-(3,7-dimethylocta-2,6-dienyl)piperidine 在 镍 氢气 作用下， 以 正庚烷 为溶剂， 60.0 ℃ 、10.13 MPa 条件下， 反应 12.0h， 以96%的产率得到1-(3,7-二甲基辛基)哌啶
  参考文献：
  名称：

  Synthesis of New Plant Growth Regulators, Isomeric 1-(Dimethyloctyl)- and 1-Alkylpiperidinium and -morpholinium Halides by Telomerization of Isoprene with Secondary Amines

  摘要：

  The known plant growth regulator, Al'den [1-(3,7-dimethyloctyl)-1-allylpiperidinium bromide], and also 1-(3,7-dimethyloctyl)-1-methylpiperidinium iodide were synthesized by treatment with allyl bromide and methyl iodide, respectively, of exhaustively hydrogenated 1-nerylpiperidine which was obtained by anionic telomerization of isoprene with piperidine. Various quaternary ammonium salts having a terpene substituent with unnatural dimethyloctane skeleton, which effectively stimulate florification of Aster Chinensis L., were prepared by the action of alkyl halides on telomerization products derived from isoprene and piperidine or morpholine in the presence of palladium complexes.

  DOI：

  10.1023/b:rugc.0000016041.29564.e9

文献信息

• ZAXARKIN, L. I.;GUSEVA, V. V.;PETRUSHKINA, E. A.
  作者：ZAXARKIN, L. I.、GUSEVA, V. V.、PETRUSHKINA, E. A.

  DOI：——

  日期：——
• US4014678A
  申请人：——

  公开号：US4014678A

  公开（公告）日：1977-03-29
• US4139367A
  申请人：——

  公开号：US4139367A

  公开（公告）日：1979-02-13
• Synthesis of New Plant Growth Regulators, Isomeric 1-(Dimethyloctyl)- and 1-Alkylpiperidinium and -morpholinium Halides by Telomerization of Isoprene with Secondary Amines
  作者：E. A. Petrushkina、L. I. Zakharkin†

  DOI：10.1023/b:rugc.0000016041.29564.e9

  日期：2003.10

  The known plant growth regulator, Al'den [1-(3,7-dimethyloctyl)-1-allylpiperidinium bromide], and also 1-(3,7-dimethyloctyl)-1-methylpiperidinium iodide were synthesized by treatment with allyl bromide and methyl iodide, respectively, of exhaustively hydrogenated 1-nerylpiperidine which was obtained by anionic telomerization of isoprene with piperidine. Various quaternary ammonium salts having a terpene substituent with unnatural dimethyloctane skeleton, which effectively stimulate florification of Aster Chinensis L., were prepared by the action of alkyl halides on telomerization products derived from isoprene and piperidine or morpholine in the presence of palladium complexes.