tetrahydroxybis((2-hydroxy-3,4-dioxocyclobut-1-en-1-yl)oxy)cadmium | 606928-19-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: tetrahydroxybis((2-hydroxy-3,4-dioxocyclobut-1-en-1-yl)oxy)cadmium
• CAS: 606928-19-2
• 化学式: C₈H₁₀CdO₁₂
• 分子量: 410.57
• InChiKey: JHIPYOAHIYHIGK-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  水 、 cadmium(II) hydroxide 、 方酸 以 水 为溶剂， 生成 tetrahydroxybis((2-hydroxy-3,4-dioxocyclobut-1-en-1-yl)oxy)cadmium
  参考文献：
  名称：

  Temperature Controlled Reversible Change of the Coordination Modes of the Highly Symmetrical Multitopic Ligand To Construct Coordination Assemblies: Experimental and Theoretical Studies

  摘要：

  By fine-tuning the reaction temperature to 5, 15, 30, and 50 degrees C, respectively, four different complexes, [Cd (HC4O4)(2)(H2O)(4)] (1), [Cd-4(C4O4)(4)(H2O)(16)]center dot(H2O)(2) (2), [Cd(C4O4)(H2O)(2)] (3), and [Cd(C4O4)(H2O)(2)] (4), were formed successfully from the identical initial reaction mixture. Moreover, an unprecedented reversible interconversion among the four complexes at the corresponding reaction temperatures mediated by the mother liquor was observed.

  DOI：

  10.1021/ja800439p