3-methyl-N'-[1-(2-hydroxynaphthyl)ethylidene]benzohydrazide | 1311392-00-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 3-methyl-N'-[1-(2-hydroxynaphthyl)ethylidene]benzohydrazide
• CAS: 1311392-00-3
• 化学式: C₂₀H₁₈N₂O₂
• 分子量: 318.375
• InChiKey: ZZRPHSSPQZRVOI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.01
• 重原子数：
  24.0
• 可旋转键数：
  3.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  61.69
• 氢给体数：
  2.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  甲醇 、 bis(acetylacetonate)oxovanadium 、 3-methyl-N'-[1-(2-hydroxynaphthyl)ethylidene]benzohydrazide 以 甲醇 为溶剂， 以90%的产率得到[oxovanadium(V)(OMe)(3-methyl-N'-[1-(2-hydroxynaphthyl)ethylidene]benzohydrazide(-H))]2
  参考文献：
  名称：

  Two New Oxovanadium(V) Complexes with Hydrazone Ligands: Synthesis, Characterization, and Structure

  摘要：

  The reaction of [VO(acac)2] with 3-methyl-N'-[1-(2-hydroxynaphthyl)ethylidene]benzohydrazide (H2L1) and 3-methyl-N'-[(2-hydroxy-1-naphthyl)methylidene]benzohydrazide (H2L2), respectively, in methanol affords two new oxovanadium(V) complexes, [VO(OMe)L1]2 (1) and [VO(OMe)(HOMe)L2] (2). Both complexes have been characterized by elemental analysis, I.R., and single crystal X-ray diffraction methods. Complex (1) is a methoxide-bridged dinuclear oxovanadium(V) compound, while complex (2) is a mononuclear oxovanadium(V) compound. The dinegative hydrazone ligands coordinate to the metal atoms through phenolate, imine, and deprotonated amine donor atoms. The geometry around each vanadium atom is a distorted VNO5 octahedron in both complexes.

  DOI：

  10.1080/15533174.2011.555873
• 作为产物：
  描述：

  1-乙酰基-2-萘酚 、 间甲苯甲酸酰肼 以 甲醇 为溶剂， 反应 1.0h， 以85%的产率得到3-methyl-N'-[1-(2-hydroxynaphthyl)ethylidene]benzohydrazide
  参考文献：
  名称：

  Two New Oxovanadium(V) Complexes with Hydrazone Ligands: Synthesis, Characterization, and Structure

  摘要：

  The reaction of [VO(acac)2] with 3-methyl-N'-[1-(2-hydroxynaphthyl)ethylidene]benzohydrazide (H2L1) and 3-methyl-N'-[(2-hydroxy-1-naphthyl)methylidene]benzohydrazide (H2L2), respectively, in methanol affords two new oxovanadium(V) complexes, [VO(OMe)L1]2 (1) and [VO(OMe)(HOMe)L2] (2). Both complexes have been characterized by elemental analysis, I.R., and single crystal X-ray diffraction methods. Complex (1) is a methoxide-bridged dinuclear oxovanadium(V) compound, while complex (2) is a mononuclear oxovanadium(V) compound. The dinegative hydrazone ligands coordinate to the metal atoms through phenolate, imine, and deprotonated amine donor atoms. The geometry around each vanadium atom is a distorted VNO5 octahedron in both complexes.

  DOI：

  10.1080/15533174.2011.555873