(N1E,N5E)-N1,N5-bis(pyridin-4-ylmethylene)naphthalene-1,5-diamine | 869734-39-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: (N1E,N5E)-N1,N5-bis(pyridin-4-ylmethylene)naphthalene-1,5-diamine
• 英文别名: (N¹E,N⁵E)-N¹,N⁵-bis(pyridin-4-ylmethylene)naphthalene-1,5-diamine；N,N'-bis[pyridin-4-ylmethylene]naphthalene-1,5-diamine
• CAS: 869734-39-4
• 化学式: C₂₂H₁₆N₄
• 分子量: 336.396
• InChiKey: FJXHPRVSTIXUPE-RYQLWAFASA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.13
• 重原子数：
  26.0
• 可旋转键数：
  4.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  50.5
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  (N1E,N5E)-N1,N5-bis(pyridin-4-ylmethylene)naphthalene-1,5-diamine 、 cadmium(II) iodide 以 乙醇 、 N,N-二甲基甲酰胺 为溶剂， 反应 96.0h， 以80%的产率得到[Cd(N,N'-bis[pyridin-4-ylmethylene]naphthalene-1,5-diamine)I₂]
  参考文献：
  名称：

  非共价相互作用在基于 N,N'-Bis-pyridin-4-ylmethylene-naphthalene-1,5-diamine 配体的两种新型 Cd(II) 和 Hg(II) 纳米配位聚合物晶体结构中的作用

  摘要：

  摘要 使用常规方法由金属碘化物和 N, N'-Bis-pyridin-4-ylmethylene-naphthalene-1,5-diamine 配体构建了两种新的 Hg(II) 和 Cd(II) 一维配位聚合物。已经详细讨论了配体几何形状和碘化物的配位模式对配位聚合物结构的影响。为了阐明实验条件对 [Cd(L)I2]n (1) 和 [Hg(L)I2]n 粒子形态和尺寸的影响，我们系统地研究了浓度和超声处理功率对以实现可控合成为目的。结果表明，浓度和超声处理功率直接影响这些配位聚合物纳米结构的最终尺寸。

  DOI：

  10.1016/j.molstruc.2017.01.024

文献信息

• WATER CAPTURE METHODS, DEVICES, AND COMPOUNDS
  申请人：University of Limerick

  公开号：US20200030737A1

  公开（公告）日：2020-01-30

  A method of capturing water from a gaseous composition comprising water vapour (e.g., air), the method comprising: (a) providing a metal-organic material; and (b) contacting the metal-organic material with water and/or water vapour; wherein upon contact with water and/or water vapour the material switches from a first state to a second state wherein the second state is able to retain a higher amount of water than the first state.

  一种从含水蒸气（例如空气）中捕获水的方法，包括以下步骤：(a) 提供金属有机材料；和(b) 将金属有机材料与水和/或水蒸气接触；其中，在接触水和/或水蒸气时，该材料从第一状态切换到第二状态，第二状态能够比第一状态更多地保留水。
• IMPROVEMENTS RELATING TO WATER CAPTURE
  申请人：University of Limerick

  公开号：EP3599019A1

  公开（公告）日：2020-01-29

  A method of capturing water from air, the method comprising: (a) providing a two-dimensional layered material; and (b) contacting the material with water and/or water vapour; wherein upon contact with water and/or water vapour the material switches from a first state to a second state wherein the second state is able to retain a higher amount of water than the first state.

  一种从空气中捕捉水的方法，该方法包括 (a) 提供二维分层材料；以及 (b) 将该材料与水和/或水蒸气接触； 其中，与水和/或水蒸气接触后，材料从第一状态切换到第二状态，第二状态能够保留比第一状态更多的水。
• An investigation of the catalytic activity in a series of isoreticular Zn(II)-based metal-organic frameworks
  作者：Fahime Bigdeli、Sedigheh Abedi、Hassan Hosseini-Monfared、Ali Morsali

  DOI：10.1016/j.inoche.2016.08.010

  日期：2016.10

  The catalyst operation of four metal-organic frameworks (MOFs), [Zn(oba)(4-bpmb)(0.5)](n)center dot(DMF)(1.5) (TMU-6), [Zn(oba)(R-4-bpmb)(0.5)](n)center dot(DMF)(1.5) (R-TMU-6), [Zn(oba)(4-bpmn)(0.5)center dot(DMF)(1.5) (TMU-21) and [Zn(oba)(R-4-bpmn)(0.5)](n) center dot(DMF)(1.5) (R-TMU-21) containing phenyl and naphthyl derivatives, respectively, is discussed. These compounds were easily prepared via mechanosynthesis and utilized for catalysis of the Knoevenagel reaction. The effect of reduction and nature of N-donor pillar ligands resulting different characteristics are investigated on the catalytic performance of the MOFs. Using various aromatic aldehydes, the catalytic activity seems to be enhanced by increased N-donor ligands basicity. Results show that among the four compounds, R-TMU-21 with the most basic center reaction bearing naphtyl-containing pillar has the highest catalytic activity. (C) 2016 Published by Elsevier B.V.
• WATER CAPTURE
  申请人：UNIVERSITY OF LIMERICK

  公开号：US20210162338A1

  公开（公告）日：2021-06-03

  A method of capturing water from a gaseous composition comprising water vapour (suitably air), the method comprising: (a) providing a metal-organic material; and (b) contacting themetal-organic material with water and/or water vapour; wherein upon contact with water and/or water vapour the material switches from a first state to a second state wherein the second state is able to retain a higher amount of water than the first state.
• [EN] IMPROVEMENTS RELATING TO WATER CAPTURE<br/>[FR] AMÉLIORATIONS SE RAPPORTANT À LA CAPTURE D'EAU
  申请人：UNIV LIMERICK

  公开号：WO2020021112A1

  公开（公告）日：2020-01-30

  A method of capturing water from a gaseous composition comprising water vapour (suitably air), the method comprising: (a) providing a metal-organic material; and (b) contacting themetal-organic material with water and/or water vapour; wherein upon contact with water and/or water vapour the material switches from a first state to a second state wherein the second state is able to retain a higher amount of water than the first state.