6-methyl-2,3-phenazinediol | 676488-91-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氮杂萘
• 英文名称: 6-methyl-2,3-phenazinediol
• 英文别名: 6-Methylphenazine-2,3-diol
• CAS: 676488-91-8
• 化学式: C₁₃H₁₀N₂O₂
• 分子量: 226.235
• InChiKey: GIFORRXQVQJDMV-UHFFFAOYSA-N

物化性质

• 沸点：
  490.1±25.0 °C(Predicted)
• 密度：
  1.438±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  17
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  66.2
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  二氯(荚)钌(II)双聚体 、 氯仿 、 6-methyl-2,3-phenazinediol 在 Cs₂CO₃ 作用下， 以 甲醇 为溶剂， 以49%的产率得到
  参考文献：
  名称：

  Diastereoselective Formation of Metallamacrocyclic (Arene)Ru^II and Cp*Rh^III Complexes

  摘要：

  The reaction of [(arene)RuCl2](2) (arene = cymene, 1,3,5-C6H3Me3) and [Cp*RhCl2](2) half-sandwich complexes with tridentate heterocyclic ligands in the presence of base has been investigated. In all cases, the chloro-ligands were substituted to give metallacyclic products with ring sizes between 4 and 18 atoms. The cyclization occurs in a highly diastereoselective fashion with chiral recognition between the different metal fragments. The complexes were comprehensively characterized by elemental analysis, NMR spectroscopy, and single crystal X-ray crystallography. For 2-hydroxy-nicotinic acid and 2-amino-nicotinic acid, dinuclear structures were obtained (1517) whereas for 2,3-dihydroxyquinoline, 2,3-dihydroxyquinoxaline, and 6-methyl-2,3-phenazinediol, trimeric assemblies were found (19-22), and for 4-imidazolecarboxylic acid, a tetrameric assembly (18) was found.

  DOI：

  10.1021/ic035328i