2-methyl-naphthalene-1,5-diyldiamine | 116530-06-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 2-methyl-naphthalene-1,5-diyldiamine
• 英文别名: 2-Methyl-naphthylindiyl-(1.5)-diamin；2-Methyl-naphthalin-1,5-diyldiamin；1.5-Diamino-2-methyl-naphthylin；1.5-Diamino-2-methyl-naphthalin；2-Methyl-naphthylendiamin-(1.5)；1,5-diamino-2-methyl-naphthalene；2-Methyl-1,5-naphthalenediamine；2-methylnaphthalene-1,5-diamine
• CAS: 116530-06-4
• 化学式: C₁₁H₁₂N₂
• 分子量: 172.23
• InChiKey: AWCQGTAMYBFTTN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  13
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  52
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-methyl-naphthalene-1,5-diyldiamine 、 乙酸酐 生成 N,N'-(2-methyl-naphthalene-1,5-diyl)-bis-acetamide
  参考文献：
  名称：

  Giral, Anales de la Real Sociedad Espanola de Fisica y Quimica, 1933, vol. 31, p. 861,878

  摘要：

  DOI：
• 作为产物：
  描述：

  2-methyl-1,5-dinitro-naphthalene 在 盐酸 、 tin 、 tin(ll) chloride 作用下， 生成 2-methyl-naphthalene-1,5-diyldiamine
  参考文献：
  名称：

  Vesely; Kapp, Recueil des Travaux Chimiques des Pays-Bas, 1925, vol. 44, p. 369

  摘要：

  DOI：

文献信息

• Process for preparation of 1,5-diaminonaphthalenes
  申请人：——

  公开号：US20030176722A1

  公开（公告）日：2003-09-18

  In a process where an ortho-alkylnitrobenzene derivative and a vinyl compound as starting materials are used to prepare a 1,5-diaminonaphthalene derivative via a 4-(2-nitrobenzene)propane derivative and a 5-nitro-1-tetralone derivative, the ortho-alkylnitrobenzene derivative and a vinyl compound having an electron withdrawing group such as an acrylonitrile derivative and an acrylate may be reacted in the presence of a base to provide an aromatic nitro compound. An aromatic nitro compound such as 4-(2-nitrobenzene)butanonitrile thus obtained may be cyclized to safely, cost-effectively and selectively provide a 5-nitro-1-tetralone derivative without forming any isomer. Furthermore, from the 5-nitro-1-tetralone derivative, a 1,5-diaminonaphthalene derivative may be prepared without forming any isomer.

  在一个过程中，使用邻位烷基硝基苯衍生物和乙烯化合物作为起始原料，通过4-(2-硝基苯基)丙烷衍生物和5-硝基-1-四氢萘酮衍生物制备1,5-二氨基萘衍生物，邻位烷基硝基苯衍生物和带有电子吸引基团的乙烯化合物，如丙烯腈衍生物和丙烯酸酯，可以在碱的存在下发生反应，以提供芳香硝基化合物。因此，所得的芳香硝基化合物，如4-(2-硝基苯基)丁酮腈，可以环化，安全、经济高效地选择性地提供5-硝基-1-四氢萘酮衍生物，而不形成任何异构体。此外，从5-硝基-1-四氢萘酮衍生物中，可以制备1,5-二氨基萘衍生物，而不形成任何异构体。
• Polymers prepared from 4,4'-bis-(2-(amino (halo) phenoxyphenyl) hexafluoroisopropyl) diphenyl ether
  申请人：HOECHST CELANESE CORPORATION

  公开号：EP0317944A2

  公开（公告）日：1989-05-31

  The application relates to fluorine-containing polyimides, polyamide-acids/esters, polyamides, addition polyimides and imide oligomers which exhibit low melting points, better solubilities, low dielectric constants, superior thermal and thermal oxidative stability, and improved processing characteristics. The products of this application are characterized by the fact that they are derived from 4,4'-bis[2-(amino(halo)phenoxyphenyl)hexafluoroisopropyl]diphenyl ether.

  本申请涉及含氟聚酰亚胺、聚酰胺酸/酯、聚酰胺、加成聚酰亚胺和亚胺低聚物，它们具有低熔点、更好的溶解性、低介电常数、优异的热稳定性和热氧化稳定性，以及更好的加工特性。 这种应用产品的特点是它们来自 4,4'-双[2-（氨基（卤代）苯氧基苯基）六氟异丙基]二苯醚。
• Polymers prepared from 4,4'-bis-[2-(3,4-(dicarboxyphenyl) hexafluoroisopropyl] diphenyl ether dianhydride
  申请人：HOECHST CELANESE CORPORATION

  公开号：EP0317943A2

  公开（公告）日：1989-05-31

  The application relates to fluorine-containing polyimides, polyamide-acids/esters, polyamides, addition polyimides and imide oligomers which exhibit low melting points, better solubilities, low dielectric constants, superior thermal and thermal oxidative stability, and improved processing characteristics. The products of this application are characterized by the fact that they are derived from 4,4'-bis[2-(3,4-(dicarboxyphenyl)­hexafluoroisopropyl]diphenyl ether dianhydride.

  本申请涉及含氟聚酰亚胺、聚酰胺酸/酯、聚酰胺、加成聚酰亚胺和亚胺低聚物，它们具有低熔点、更好的溶解性、低介电常数、优异的热稳定性和热氧化稳定性，以及更好的加工特性。 这种应用产品的特点是它们来自 4,4'-双[2-(3,4-(二羧基苯基)六氟异丙基]二苯醚二酐。
• Copolyimides prepared from 2-(3-aminophenyl)-2-(4-aminophenyl) hexafluoro propane
  申请人：HOECHST CELANESE CORPORATION

  公开号：EP0361413A1

  公开（公告）日：1990-04-04

  Coolyimides and copolyamide-acids having improved solubility and processing characteristics are provided having incorporated into the polymeric chain as a novel aromatic diamine compound, 2-(3-aminophenyl)-2-­(4-aminophenyl) hexafluoropropane (3,4′-6F Diamine). The copolyamide-acids and copolyimides are prepared by reacting the 3,4′-6F Diamine with a mixture of two or more aromatic tetracarboxylic acids or anhydrides thereof. It has been found that the copolyimides of this invention have improved solubility characteristics, low dielectric constants and improved thermal flow properties as a consequence of the meta/para positioning of the amino groups on the diamine, which renders these copolymers more readily melt spinnable for the production of fibers. The copolymers may also be compression molded and fabricated into composites at moderate temperatures and pressures. Solutions of the copolyimides may be cast into films.

  在聚合物链中加入新型芳香族二胺化合物 2-(3-氨基苯基)-2-(4-氨基苯基)六氟丙烷(3,4′-6F 二胺)，可提供具有更好溶解性和加工特性的共聚多酰胺-酰亚胺和共聚多酰胺-酰亚胺。共聚多酰胺酸和共聚多亚胺是通过 3，4′-6F 二胺与两种或两种以上芳香族四羧酸或其酸酐的混合物反应制备的。研究发现，本发明的共聚亚胺具有更好的溶解特性、更低的介电常数和更好的热流特性，这是因为二胺上的氨基具有偏/对位定位，从而使这些共聚物更容易熔融纺丝，用于生产纤维。这些共聚物还可以在中等温度和压力下压缩成型并制成复合材料。共聚亚胺的溶液可浇铸成薄膜。
• Polymers prepared from 2-(3-aminophenyl)-2-(4-aminophenyl) hexafluoro propane
  申请人：HOECHST CELANESE CORPORATION

  公开号：EP0361415A1

  公开（公告）日：1990-04-04

  Polyimides and polyamide-acids having improved solubility and processing characteristics are provided having incorporated into the polymeric chain as a novel aromatic diamine compound, 2-(3-aminophenyl)-2-­(4-aminophenyl) hexafluoropropane (3,4′-6F Diamine). The polyamide-acids and polyimides are prepared by reacting the 3,4′-6F Diamine with aromatic tetracarboxylic acids or anhydrides thereof. It has been.found that the polyimides of this invention have improved solubility characteristics, low dielectric constants and improved thermal flow properties as a consequence of the meta/para positioning of the amino groups on the diamine, which renders these polymers more readily melt spinnable for the production of fibers. The polymers may also be compression molded and fabricated into composites at moderate temperatures and pressures. Solutions of the polyimides may be cast into films.

  本发明提供的聚酰亚胺和聚酰胺-酸具有更好的溶解性和加工特性，在聚合物链中加入了新型芳香族二胺化合物 2-(3-氨基苯基)-2-(4-氨基苯基)六氟丙烷(3,4′-6F 二胺)。聚酰胺酸和聚酰亚胺是通过 3，4′-6F 二胺与芳香族四羧酸或其酸酐反应制备的。研究发现，本发明的聚酰亚胺具有更好的溶解特性、更低的介电常数和更好的热流特性，这是因为二胺上的氨基具有偏/对位定位，从而使这些聚合物更容易熔融纺丝以生产纤维。这些聚合物还可以在中等温度和压力下压缩成型并制成复合材料。聚酰亚胺的溶液可浇铸成薄膜。