2,2'-bis(4-hydroxybutoxy)-1,1'-binaphthalene | 158073-85-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 2,2'-bis(4-hydroxybutoxy)-1,1'-binaphthalene
• 英文别名: 2,2'-bis(4-hydroxybutoxy)-1,1'-binaphthyl；4-[1-[2-(4-Hydroxybutoxy)naphthalen-1-yl]naphthalen-2-yl]oxybutan-1-ol；4-[1-[2-(4-hydroxybutoxy)naphthalen-1-yl]naphthalen-2-yl]oxybutan-1-ol
• CAS: 158073-85-9；158074-01-2
• 化学式: C₂₈H₃₀O₄
• 分子量: 430.544
• InChiKey: FRZFVJFGJXFYMW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  32
• 可旋转键数：
  11
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  58.9
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2,2'-bis(4-hydroxybutoxy)-1,1'-binaphthalene 在 吡啶 、 正丁基锂 作用下， 反应 24.0h， 生成 rac-(S_a,16S,21S)-13,14,15,16,22,23,24,25-octahydro-16,21-diphenyl-12H,21H-benzodinaphtho<2,1-o:1',2'-q><1,14,6,9>dioxadiphosphacyclooctadecine
  参考文献：
  名称：

  Widhalm, Michael; Klintschar, Gerd, Chemische Berichte, 1994, vol. 127, # 8, p. 1411 - 1426

  摘要：

  DOI：
• 作为产物：
  描述：

  S-1,1'-联-2-萘酚 在 lithium aluminium tetrahydride 、 potassium tert-butylate 作用下， 以 乙醚 为溶剂， 反应 40.0h， 生成 2,2'-bis(4-hydroxybutoxy)-1,1'-binaphthalene
  参考文献：
  名称：

  Widhalm, Michael; Klintschar, Gerd, Chemische Berichte, 1994, vol. 127, # 8, p. 1411 - 1426

  摘要：

  DOI：

文献信息

• [EN] POLYCYCLIC COMPOUNDS<br/>[FR] COMPOSÉS POLYCYCLIQUES
  申请人：REUTER CHEMISCHE APPBAU E K

  公开号：WO2020079225A1

  公开（公告）日：2020-04-23

  The present invention relates to compounds of the formula (I), which are suitable as monomers for preparing thermoplastic resins having beneficial optical properties and which can be used for producing optical devices. In Formula (I), A1, A2 are selected from mono- or bicyclic aromatic radicals and mono- or bicyclic heteroaromatic radicals; X represents e.g. a single bond, O, NH, CR6R7; Y is e.g. absent or represents a single bond, O, NH, CR8R9; R1, R2 are hydrogen, a radical Ar' or a radical Ra; R3 is Alk, O-Alk'-, O-Alk'-[O-Alk']o, O-CH2-Ar-C(O)-, O-C(O)-Ar-C(O)-or O-Alk-C(O)-,where in the last five moieties the left O is bound to A1 and A2, respectively; m, n are 0, 1 or 2; o is an integer from 1 to 10; R4, R5 are e.g. selected from CN and a radical Ra; R6, R8 are e.g. selected from hydrogen, a radical Ar' and a radical Ra; R7, R9 are e.g. selected from hydrogen, C1-C4-alkyl and a radical Ar'; Ra is selected from the group consisting of C≡C-R11 and Ar-C≡C-R11; R11 is e.g. selected from hydrogen, methyl, mono- or polycyclic aryl having from 6 to 26 carbon atoms and mono- or polycyclic hetaryl having a total of 5 to 26 atoms, which are ring members, where 1, 2, 3 or 4 of the ring atoms of hetaryl are selected from nitrogen, sulphur and oxygen, while the remainder of these atoms are carbon atoms, where mono- or polycyclic aryl are unsubstituted or substituted; and Ar is e.g. phenylene or naphthylene. The invention also relates to thermoplastic resins comprising a polymerized unit of the compound of formula (I) and to optical devices made of such resins.

  本发明涉及公式（I）的化合物，这些化合物适用作为单体制备具有有益光学性能的热塑性树脂，并可用于制造光学器件。在公式（I）中，A1、A2选自单环或双环芳香基团和单环或双环杂芳基团；X代表例如单键，O，NH，CR6R7；Y例如缺失或代表单键，O，NH，CR8R9；R1、R2为氢，基团Ar'或基团Ra；R3为Alk，O-Alk'-，O-Alk'-[O-Alk']o，O-CH2-Ar-C(O)-，O-C(O)-Ar-C(O)-或O-Alk-C(O)-，在最后五个基团中，左侧的O分别与A1和A2结合；m、n为0、1或2；o为1到10的整数；R4、R5例如选自CN和基团Ra；R6、R8例如选自氢，基团Ar'和基团Ra；R7、R9例如选自氢，C1-C4-烷基和基团Ar'；Ra选自C≡C-R11和Ar-C≡C-R11的组，R11例如选自氢，甲基，含有6到26个碳原子的单环或多环芳基和含有总共5到26个原子的单环或多环杂芳基，其中环原子中的1、2、3或4个来自氮、硫和氧，其余原子为碳原子，其中单环或多环芳基是未取代或取代的；Ar例如苯基或萘基。该发明还涉及包含公式（I）化合物聚合单元的热塑性树脂以及由这种树脂制成的光学器件。
• METHOD FOR PRODUCING CARBONATE DERIVATIVE
  申请人：NATIONAL UNIVERSITY CORPORATION KOBE UNIVERSITY

  公开号：US20210403409A1

  公开（公告）日：2021-12-30

  The objective of the present invention is to provide a method for producing a polycarbonate safely and efficiently even without using a base. The method for producing a carbonate derivative according to the present invention is characterized in comprising the step of irradiating a high energy light to a composition comprising the halogenated methane and the hydroxy group-containing compound in the presence of oxygen, wherein a molar ratio of a total usage amount of the hydroxy group-containing compound to 1 mole of the halogenated methane is 0.05 or more.

  本发明的目标是提供一种即使不使用碱也能安全高效生产聚碳酸酯的方法。根据本发明的碳酸酯衍生物生产方法的特征在于，在氧气存在的情况下，将含卤代甲烷和含羟基化合物的组合物照射高能光，其中羟基化合物总使用量与1摩尔卤代甲烷的摩尔比为0.05或更高。
• POLYCARBONATE RESIN COMPOSITION, AND OPTICAL MATERIAL AND OPTICAL LENS EACH MANUFACTURED USING SAME
  申请人：Mitsubishi Gas Chemical Company, Inc.

  公开号：EP3138876A1

  公开（公告）日：2017-03-08

  [Problem] To provide: a polycarbonate resin composition which has a high refractive index and fluidability at a suitable level for molding use, also has low birefringence, and rarely undergoes optical distortion; and an optical material. [Solution] A polycarbonate resin composition comprising: a polycarbonate resin (A) which has a constitutional unit (a) represented by general formula (4); and a polycarbonate resin (B) which has a constitutional unit (b) represented by general formula (5). (In formula (4), X represents an alkylene group having 1 to 4 carbon atoms.) (In formula (5), R1 and R2 independently represent a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an alkoxyl group having 1 to 20 carbon atoms, a cycloalkyl group having 5 to 20 carbon atoms, a cycloalkoxyl group having 5 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, or an aryloxy group having 6 to 20 carbon atoms; and Y represents an alkylene group having 1 to 4 carbon atoms.)

  [问题]提供一种聚碳酸酯树脂组合物，该组合物具有高折射率和流动性，适合模塑使用，同时具有低双折射，并且很少发生光学畸变；以及一种光学材料。 [解决方案] 一种聚碳酸酯树脂组合物，包括：具有通式（4）表示的组成单元（a）的聚碳酸酯树脂 （A）；以及具有通式（5）表示的组成单元（b）的聚碳酸酯树脂（B）。式（4）中，X 代表具有 1 至 4 个碳原子的亚烷基。(在式(5)中，R1 和 R2 分别代表氢原子、具有 1 至 20 个碳原子的烷基、具有 1 至 20 个碳原子的烷氧基、具有 5 至 20 个碳原子的环烷基、具有 5 至 20 个碳原子的环烷氧基、具有 6 至 20 个碳原子的芳基或具有 6 至 20 个碳原子的芳氧基；Y 代表具有 1 至 4 个碳原子的亚烷基）。
• RESIN PRODUCED BY POLYCONDENSATION, AND RESIN COMPOSITION
  申请人：Mitsubishi Gas Chemical Company, Inc.

  公开号：EP3141570A1

  公开（公告）日：2017-03-15

  According to one embodiment, a polyester resin is provided, which includes a structural unit derived from a compound represented by general formula (1), a structural unit derived from a compound represented by general formula (2), and a structural unit derived from a dicarboxylic acid or a derivative thereof.

  根据其中一个实施方案，提供了一种聚酯树脂，它包括由通式（1）代表的化合物衍生的结构单元、由通式（2）代表的化合物衍生的结构单元和由二羧酸或其衍生物衍生的结构单元。
• METHOD OF PRODUCING THERMOPLASTIC RESIN
  申请人：Mitsubishi Gas Chemical Company, Inc.

  公开号：EP3372627A1

  公开（公告）日：2018-09-12

  The present invention provides a method for producing a thermoplastic resin by reacting reactants comprising a dihydroxy compound. In this production method, the dihydroxy compound comprises a dihydroxy compound represented by the following formula (1), and at least one of a compound represented by the following formula (A), a compound represented by the following formula (B), and a compound represented by the following formula (C), wherein the total weight of the compound represented by the formula (A), the compound represented by the formula (B), and the compound represented by the formula (C) is 1,500 ppm or more, based on the weight (100 parts by weight) of the dihydroxy compound represented by the formula (1).

  本发明提供了一种通过对包含二羟基化合物的反应物进行反应生产热塑性树脂的方法。在该生产方法中，二羟基化合物包括下式(1)代表的二羟基化合物，以及下式(A)代表的化合物、下式(B)代表的化合物和下式(C)代表的化合物中的至少一种、其中式（A）代表的化合物、式（B）代表的化合物和式（C）代表的化合物的总重量，以式（1）代表的二羟基化合物的重量（100 重量份）为基准，为 1,500 ppm 或以上。