1,1'-Binaphthyl-2,2'-diyl benzylphosphoramidate | 1313031-64-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1,1'-Binaphthyl-2,2'-diyl benzylphosphoramidate
• 英文别名: N-benzyl-13-oxo-12,14-dioxa-13λ5-phosphapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-13-amine
• CAS: 1313031-64-9
• 化学式: C₂₇H₂₀NO₃P
• 分子量: 437.434
• InChiKey: IWMBNQNKKMDUIS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.6
• 重原子数：
  32
• 可旋转键数：
  3
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  47.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  S-1,1'-联-2-萘酚 在 三乙胺 、 三氯氧磷 作用下， 以 二氯甲烷 为溶剂， 反应 6.67h， 生成 1,1'-Binaphthyl-2,2'-diyl benzylphosphoramidate
  参考文献：
  名称：

  Phosphoroamidate compounds of 1,1′-Bi-2-napthol: Synthesis, structural characterization and solvent-free ring-opening polymerization of ε-caprolactone and l-lactide

  摘要：

  New phosphoroamidate compounds with 1,1'-Bi-2-napthol (binol) ligand were synthesized from the corresponding phosphorochloridate intermediates and benzyl amine or benzyl amine derivatives. They were completely characterized using different spectroscopic methods and single crystal X-ray diffraction studies. These compounds effectively catalyze the ring-opening polymerization of epsilon-caprolactone (CL) and L-lactide (LA). This methodology of polymer synthesis is green and environmental benign since phosphorus is a natural constituent of human anatomy and these polymers being completely biodegradable. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.01.088

文献信息

• Phosphoroamidate compounds of 1,1′-Bi-2-napthol: Synthesis, structural characterization and solvent-free ring-opening polymerization of ε-caprolactone and l-lactide
  作者：Ravikumar R. Gowda、Debashis Chakraborty、Venkatachalam Ramkumar

  DOI：10.1016/j.ica.2011.01.088

  日期：2011.6

  New phosphoroamidate compounds with 1,1'-Bi-2-napthol (binol) ligand were synthesized from the corresponding phosphorochloridate intermediates and benzyl amine or benzyl amine derivatives. They were completely characterized using different spectroscopic methods and single crystal X-ray diffraction studies. These compounds effectively catalyze the ring-opening polymerization of epsilon-caprolactone (CL) and L-lactide (LA). This methodology of polymer synthesis is green and environmental benign since phosphorus is a natural constituent of human anatomy and these polymers being completely biodegradable. (C) 2011 Elsevier B. V. All rights reserved.