2-(ethylanilino)ethyl bicyclo[2.2.1]hept-5-ene-2-carboxylate | 736981-09-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 2-(ethylanilino)ethyl bicyclo[2.2.1]hept-5-ene-2-carboxylate
• CAS: 736981-09-2
• 化学式: C₁₈H₂₃NO₂
• 分子量: 285.386
• InChiKey: FVYBDZZZVHNYFU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.27
• 重原子数：
  21.0
• 可旋转键数：
  6.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  29.54
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  2-(ethylanilino)ethyl bicyclo[2.2.1]hept-5-ene-2-carboxylate 在 哌啶 、 三氯氧磷 作用下， 以 乙醇 为溶剂， 反应 25.0h， 生成 2-[N-ethyl-4-[(E)-2-(4-nitrophenyl)ethenyl]anilino]ethyl bicyclo[2.2.1]hept-5-ene-2-carboxylate
  参考文献：
  名称：

  Synthesis and Nonlinear-Optical Properties of Vinyl-Addition Poly(norbornene)s

  摘要：

  Vinyl-addition poly(norbornene) copolymers functionalized with nonlinear optical chromophore side groups have been prepared using (eta(6)-toluene)Ni(C6F5)(2), and their electrooptic properties have been characterized. The nickel complex used to polymerize the norbornene monomers is tolerant to many functional groups found in nonlinear optical chromophores although nitriles and amines other than trisubstituted amines strongly inhibit the reaction. A vinyl-addition copolymer of hexylnorbornene and a norbornene-functionalized Disperse Red 1 chromophore was scaled up and studied in detail. Initial studies indicate that electric field poling is effective but that relaxation of polar order in the poly(norbornene) is faster than in a comparable methacrylate copolymer.

  DOI：

  10.1021/ma040044i
• 作为产物：
  描述：

  N-乙基-N-羟乙基苯胺 、 5-降冰片烯-2-羧酸乙酯 在 二正丁基氧化锡 作用下， 以 甲苯 为溶剂， 反应 6.0h， 以70%的产率得到2-(ethylanilino)ethyl bicyclo[2.2.1]hept-5-ene-2-carboxylate
  参考文献：
  名称：

  Synthesis and Nonlinear-Optical Properties of Vinyl-Addition Poly(norbornene)s

  摘要：

  Vinyl-addition poly(norbornene) copolymers functionalized with nonlinear optical chromophore side groups have been prepared using (eta(6)-toluene)Ni(C6F5)(2), and their electrooptic properties have been characterized. The nickel complex used to polymerize the norbornene monomers is tolerant to many functional groups found in nonlinear optical chromophores although nitriles and amines other than trisubstituted amines strongly inhibit the reaction. A vinyl-addition copolymer of hexylnorbornene and a norbornene-functionalized Disperse Red 1 chromophore was scaled up and studied in detail. Initial studies indicate that electric field poling is effective but that relaxation of polar order in the poly(norbornene) is faster than in a comparable methacrylate copolymer.

  DOI：

  10.1021/ma040044i