β-perfluoronaphthyllithium | 73501-11-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: β-perfluoronaphthyllithium
• 英文别名: heptafluoro-2-naphthyl-lithium；heptafluoro-2-naphthyllithium
• CAS: 73501-11-8
• 化学式: C₁₀F₇Li
• 分子量: 260.04
• InChiKey: NYMKZWYXYUXLEF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.61
• 重原子数：
  18.0
• 可旋转键数：
  0.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  β-perfluoronaphthyllithium 生成 1,3,4,5,6,7,8-七氟萘-2-羧酸
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: F: PerFHalOrg.SVol.1, 1.2, page 1 - 15

  摘要：

  DOI：
• 作为产物：
  描述：

  1,3,4,5,6,7,8-heptafluoronaphthalene 在 正丁基锂 作用下， 以 乙醚 、 正己烷 为溶剂， 生成 β-perfluoronaphthyllithium
  参考文献：
  名称：

  六氟1,2-萘

  摘要：

  1,3,4,5,6,7,8-七氟萘基锂消除了氟化锂，仅生成六氟-1,2-萘，而不是其2,3-异构体，如用呋喃捕集并通过添加未分解的1,3,4,5,6,7,8-七氟萘基锂可得到十三氟联萘的特征混合物。

  DOI：

  10.1039/c39790001147

文献信息

• [EN] NON-COORDINATING ANION ACTIVATORS CONTAINING A CATION WITH LONG CHAIN ALKOXY FUNCTIONALIZATION<br/>[FR] ACTIVATEURS ANIONIQUES NON COORDONNANTS CONTENANT UN CATION À FONCTIONNALISATION ALCOXY À LONGUE CHAÎNE
  申请人：EXXONMOBIL CHEMICAL PATENTS INC

  公开号：WO2021086467A1

  公开（公告）日：2021-05-06

  Activators may comprise compounds represented by the Formula [Ar(EHR1R2)(OR3)]d+[Mk+Qn]d, wherein: Ar is an aryl group; E is nitrogen or phosphorous; R1 is a C1-C30, optionally substituted, linear alkyl group; R2 is a C1-C30, optionally substituted, linear alkyl group; R3 is a C10-C30, optionally substituted, linear alkyl group; M is an element selected from group 13 of the Periodic Table of the Elements; d is 1, 2 or 3; k is 1, 2, or 3; n is 1, 2, 3, 4, 5, or 6; n - k = d; and each Q is independently hydride, bridged or unbridged dialkylamido, halide, alkoxide, aryloxide, hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, or halosubstituted-hydrocarbyl radical. Catalysts systems may comprise these activators and methods of preparing polyolefins may use these catalysts systems.

  激活剂可能包括由公式[Ar(EHR1R2)(OR3)]d+[Mk+Qn]d所代表的化合物，其中：Ar是芳基团；E是氮或磷；R1是C1-C30的、可选择地取代的、直链烷基基团；R2是C1-C30的、可选择地取代的、直链烷基基团；R3是C10-C30的、可选择地取代的、直链烷基基团；M是周期表元素第13族中选择的元素；d为1、2或3；k为1、2或3；n为1、2、3、4、5或6；n - k = d；每个Q独立地是氢化物、桥联或非桥联的二烷基胺基、卤化物、烷氧基、芳氧基、烃基、取代烃基、卤代烃基、取代卤代烃基或卤代取代烃基基团。催化剂系统可能包括这些激活剂，制备聚烯烃的方法可能使用这些催化剂系统。
• Polycyclic fluoro-aromatic compounds. Part 11 [1]. Hexafluoro-1,2-naphthalyne
  作者：James Burdon、Harpal S. Gill、Ian W. Parsons、John Colin Tatlow

  DOI：10.1016/s0022-1139(00)85209-4

  日期：1984.2

  Heptafluoro-2-naphthyl-lithium decomposes to give hexafluoro-1,2- naphthalyne and not the 2,3-compound. This was demonstrated by capture of the aryne with furan and with heptafluoro-2-naphthyl-lithium; in this last reaction the ratio of attack at the 2-position of the naphthalyne to that at the 1 was 9:2.

  七氟-2-萘基锂分解得到六氟1,2-萘，而不是2,3-化合物。用呋喃和七氟-2-萘基锂捕获芳烃证明了这一点。在最后一个反应中，萘2位与1位的进攻比率为9：2。
• Burdon, James; Gill, Harpal S.; Parsons, Ian W., Journal of the Chemical Society. Perkin transactions I, 1980, p. 2494 - 2496
  作者：Burdon, James、Gill, Harpal S.、Parsons, Ian W.

  DOI：——

  日期：——
• BURDON J.; GILL H. S.; PARSONS I. W.; TATLOW J. COLIN, J. CHEM. SOC. CHEM. COMMUN., 1979, NO 24, 1147-1148
  作者：BURDON J.、 GILL H. S.、 PARSONS I. W.、 TATLOW J. COLIN

  DOI：——

  日期：——
• Non-Coordinating Anion Activators Containing a Cation with Long Chain Alkoxy Functionalization
  申请人：ExxonMobil Chemical Patents Inc.

  公开号：US20220388946A1

  公开（公告）日：2022-12-08

  Activators may comprise compounds represented by the Formula [Ar(EHR 1 R 2 )(OR 3 )]d+[M k+ Q n ] d , wherein: Ar is an aryl group; E is nitrogen or phosphorous; R 1 is a C 1 -C 30 , optionally substituted, linear alkyl group; R 2 is a C 1 -C 30 , optionally substituted, linear alkyl group; R 3 is a C 10 -C 30 , optionally substituted, linear alkyl group; M is an element selected from group 13 of the Periodic Table of the Elements; d is 1, 2 or 3; k is 1, 2, or 3; n is 1, 2, 3, 4, 5, or 6; n−k=d; and each Q is independently hydride, bridged or unbridged dialkylamido, halide, alkoxide, aryloxide, hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, or halosubstituted-hydrocarbyl radical. Catalysts systems may comprise these activators and methods of preparing polyolefins may use these catalysts systems.