[RuH(1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane)4Cl] | 313254-45-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氮杂环化合物
• 英文名称: [RuH(1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane)4Cl]
• 英文别名: [RuH(pta)4Cl]；chloro(hydrido)ruthenium;1,3,5-triaza-7-phosphatricyclo[3.3.1.13,7]decane
• CAS: 313254-45-4
• 化学式: C₂₄H₄₉ClN₁₂P₄Ru
• 分子量: 766.151
• InChiKey: QRNAILBJOFOQEV-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  水 、 氢气 、 [RuCl₂(1,3,5-triaza-7-phosphaadamantane)₄] 以 水 为溶剂， 生成 [RuH2(1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane)4] 、 [RuH(1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane)4(H2O)](1+) 、 [RuH(1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane)4Cl]
  参考文献：
  名称：

  Water-soluble (η6-arene)ruthenium(II)-phosphine complexes and their catalytic activity in the hydrogenation of bicarbonate in aqueous solution

  摘要：

  The reactions of [(eta(6)-C6H6)RuCl2](2) and [(eta(6)-p-cymene)RuCl2](2) With hydrogen in the presence of the water-soluble phosphines tppts (meta-trisulfonated triphenylphosphine) and pta (1,3,5-triaza-7-phosphaadamantane) afforded as the main species [(eta(6)- C6H6)RuH(tppts)(2)](+), [(eta(6)-C6H6)RuH(pta)(2)](+), [(eta(6)-p-cymene)RuH(tppts)(2)](+) and [(eta(6)-p-cymene)RuH(pta)(2)](+). This latter complex was also formed in the reaction of [(eta(6)-p-cymene)RuCl2(pta)] and hydrogen with a redistribution of pta. In addition, prolonged hydrogenation at elevated temperatures and in the presence of excess of pta led to the formation of the arene-free [RuH(pta)(4)CI], [RuH(pta)(4)(H2O)](+), [RuH2(pta)(4)] and [RuH(pta)(5)](+) complexes. Ru-hydrides, such as [(eta6-arene)RuH(L)(2)](+), catalyzed the hydrogenation of bicarbonate to formate in aqueous solutions at p(H-2) = 100 bar, T = 50-70 degreesC. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2003.11.036