(E)-<2-(4-dimethylaminonaphthyl)ethenyl>pyridinium iodide | 201593-27-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: (E)-<2-(4-dimethylaminonaphthyl)ethenyl>pyridinium iodide
• 英文别名: (E)-N-octadecyl-4-[2-(4-dimethylaminonaphtyl)ethenyl]pyridinuim iodide
• CAS: 201593-27-3；181777-39-9
• 化学式: C₃₇H₅₅N₂*I
• 分子量: 654.762
• InChiKey: MOPDRRDGYVNFPE-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  7.63
• 重原子数：
  40.0
• 可旋转键数：
  20.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  7.12
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  bis(tetrabutylammonium) bis(2-thione-1,3-dithiol-4,5-dimercapto) zinc 、 (E)-<2-(4-dimethylaminonaphthyl)ethenyl>pyridinium iodide 以 乙醇 、 丙酮 为溶剂， 以70%的产率得到bis(E)-N-octadecyl-4-[2-(4-dimethylaminonaphtyl)ethenyl]pyridinuim bis(2-thione-1,3-dithiol-4,5-dimerkapto) zinc
  参考文献：
  名称：

  Langmuir–Blodgett film and second harmonic generation of a new type of amphiphilic non-linear optical bis-chromophore complex dye

  摘要：

  A bivalent zinc complex anion: bis(2-thione-1,3-dithiol-4,5-dimercapto)zinc, has been chosen to balance several non-linear optical (NLO) dye cations in the design and synthesis of a series of novel bis-chromophore complex dyes. The Langmuir film-forming properties of these new NLO complex dyes at the air/water interface, the stability and second-order non-linear optical properties of the monolayer and Langmuir-Blodgett multilayer films were investigated. Results show that both the film-forming properties and NLO coefficiencies were improved greatly when the zinc complex anion was incorporated into four types of NLO-active organic dyes.

  DOI：

  10.1039/ft9969202585
• 作为产物：
  描述：

  4-甲基吡啶 在 哌啶 作用下， 以 乙醇 为溶剂， 反应 76.0h， 生成 (E)-<2-(4-dimethylaminonaphthyl)ethenyl>pyridinium iodide
  参考文献：
  名称：

  Langmuir–Blodgett film and second harmonic generation of a new type of amphiphilic non-linear optical bis-chromophore complex dye

  摘要：

  A bivalent zinc complex anion: bis(2-thione-1,3-dithiol-4,5-dimercapto)zinc, has been chosen to balance several non-linear optical (NLO) dye cations in the design and synthesis of a series of novel bis-chromophore complex dyes. The Langmuir film-forming properties of these new NLO complex dyes at the air/water interface, the stability and second-order non-linear optical properties of the monolayer and Langmuir-Blodgett multilayer films were investigated. Results show that both the film-forming properties and NLO coefficiencies were improved greatly when the zinc complex anion was incorporated into four types of NLO-active organic dyes.

  DOI：

  10.1039/ft9969202585